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Vinylmagnesium bromide

Product Name
Vinylmagnesium bromide
CAS No.
1826-67-1
Chemical Name
Vinylmagnesium bromide
Synonyms
bromovinylmagnesium;PEFC-028;0.98g/ml,20℃;bromoethenyl-magn;Bromvinylmagnesium;bromoethenyl-magnesiu;Bromoethenylmagnesium;VINYLMAGNESIUMBROMICLC;VINYLMAGNESIUM BROMIDE;Magnesium vinyl bromide
CBNumber
CB6710891
Molecular Formula
C2H3BrMg
Formula Weight
131.26
MOL File
1826-67-1.mol
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Vinylmagnesium bromide Property

Density 
0.981 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
Refrigerator
solubility 
vigorous reaction
form 
Solution
color 
Clear light brown to brown
Water Solubility 
vigorous reaction
BRN 
3535841
CAS DataBase Reference
1826-67-1(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, bromoethenyl- (1826-67-1)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14-19-34-14/15-40-37
Safety Statements 
16-26-29-33-36/37/39-45-6A-43B-43
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
1-3-10
HazardClass 
4.3/3
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0 M in THF
Packaging
100ml
Price
$63.4
Updated
2024/03/01
Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0?M in THF
Packaging
4X25ML
Price
$90.4
Updated
2024/03/01
Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0?M in THF
Packaging
18L
Price
$2330
Updated
2024/03/01
TCI Chemical
Product number
V0053
Product name
Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
Packaging
100g
Price
$79
Updated
2024/03/01
Sigma-Aldrich
Product number
257257
Product name
Vinylmagnesium bromide solution
Purity
1.0 M in THF
Packaging
200ml
Price
$214
Updated
2024/03/01
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Vinylmagnesium bromide Chemical Properties,Usage,Production

Chemical Properties

Clear light brown to brown solution

Uses

Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.
It may also be used in the following transformations:

  • (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.
  • (R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.
  • 2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.
  • (4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.
  • Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.

Vinylmagnesium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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Vinylmagnesium bromide Suppliers

Shanghai Chemart Chemical Technology Co., Ltd.
Tel
021-021-50400622 15618790390
Email
info@chemart.cn
Country
China
ProdList
210
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58
Gansu Gefu Chemical Technology Co.,Ltd
Tel
+8615858145714 Mobile,Whatsapp,Telegram; 13951998329
Fax
0571-56059825 (fandachem@gmail.com)
Email
sjg9988@126.com
Country
China
ProdList
21
Advantage
55
Shanghai Weiji Environmental Protection Technology Co., LTD
Tel
13817380975 13391095697
Email
info@wjscientific.cn
Country
China
ProdList
17
Advantage
58
Shanghai qiyan medicine technology co., ltd
Tel
15021941186
Email
3572772243@qq.com
Country
China
ProdList
182
Advantage
58
Nanjing Freehoo Chemical Technology Co., Ltd.
Tel
025-57798086 13951998329
Fax
025-57798086
Email
sjg9988@126.com
Country
China
ProdList
37
Advantage
58
Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
+86-18521732826
Email
market@aladdin-e.com
Country
China
ProdList
48617
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2341
Advantage
56
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View Lastest Price from Vinylmagnesium bromide manufacturers

Hebei Duling International Trade Co. LTD
Product
Vinylmagnesium bromide 1826-67-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-01-13
Hebei Yanxi Chemical Co., Ltd.
Product
Vinylmagnesium bromide 1826-67-1
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-29
Career Henan Chemical Co
Product
Vinylmagnesium bromide 1826-67-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10KG
Release date
2019-08-05

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  • CH2CHMgBr
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  • Organometallic Reagents
  • Alkenyl
  • Grignard Reagents & Alkyl Metals
  • Grignard Reagents
  • Typical Metal Compounds
  • Mg (Magnesium) Compounds
  • Classes of Metal Compounds
  • Grignard Reagent
  • GRIGNARD REAGENTS
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry