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1-Chloro-2-methylpropane

Product Name
1-Chloro-2-methylpropane
CAS No.
513-36-0
Chemical Name
1-Chloro-2-methylpropane
Synonyms
ISOBUTYL CHLORIDE;2-Chloromethylpropane;iso-C4H9Cl;Chloroisobutane;Isobutylchlorid;1-CHLOROISOBUTANE;iso-Chloro-butane;Chloro-2-Methylprop;1-Chlor-2-methylpropan;CHLORO-2-METHYLPROPANE
CBNumber
CB0477314
Molecular Formula
C4H9Cl
Formula Weight
92.57
MOL File
513-36-0.mol
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1-Chloro-2-methylpropane Property

Melting point:
-131 °C (lit.)
Boiling point:
68-69 °C (lit.)
Density 
0.883 g/mL at 25 °C (lit.)
vapor pressure 
161 hPa (20 °C)
refractive index 
n20/D 1.398(lit.)
Flash point:
70 °F
storage temp. 
2-8°C
solubility 
H2O: insoluble
form 
Liquid
color 
Colorless to Almost colorless
explosive limit
2.0-8.8%(V)
Water Solubility 
28 mg/l (20 ºC)
Merck 
14,5138
BRN 
635650
Dielectric constant
7.1(20℃)
InChI
1S/C4H9Cl/c1-4(2)3-5/h4H,3H2,1-2H3
InChIKey
QTBFPMKWQKYFLR-UHFFFAOYSA-N
SMILES
CC(C)CCl
Surface tension
22.31mN/m at 293.15K
CAS DataBase Reference
513-36-0(CAS DataBase Reference)
NIST Chemistry Reference
Propane, 1-chloro-2-methyl-(513-36-0)
EPA Substance Registry System
Propane, 1-chloro-2-methyl- (513-36-0)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16-9-33-29
RIDADR 
UN 1127 3/PG 2
WGK Germany 
3
Autoignition Temperature
395 °C
TSCA 
TSCA listed
HazardClass 
3
PackingGroup 
II
HS Code 
29031990
Storage Class
3 - Flammable liquids
Hazard Classifications
Flam. Liq. 2
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20314
Product name
1-Chloro-2-methylpropane
Purity
for synthesis
Packaging
50mL
Price
$49.2
Updated
2025/07/31
Sigma-Aldrich
Product number
8.20314
Product name
1-Chloro-2-methylpropane
Purity
for synthesis
Packaging
250ML
Price
$110
Updated
2025/07/31
Sigma-Aldrich
Product number
178004
Product name
1-Chloro-2-methylpropane
Purity
98%
Packaging
100ml
Price
$103.01
Updated
2025/07/31
Sigma-Aldrich
Product number
178004
Product name
1-Chloro-2-methylpropane
Purity
98%
Packaging
500ml
Price
$167.3
Updated
2025/07/31
TCI Chemical
Product number
C0207
Product name
1-Chloro-2-methylpropane
Purity
>98.0%(GC)
Packaging
25mL
Price
$31
Updated
2025/07/31
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1-Chloro-2-methylpropane Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

1-Chloro-2-methylpropane is used to prepare an organometllic compound, isobutyllithium by reacting with lithium using petroleum ether as a solvent.

General Description

The gas-solid virial co-effiicent of 1-chloro-2-methylpropane was determined. The infrared and Raman spectra of 1-chloro-2-methylpropane was studied.

Synthesis

1) After adding a quantity of sulfoxide chloride to a 250mL three-necked flask, add a small amount of pyridine and keep the reaction at a constant temperature. . (2) Add a quantity of isobutanol to a dropping funnel, adjust the piston so that it is dropped drop by drop into the sulfoxide-pyridine mixture with stirring, the reaction off-gas is absorbed with a dilute solution of NaOH, and the reaction time is recorded at the end of the drop. (3) After the reaction is completed, take the upper layer of the clear liquid by alkali washing, water washing, drying, distillation, collect the 68-72 ?? fraction, calculate the yield of chlorinated isobutane.

Purification Methods

Use the same methods as described under isoamyl chloride.[Beilstein 1 IV 287.]

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1-Chloro-2-methylpropane Suppliers

Shanghai Kaisai Chemical Co., Ltd
Tel
021-33516722 13701817765
Fax
021-33516776
Email
kaisaichem@163.com
Country
China
ProdList
4609
Advantage
58
Lianyungang Xuanyuan Chemical Co., Ltd
Tel
0518-85415818; 18000194506
Email
2818153737@qq.com
Country
China
ProdList
48
Advantage
58
Nanyang Runhong Pharmaceutical Technology Co., Ltd
Tel
17637776888
Email
17637776888@163.com
Country
China
ProdList
23
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9309
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
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View Lastest Price from 1-Chloro-2-methylpropane manufacturers

Yancheng Longshen Chemical Co.,Ltd.
Product
1-Chloro-2-methylpropane;Isobutyl chloride 513-36-0
Price
US $0.00/KG
Min. Order
1KG
Purity
≥99%
Supply Ability
60 Tons/Month
Release date
2026-01-24
Hebei Chuanghai Biotechnology Co., Ltd
Product
1-Chloro-2-methylpropane 513-36-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-12-04
Hebei Yanxi Chemical Co., Ltd.
Product
1-Chloro-2-methylpropane 513-36-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2023-09-08

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