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Vinyl bromide

Product Name
Vinyl bromide
CAS No.
593-60-2
Chemical Name
Vinyl bromide
Synonyms
Bromoethene;C2H3Br;1-Bromoethylene;Vinylbromid;1-Bromoethene;R1140B1;Bromethen;NCI-C50373;SAYTEX VBR;bromo-ethen
CBNumber
CB5853922
Molecular Formula
C2H3Br
Formula Weight
106.95
MOL File
593-60-2.mol
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Vinyl bromide Property

Melting point:
−139 °C(lit.)
Boiling point:
16 °C750 mm Hg(lit.)
Density 
1.517 g/mL at 25 °C(lit.)
vapor density 
3.8 (15 °C, vs air)
vapor pressure 
1551 mm Hg ( 37.8 °C)
refractive index 
n20/D 1.410
Flash point:
1 °F
storage temp. 
2-8°C
form 
Gas
color 
Colorless to Almost colorless
explosive limit
15%
Water Solubility 
insoluble
BRN 
1361370
Exposure limits
TLV-TWA 5 ppm (~22 mg/m3)(ACGIH); Lowest Detectable Level (NIOSH); car cinogenicity: Suspected Human Carcinogen (ACGIH), Animal Sufficient Evidence (IARC).
Dielectric constant
4.8(25℃)
Stability:
Stable, but may polymerize in sunlight. Reacts violently with all types of oxidizer. Incompatible with strong oxidizing agents, peroxides, copper, copper alloys, plastics. Highly flammable.
InChIKey
INLLPKCGLOXCIV-UHFFFAOYSA-N
CAS DataBase Reference
593-60-2(CAS DataBase Reference)
IARC
2A (Vol. 39, Sup 7, 71, 97) 2008
NIST Chemistry Reference
Ethene, bromo-(593-60-2)
EPA Substance Registry System
Vinyl bromide (593-60-2)
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Safety

Hazard Codes 
F+,T,F
Risk Statements 
45-12-19-36/37-22-11
Safety Statements 
53-9-16-29-33-45-26
RIDADR 
UN 1993 3/PG 1
WGK Germany 
3
RTECS 
KU8400000
3-10
Autoignition Temperature
986 °F
HazardClass 
2.1
PackingGroup 
II
HS Code 
29033990
Hazardous Substances Data
593-60-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H220Extremely flammable gas

H280Contains gas under pressure; may explode if heated

H302Harmful if swallowed

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

P410+P403Protect from sunlight. Store in a well-ventilated place.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
434191
Product name
Vinyl bromide solution
Purity
1.0 M in THF
Packaging
100ml
Price
$106
Updated
2024/03/01
Sigma-Aldrich
Product number
434191
Product name
Vinyl bromide solution
Purity
1.0 M in THF
Packaging
800ml
Price
$462
Updated
2024/03/01
TCI Chemical
Product number
V0127
Product name
Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
Packaging
100mL
Price
$87
Updated
2024/03/01
Sigma-Aldrich
Product number
V1902
Product name
Vinyl bromide
Purity
98%
Packaging
100g
Price
$200
Updated
2024/03/01
Sigma-Aldrich
Product number
V1902
Product name
Vinyl bromide
Purity
98%
Packaging
2.2kg
Price
$1090
Updated
2024/03/01
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Vinyl bromide Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Vinyl bromide is a colorless gas or liquid at low ambient temperature. Pleasant odor. Shipped as a liquefied compressed gas with 0.1% phenol added to prevent polymerization.

Uses

Vinyl bromide is used as a fire retardant inplastics.

Uses

Production of flame-resistant plastics or thermoplastic resins.

Definition

ChEBI: Bromoethene is a monohaloethene and a bromoalkene.

Production Methods

VB can be produced by the catalytic addition of hydrogen bromide to acetylene in the presence of mercury and copper halide catalysts or by partial dehydrobromination of ethylene dibromide with alcoholic potassium hydroxide.

General Description

Boiling point 60°F. Liquid at low ambient temperatures. Specific gravity 1.51. A suspected carcinogen. Under exposure to fire or heat containers may rupture violently and rocket.

Air & Water Reactions

Highly flammable, with air forms peroxides

Reactivity Profile

VINYL BROMIDE is a light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material [Handling Chemicals Safely 1980.. p. 958]. Vinyl bromide will react violently with oxidants.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

Health Hazard

Inhalation of this gas at high concentrationscan produce anesthesia and kidney damage.Exposure to 2.5% concentration in air pro duced anesthetic effects in rats. A 15-minuteexposure to 10% concentration was fatal torats (ACGIH 1986). Kidney injury occurredat a 5% exposure level. Human toxicity datafor this compound are not available. The liq uid is mild to moderately irritating to theeyes.
Vinyl bromide manifested carcinogenicproperties in laboratory animals. It producedliver and blood tumors in rats and mice.Its cancer-causing effects in humans arenot known. However, on the basis of itssimilarity to vinyl chloride, it is suspectedto be a human carcinogen.

Fire Hazard

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane will ignite spontaneously in air. May polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. Can react violently with oxidzing materials. May polymerize in sunlight. To fight fire, use CO2, dry chemical, or water spray. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and VINYL CHLORIDE.

Potential Exposure

Vinyl bromide is used as an intermediate in organic synthesis and for the preparation of plastics by polymerization and copolymerization; as a comonomer with acrylonitrile and other vinyl monomers in modacrylic fibers; in the production of flame-retardant synthetic fibers.

Carcinogenicity

Vinyl bromide is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Shipping

UN1085 Vinyl bromide, stabilized, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Incompatibilities

Vinyl bromide is a dangerous chemically unstable compound that may polymerize spontaneously in heat, sunlight and possibly exposure to UV. Dangerously reactive with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, acetylene, strong acids, strong bases, copper compounds. Add 0.1% phenol to gas to prevent polymerization.

Waste Disposal

Return refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federal regulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillabletype cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place.

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Vinyl bromide Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Shanghai Ennopharm Co., Ltd.
Tel
+86 (21) 6435-5022
Country
China
ProdList
4271
Advantage
65
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from Vinyl bromide manufacturers

Henan Tianfu Chemical Co.,Ltd.
Product
593-60-2 593-60-2
Price
US $0.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100
Release date
2021-07-19
Zhuozhou Wenxi import and Export Co., Ltd
Product
Vinyl bromide 593-60-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
Vinyl bromide 593-60-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-08-08

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