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Bromocyclohexane

Product Name
Bromocyclohexane
CAS No.
108-85-0
Chemical Name
Bromocyclohexane
Synonyms
CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;1-Bromocyclohexane;Cyelohexyl bromide;Cyclohexane,bromo-;Bromocyclohexane>
CBNumber
CB0234782
Molecular Formula
C6H11Br
Formula Weight
163.06
MOL File
108-85-0.mol
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Bromocyclohexane Property

Melting point:
-57°C
Boiling point:
166-167 °C (lit.)
Density 
1.324 g/mL at 25 °C (lit.)
vapor density 
5.62 (vs air)
refractive index 
n20/D 1.495(lit.)
Flash point:
145 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
form 
Liquid
Specific Gravity
approximate 1.33 (20℃)
color 
Clear colorless to light yellow
Odor
Unpleasant Odor
Water Solubility 
insoluble
Sensitive 
Air & Light Sensitive
Merck 
14,2730
BRN 
1098373
Dielectric constant
7.9(25℃)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChIKey
AQNQQHJNRPDOQV-UHFFFAOYSA-N
CAS DataBase Reference
108-85-0(CAS DataBase Reference)
NIST Chemistry Reference
Cyclohexane, bromo-(108-85-0)
EPA Substance Registry System
Cyclohexane, bromo- (108-85-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-20-18-52
Safety Statements 
23-24/25-37/39-26
WGK Germany 
3
RTECS 
GU7171700
8
TSCA 
Yes
HS Code 
29035990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
135194
Product name
Bromocyclohexane
Purity
98%
Packaging
5g
Price
$23
Updated
2024/03/01
Sigma-Aldrich
Product number
135194
Product name
Bromocyclohexane
Purity
98%
Packaging
1kg
Price
$178
Updated
2024/03/01
TCI Chemical
Product number
B0581
Product name
Bromocyclohexane
Purity
>98.0%(GC)
Packaging
25g
Price
$18
Updated
2024/03/01
TCI Chemical
Product number
B0581
Product name
Bromocyclohexane
Purity
>98.0%(GC)
Packaging
100g
Price
$30
Updated
2024/03/01
Alfa Aesar
Product number
A11593
Product name
Bromocyclohexane, 98%
Packaging
100g
Price
$27.65
Updated
2024/03/01
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Bromocyclohexane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

Preparation

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

Synthesis Reference(s)

Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020

General Description

Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods

Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

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Bromocyclohexane Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
ecochem international chemical broker
Tel
--
Fax
--
Email
export@ecochem.dk
Country
Europe
ProdList
6371
Advantage
66
kemikalieimport
Tel
--
Fax
--
Email
Sales@kemikalieimport.dk
Country
Europe
ProdList
6685
Advantage
47
Camida
Tel
--
Fax
--
Email
info@camida.com
Country
Europe
ProdList
3704
Advantage
71
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View Lastest Price from Bromocyclohexane manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
CYCLOHEXYL BROMIDE 108-85-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-05
Hebei Yanxi Chemical Co., Ltd.
Product
Bromocyclohexane 108-85-0
Price
US $50.00/kg
Min. Order
1kg
Purity
99.9(%)
Supply Ability
30 tons
Release date
2024-03-12
Hebei Chuanghai Biotechnology Co,.LTD
Product
Bromocyclohexane 108-85-0
Price
US $10.70/KG
Min. Order
10KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20

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