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ChemicalBook > CAS DataBase List > 1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene

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Product Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
CAS No.
84680-95-5
Chemical Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms
DTBPF;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;DBtPF;98% DtBPF;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE;1,1'-Bis(di-tert-butylphosphino)ferrocene
CBNumber
CB3689138
Molecular Formula
C26H44FeP210*
Formula Weight
474.42
MOL File
84680-95-5.mol
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1,1'-Bis(di-tert-butylphosphino)ferrocene Property

Melting point:
181-182°C (dec.)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
orange to red
Water Solubility 
Insoluble in water.
InChIKey
FPLSJBJGQLJLSV-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36/37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
1g
Price
$171
Updated
2024/03/01
Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
250mg
Price
$93.8
Updated
2023/06/20
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
1g
Price
$124
Updated
2024/03/01
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
100mg
Price
$23
Updated
2024/03/01
Alfa Aesar
Product number
L19759
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%
Packaging
500mg
Price
$65.2
Updated
2021/12/16
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1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

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1,1'-Bis(di-tert-butylphosphino)ferrocene Suppliers

Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-8910800 18790963537
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
549
Advantage
64
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
441
Advantage
55
He' nan ruisiqi new material co., ltd
Tel
18903931628
Email
researchvip@163.com
Country
China
ProdList
214
Advantage
58
Entegris, Inc.
Tel
021-52980362 18121213678
Email
jenny.ji@entegris.com
Country
China
ProdList
101
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
950
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
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View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price
US $100.00-30.00/kg
Min. Order
1kg
Purity
99.93%
Supply Ability
1000kg per week
Release date
2024-04-28
Hebei Mojin Biotechnology Co., Ltd
Product
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-27
XINXIANG RUNYU MATERIAL CO., LTD.
Product
1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
500kg
Release date
2021-11-29

84680-95-5, 1,1'-Bis(di-tert-butylphosphino)ferroceneRelated Search:


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  • 84680-95-5
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  • C26H42FeP2
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  • C4H92PC5H42Fe
  • 2C13H22PFe
  • C26H44FeP210
  • 2C13H23PFe
  • Metallocenes
  • Transition Metal Compounds
  • Phosphine Ligands
  • Classes of Metal Compounds
  • Ferrocenes
  • Fe (Iron) Compounds
  • Achiral Phosphine
  • Aryl Phosphine
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands