Chlorocyclohexane
- Product Name
- Chlorocyclohexane
- CAS No.
- 542-18-7
- Chemical Name
- Chlorocyclohexane
- Synonyms
- CC;CYCLOHEXYL CHLORIDE;Cyclohexylchlorid;IL8RA;IL8R2;CDw128b);Chlorcyclohexan;CHLOROCYCLOHEXANE;CHLORHEXAMETHYLENE;3-chloro-cyclohexen
- CBNumber
- CB4483443
- Molecular Formula
- C6H11Cl
- Formula Weight
- 118.6
- MOL File
- 542-18-7.mol
Chlorocyclohexane Property
- Melting point:
- -44 °C (lit.)
- Boiling point:
- 142 °C (lit.)
- Density
- 1 g/mL at 25 °C (lit.)
- vapor pressure
- 7 hPa (20 °C)
- refractive index
- n20/D 1.462(lit.)
- Flash point:
- 84 °F
- storage temp.
- Store below +30°C.
- solubility
- 0.40g/l
- form
- Liquid
- color
- Clear
- explosive limit
- 1.1-7.5%(V)
- Water Solubility
- 0.02 g/L (20 ºC)
- Merck
- 14,2732
- BRN
- 1900796
- Dielectric constant
- 7.6（24℃）
- InChI
- 1S/C6H11Cl/c7-6-4-2-1-3-5-6/h6H,1-5H2
- InChIKey
- UNFUYWDGSFDHCW-UHFFFAOYSA-N
- SMILES
- ClC1CCCCC1
- CAS DataBase Reference
- 542-18-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclohexane, chloro-(542-18-7)
- EPA Substance Registry System
- Cyclohexane, chloro- (542-18-7)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 10-36/37/38-20
- Safety Statements
- 26-36-37/39-16
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 1
- RTECS
- GU8685000
- Autoignition Temperature
- 290 °C
- TSCA
- TSCA listed
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29035990
- Storage Class
- 3 - Flammable liquids
- Hazard Classifications
- Aquatic Chronic 2
Flam. Liq. 3 - Hazardous Substances Data
- 542-18-7(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 3000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
N-Bromosuccinimide Price
- Product number
- C105058
- Product name
- Chlorocyclohexane
- Purity
- 99%
- Packaging
- 100g
- Price
- $42.4
- Updated
- 2025/07/31
- Product number
- 8.20287
- Product name
- Chlorocyclohexane
- Purity
- for synthesis
- Packaging
- 250ML
- Price
- $47.9
- Updated
- 2025/07/31
- Product number
- 8.20287
- Product name
- Chlorocyclohexane
- Purity
- for synthesis
- Packaging
- 1L
- Price
- $124
- Updated
- 2025/07/31
- Product number
- C0153
- Product name
- Chlorocyclohexane
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $22
- Updated
- 2025/07/31
- Product number
- C0153
- Product name
- Chlorocyclohexane
- Purity
- >98.0%(GC)
- Packaging
- 500mL
- Price
- $58
- Updated
- 2025/07/31
Chlorocyclohexane Chemical Properties,Usage,Production
Chemical Properties
clear liquid
Uses
Chlorocyclohexane is used as the raw material in synthesis agrochemical and medicine chemical engineering products.
Definition
ChEBI: A chlorocyclohexane carrying a single chloro group.
Synthesis Reference(s)
Journal of the American Chemical Society, 101, p. 3060, 1979 DOI: 10.1021/ja00505a038
Journal of the American Chemical Society, 97, p. 2281, 1975 DOI: 10.1021/ja00841a054
Tetrahedron, 44, p. 2785, 1988 DOI: 10.1016/S0040-4020(88)90014-2
Synthesis
Take 158g of cyclohexane and add it to a four-necked flask equipped with a stirrer, a thermometer, a reflux condenser and a chlorine tube, add 0.1g of composite catalyst, place the four-necked flask in the dark, turn on the stirrer and rotate it at 100 rpm, heat it up to 60??C, and pass the chlorine gas at a rate of 0.05l/min and maintain it for 10-20min; then reduce the temperature to 40??C and increase the rate of chlorine gas passing to make 50g of chlorine gas within 4 hours. so that 50g of chlorine gas was passed in 4 hours. After the reaction material was neutralized with sodium carbonate and washed with water, it was first distilled at atmospheric pressure to obtain 101.5g of unreacted cyclohexane for the next synthesis, and then the 81-85?? fraction was collected under the vacuum degree of 0.08MPa to obtain 68.2g of chlorinated cyclohexane, and the product was analyzed by gas chromatography of HP6890 with the content of 99.65%, the cyclohexane one-way conversion rate of 35.8%, the selectivity of 88.9%, the yield of 85.5% and the yield of 85.5%. The product was analyzed by HP6890 gas chromatography, the content was 99.65%, the one-way conversion of cyclohexane was 35.8%, the selectivity was 88.9% and the yield was 85.5%.
Purification Methods
Wash chlorocyclohexane several times with dilute NaHCO3, then repeatedly with distilled water. Dry it with CaCl2 and fractionally distil it slowly at atmospheric pressure or better under vacuum. [Perlman et al. J Org Chem 1 294 1937, IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 H 21, 5 I 8, 5 II 11, 5 III 37, 5 IV 48.]
Chlorocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Chlorocyclohexane manufacturers
- Product
- Chlorocyclohexane;Cyclohexyl chloride 542-18-7
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- ≥99%
- Supply Ability
- 40 Tons/Month
- Release date
- 2026-01-26
- Product
- Chlorocyclohexane 542-18-7
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5tons
- Release date
- 2024-12-03
- Product
- Chlorocyclohexane 542-18-7
- Price
- US $0.00/KG
- Min. Order
- 5KG
- Purity
- 99%
- Supply Ability
- 500MT/Month
- Release date
- 2024-04-15