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Cyclobutane-1,2,3,4-tetracarboxylic dianhydride

Product Name
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
CAS No.
4415-87-6
Chemical Name
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
Synonyms
1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE;Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride;-tetraone;Maleic anhydride cyclic dimer.;Cyclobutane-1,2,3,4-tetracarboxylic;Cyclobutanetetracarboxylic Dianhydride;1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&;Cyclobutanetetracarboxylic acid dianhydride;1,2,3,4-butanetetracarboxylicdianhydride(CBDA);CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE
CBNumber
CB6718246
Molecular Formula
C8H4O6
Formula Weight
196.11
MOL File
4415-87-6.mol
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Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Property

Melting point:
>300 °C (lit.)
Boiling point:
545.3±50.0 °C(Predicted)
Density 
1.823±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
soluble in Toluene
form 
powder to crystal
color 
White to Light yellow
BRN 
1430553
CAS DataBase Reference
4415-87-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
1759
WGK Germany 
3
9-21
HazardClass 
8
PackingGroup 
III
HS Code 
29172090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
161330
Product name
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
Purity
≥94%
Packaging
5g
Price
$229
Updated
2024/03/01
TCI Chemical
Product number
C2262
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
Purity
>98.0%(T)
Packaging
1g
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
C2262
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride
Purity
>98.0%(T)
Packaging
5g
Price
$200
Updated
2024/03/01
TCI Chemical
Product number
C2842
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
Purity
>98.0%(T)
Packaging
1g
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
C2842
Product name
1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
Purity
>98.0%(T)
Packaging
5g
Price
$202
Updated
2024/03/01
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Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Chemical Properties,Usage,Production

Chemical Properties

White to light yellow solid

Uses

cyclobutane-1,2,3,4-tetracarboxylic dianhydride and diamine monomer are used for preparation a polyimide (PI), the type of polyimide has excellent electrical characteristics and optical type, with the material prepared the PI film, in addition to having a higher rate cast visible outside, and can withstand high temperatures thirty-four Baidu. Its performance is very good, is the preparation of a liquid crystal display with an ideal material for the film.

Uses

Reactant for:

  • Preparation of biologically and pharmacologically active molecules
  • Preparation of photosensitive polyimide material for high performance organic thin-film transistors
  • Selective crosslinking of polyimide for photonic devices

Preparation

Preparation of 1,2,3,4- cyclobutanetetracarboxylic acid dianhydride (CBDA)To a 2L quartz glass photoreactor equipped with sixteen UV lamps (300nm) , a stirrer and a cooler were attached and 250ml of ethyl acetate and 100g of maleic anhydride were added thereto followed by stirring for complete mixing. To avoid an excessive temperature increase, an air-cooling type cooler was first run and then UV light was illuminated for a photoreaction for 24h with stirring so as not to have the reactants adhered to the reactor walls. As a result, 71g of white solid was obtained. After the filtration, the white solid was dried for 24h in a vacuum dryer at 60°C Thus-obtained solid was then added to acetic anhydride, dissolved therein and slowly heated to 150°C followed by the reaction for 24h . Hot reaction solution was filtered through a filter paper to remove impurities and kept in a freezer at the temperature of 0°C or less for recrystallization for 24h to obtain a yellow solid. Thus-obtained solid was filtered and washed three times with 1,4-dioxane to remove acetic anhydride, and then dried in a vacuum oven at 60°C for 48h to obtain 64g of 1, 2, 3, 4 -cyclobutane tetracarboxylic acid dianhydride (CBDA) .

Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Suppliers

Shenzhen Feiming Science and Technology Co.,Ltd.
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0755-85232577
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+86-755-84594577
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sale@fmect.com
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China
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Sino-Biochemical Laboratory Co., Ltd.
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21-21-31590156 13042155638
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+86 21 31590152
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sales@sino-biochemlab.com
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Shaoxing Shunbang Medical Technology Co. LTD
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13355710117
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J & K SCIENTIFIC LTD.
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86-10-82849933
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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TCI (Shanghai) Development Co., Ltd.
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BeiJing Hwrk Chemicals Limted
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View Lastest Price from Cyclobutane-1,2,3,4-tetracarboxylic dianhydride manufacturers

Henan Fengda Chemical Co., Ltd
Product
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride 4415-87-6
Price
US $111.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-08
Hebei Duling International Trade Co. LTD
Product
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride 4415-87-6
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000 tons
Release date
2022-12-06
Hebei Yanxi Chemical Co., Ltd.
Product
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride 4415-87-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2023-03-09

4415-87-6, Cyclobutane-1,2,3,4-tetracarboxylic dianhydrideRelated Search:


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  • C8H4O6
  • Organic Building Blocks
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  • Fluorenes, etc. (reagent for high-performance polymer research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • Carbonyl Compounds
  • Carboxylic Acid Anhydrides
  • Organic Building Blocks
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, Organic Building Blocks
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, pharmaceutical intermediates
  • monomer