1,1'-Bis(di-tert-butylphosphino)ferrocene

Reaction

Product Name: 1,1'-Bis(di-tert-butylphosphino)ferrocene
CAS No.: 84680-95-5
Chemical Name: 1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms: DTBPF;DBtPF;98% DtBPF;DTBPF ChemBeads;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-t-butylphosphino)ferrocene;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-Bis(di-tert-butylphosphino)ferrocene
CBNumber: CB3689138
Molecular Formula: C26H44FeP210*
Formula Weight: 474.42
MOL File: 84680-95-5.mol

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1,1'-Bis(di-tert-butylphosphino)ferrocene Property

Melting point:: 181-182°C (dec.)
storage temp.: Inert atmosphere,Room Temperature
form: crystal
color: orange to red
Water Solubility: Insoluble in water.
InChI: InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;
InChIKey: FPLSJBJGQLJLSV-UHFFFAOYSA-N
SMILES: P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27|

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-24/25-36/37/39-26
WGK Germany: 3
TSCA: No
HS Code: 29319090
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 695149
Product name: 1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging: 1g
Price: $176
Updated: 2025/07/31

Sigma-Aldrich

Product number: 695149
Product name: 1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging: 250mg
Price: $93.8
Updated: 2023/06/20

TCI Chemical

Product number: B2711
Product name: 1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity: >95.0%(T)
Packaging: 1g
Price: $124
Updated: 2025/07/31

TCI Chemical

Product number: B2711
Product name: 1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity: >95.0%(T)
Packaging: 100mg
Price: $23
Updated: 2025/07/31

Strem Chemicals

Product number: 26-0150
Product name: 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF
Packaging: 500mg
Price: $51
Updated: 2024/03/01

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1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

Chemical Properties

1,1'-Bis(di-tert-butylphosphino)ferrocene has good stability and reactivity and can participate in a variety of organometallic catalytic reactions, such as diene complex formation, carbonyl insertion, addition, reduction and deoxygenation reactions.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

1,1'-Bis(di-tert-butylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Bromocyclohexane 2-Butanol Ferrocene Hexane Di-tert-butylchlorophosphane N,N,N',N'-Tetramethylethylenediamine 2-Chloro-2-methylpropane 2,2'-Bipyridine Cinchonidine Phosphorus trichloride Tetrahydrofuran Ethyl acetate Dichloromethane Magnesium n-Butyllithium

Preparation Products

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1,1'-Bis(di-tert-butylphosphino)ferrocene Suppliers

Americas 1 China 229 Europe 2 Germany 3 India 4 Japan 2 Norway 1 Russia 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 4 United States 16 Global 266

Puyang Huicheng Electronic Material Co. Ltd.

Tel: 0393-0393-8910800 15039333257
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Email: info@huichengchem.com
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Xinxiang Runyu Material Co., Ltd.

Tel: 166-166-37336996 15690792173
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Henan Research New Material Co., Ltd.

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Sinocompound Catalysts Co., Ltd.

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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Beijing Donghualituo Techonlogy Development Co.,Ltd.

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INTATRADE GmbH

Tel: +49 3493/605464
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Country: Germany
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View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-11

Henan Research New Materials Co., Ltd.

Product: 1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price: US $0.00/g
Min. Order: 500g
Purity: 98％
Supply Ability: 10
Release date: 2024-07-18

Shaanxi Dideu New Materials Co. Ltd

Product: 1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-11

84680-95-5, 1,1'-Bis(di-tert-butylphosphino)ferroceneRelated Search:

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE TERT-BUTYLDIISOPROPYLPHOSPHINE 1,1'-Bis(di-tert-butylphosphino)ferrocene Ferrocene T-BUTYLPHOSPHINE 1,1''-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORI 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE DI-T-BUTYL(I-PROPYL)PHOSPHINE 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Di-tert-butylphosphine TRIISOPROPYLPHOSPHINE

BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON

1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%

1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%

1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%

1,1'-Bis(di-tert-butylphosphin

98% DtBPF

1,1'-Bis(di-tert-butylphosphiNA)ferrocene

1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98%

1,1'-Bis(di-t-butylphosphino)ferrocene,98% DtBPF

DBtPF

1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF

DTBPF

1,1'-Bis(di-tert-butylphosphi

1,1'-Bis(di-t-butylphosphino)ferrocene,DtBPF

DTBPF / 1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene 98%

1,1'-Bis(di-tert-butylphosphino)ferrocene &gt

1,1'-Bis(di-t-butyL

Dehch（bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate）

1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene

1,1'-Bis(di-t-butylphosphino)ferrocene

DTBPF ChemBeads

1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene

84680-95-5

94680-95-5

C26H42FeP2

C26H44FeP2

C4H92PC5H42Fe

2C13H22PFe

C26H44FeP210

2C13H23PFe

Metallocenes

Transition Metal Compounds

Phosphine Ligands

Classes of Metal Compounds

Ferrocenes

Fe (Iron) Compounds

Achiral Phosphine

Aryl Phosphine

Classes of Metal Compounds

Fe (Iron) Compounds

Ferrocenes

Metallocenes

Phosphine Ligands

Synthetic Organic Chemistry

Transition Metal Compounds

Catalysis and Inorganic Chemistry

Phosphorus Compounds

Polydentate Phosphine Ligands