ChemicalBook > CAS DataBase List > 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride

1,2,3,4-Cyclobutanetetracarboxylic Dianhydride

Product Name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
CAS No.
4415-87-6
Chemical Name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
Synonyms
1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE;Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride;CDBA;-tetraone;Maleic anhydride cyclic dimer.;Cyclobutane-1,2,3,4-tetracarboxylic;Cyclobutanetetracarboxylic Dianhydride;1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&;Cyclobutanetetracarboxylic acid dianhydride;Cyclobutanetetracarboxylic Dianhydride (CBDA)
CBNumber
CB6718246
Molecular Formula
C8H4O6
Formula Weight
196.11
MOL File
4415-87-6.mol
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1,2,3,4-Cyclobutanetetracarboxylic Dianhydride Property

Melting point:
>300 °C (lit.)
Boiling point:
545.3±50.0 °C(Predicted)
Density 
1.823±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
soluble in Toluene
form 
powder to crystal
color 
White to Light yellow
Sensitive 
Moisture Sensitive
BRN 
1430553
InChI
InChI=1S/C8H4O6/c9-5-1-2(6(10)13-5)4-3(1)7(11)14-8(4)12/h1-4H
InChIKey
YGYCECQIOXZODZ-UHFFFAOYSA-N
SMILES
O1C(=O)C2C3C(C2C1=O)C(=O)OC3=O
CAS DataBase Reference
4415-87-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
1759
WGK Germany 
3
9-21
HazardClass 
8
PackingGroup 
III
HS Code 
29172090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
161330
Product name
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
Purity
≥94%
Packaging
5g
Price
$236
Updated
2025/07/31
TCI Chemical
Product number
C2262
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
Purity
>98.0%(T)
Packaging
1g
Price
$60
Updated
2025/07/31
TCI Chemical
Product number
C2262
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
Purity
>98.0%(T)
Packaging
5g
Price
$200
Updated
2025/07/31
TCI Chemical
Product number
C2842
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
Purity
>98.0%(T)
Packaging
1g
Price
$36
Updated
2025/07/31
TCI Chemical
Product number
C2842
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
Purity
>98.0%(T)
Packaging
5g
Price
$182
Updated
2025/07/31
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1,2,3,4-Cyclobutanetetracarboxylic Dianhydride Chemical Properties,Usage,Production

Description

Cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CBDA) is an anhydride with a cis-trans-cis configuration. It can be used to synthesise polyimide films. Polymer films have excellent heat resistance, are transparent and colourless, with transmittance ranging from 81.5% to 85.8%, and are suitable for use in high quality display materials such as liquid crystal displays. The polymers made with pyrrolidine dianhydride instead of CBDA are dark yellow in colour and have a lower transmittance in the range of 48% to 63.9%.

Chemical Properties

White to light yellow solid

Uses

Reactant for:

  • Preparation of biologically and pharmacologically active molecules
  • Preparation of photosensitive polyimide material for high performance organic thin-film transistors
  • Selective crosslinking of polyimide for photonic devices

Uses

1,2,3,4-Cyclobutanetetracarboxylic Dianhydride and diamine monomer are used for preparation a polyimide (PI), the type of polyimide has excellent electrical characteristics and optical type, with the material prepared the PI film, in addition to having a higher rate cast visible outside, and can withstand high temperatures thirty-four Baidu. Its performance is very good, is the preparation of a liquid crystal display with an ideal material for the film.

Preparation

Preparation of 1,2,3,4- cyclobutanetetracarboxylic acid dianhydride (CBDA)To a 2L quartz glass photoreactor equipped with sixteen UV lamps (300nm) , a stirrer and a cooler were attached and 250ml of ethyl acetate and 100g of maleic anhydride were added thereto followed by stirring for complete mixing. To avoid an excessive temperature increase, an air-cooling type cooler was first run and then UV light was illuminated for a photoreaction for 24h with stirring so as not to have the reactants adhered to the reactor walls. As a result, 71g of white solid was obtained. After the filtration, the white solid was dried for 24h in a vacuum dryer at 60°C Thus-obtained solid was then added to acetic anhydride, dissolved therein and slowly heated to 150°C followed by the reaction for 24h . Hot reaction solution was filtered through a filter paper to remove impurities and kept in a freezer at the temperature of 0°C or less for recrystallization for 24h to obtain a yellow solid. Thus-obtained solid was filtered and washed three times with 1,4-dioxane to remove acetic anhydride, and then dried in a vacuum oven at 60°C for 48h to obtain 64g of 1, 2, 3, 4 -cyclobutane tetracarboxylic acid dianhydride (CBDA) .

1,2,3,4-Cyclobutanetetracarboxylic Dianhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,3,4-Cyclobutanetetracarboxylic Dianhydride Suppliers

Sino-Biochemical Laboratory Co., Ltd.
Tel
21-21-31590156 13042155638
Fax
+86 21 31590152
Email
sales@sino-biochemlab.com
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China
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Shaoxing Shunbang Medical Technology Co. LTD
Tel
13355710117
Email
214519960@qq.com
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China
ProdList
109
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Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
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master@sjzsdyn.com
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China
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2809
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CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
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+86-022-83726202 18222223751
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022-83726200
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sales@chinatechem.com
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China
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Heynova (Shanghai) New Material Technology CO., Ltd
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17821102608
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horea@heynovachem.com
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China
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LinkChem Technology Co., Ltd.
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+86(21)5895 0110 13124863828
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sales@linkchem.cn
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China
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Chengdu Yuanda chemical co.,ltd
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028-85356300 18980937689
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+86-28-85356300
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chenquanxing@126.com
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China
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J & K SCIENTIFIC LTD.
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18210857532; 18210857532
Fax
86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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View Lastest Price from 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride manufacturers

Yurui(Shanghai) Chemical Co. Ltd
Product
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride 4415-87-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1kg 25kg 50kg 100kg 1000kg
Release date
2025-11-28
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Product
1,2,3,4-Cyclobutanetetracarboxylic1,2,3,4-dianhydride (CBDA) 4415-87-6
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
≥99.5%
Supply Ability
1MT
Release date
2025-10-27
Changsha YuTeng New Materials Co., Ltd.
Product
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride 4415-87-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1ton
Release date
2025-08-28

4415-87-6, 1,2,3,4-Cyclobutanetetracarboxylic DianhydrideRelated Search:


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  • C8H4O6
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  • monomer