Bromocyclohexane
- Product Name
- Bromocyclohexane
- CAS No.
- 108-85-0
- Chemical Name
- Bromocyclohexane
- Synonyms
- CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;1-Bromocyclohexane;Cyelohexyl bromide;Cyclohexane,bromo-;Bromocyclohexane>
- CBNumber
- CB0234782
- Molecular Formula
- C6H11Br
- Formula Weight
- 163.06
- MOL File
- 108-85-0.mol
Bromocyclohexane Property
- Melting point:
- -57°C
- Boiling point:
- 166-167 °C (lit.)
- Density
- 1.324 g/mL at 25 °C (lit.)
- vapor density
- 5.62 (vs air)
- refractive index
- n20/D 1.495(lit.)
- Flash point:
- 145 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
- form
- Liquid
- Specific Gravity
- approximate 1.33 (20℃)
- color
- Clear colorless to light yellow
- Odor
- Unpleasant Odor
- Water Solubility
- insoluble
- Sensitive
- Air & Light Sensitive
- Merck
- 14,2730
- BRN
- 1098373
- Dielectric constant
- 7.9（25℃）
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
- InChIKey
- AQNQQHJNRPDOQV-UHFFFAOYSA-N
- CAS DataBase Reference
- 108-85-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclohexane, bromo-(108-85-0)
- EPA Substance Registry System
- Cyclohexane, bromo- (108-85-0)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-20-18-52
- Safety Statements
- 23-24/25-37/39-26
- WGK Germany
- 3
- RTECS
- GU7171700
- F
- 8
- TSCA
- Yes
- HS Code
- 29035990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 135194
- Product name
- Bromocyclohexane
- Purity
- 98%
- Packaging
- 5g
- Price
- $23
- Updated
- 2024/03/01
- Product number
- 135194
- Product name
- Bromocyclohexane
- Purity
- 98%
- Packaging
- 1kg
- Price
- $178
- Updated
- 2024/03/01
- Product number
- B0581
- Product name
- Bromocyclohexane
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $18
- Updated
- 2024/03/01
- Product number
- B0581
- Product name
- Bromocyclohexane
- Purity
- >98.0%(GC)
- Packaging
- 100g
- Price
- $30
- Updated
- 2024/03/01
- Product number
- A11593
- Product name
- Bromocyclohexane, 98%
- Packaging
- 100g
- Price
- $27.65
- Updated
- 2024/03/01
Bromocyclohexane Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
Preparation
Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.
Synthesis Reference(s)
Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General Description
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Purification Methods
Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]
Bromocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bromocyclohexane manufacturers
- Product
- Bromocyclohexane 108-85-0
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99.8%
- Supply Ability
- 10000ton
- Release date
- 2024-04-25
- Product
- Bromocyclohexane 108-85-0
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
- Product
- Bromocyclohexane 108-85-0
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99.9（%）
- Supply Ability
- 30 tons
- Release date
- 2024-03-12