Reaction
ChemicalBook > CAS DataBase List > 1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene

Reaction
Product Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
CAS No.
84680-95-5
Chemical Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms
DTBPF;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;DBtPF;98% DtBPF;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-t-butylphosphino)ferrocene;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
CBNumber
CB3689138
Molecular Formula
C26H44FeP210*
Formula Weight
474.42
MOL File
84680-95-5.mol
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1,1'-Bis(di-tert-butylphosphino)ferrocene Property

Melting point:
181-182°C (dec.)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
orange to red
Water Solubility 
Insoluble in water.
InChI
InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;
InChIKey
FPLSJBJGQLJLSV-UHFFFAOYSA-N
SMILES
P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27|
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36/37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
1g
Price
$171
Updated
2024/03/01
Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
250mg
Price
$93.8
Updated
2023/06/20
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
1g
Price
$124
Updated
2024/03/01
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
100mg
Price
$23
Updated
2024/03/01
Alfa Aesar
Product number
L19759
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%
Packaging
500mg
Price
$65.2
Updated
2021/12/16
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1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

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1,1'-Bis(di-tert-butylphosphino)ferrocene Suppliers

Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-0393-8910800 15036113989
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
564
Advantage
64
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
299
Advantage
55
Henan Research New Material Co., Ltd.
Tel
1890-3931531 18903931628
Email
sales036@researchvip.com
Country
China
ProdList
183
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
954
Advantage
55
BeiJing Greenchem Technology Co.,Ltd.
Tel
131-21959385 15640741633
Fax
010-62925455
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
269
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58
Sinocompound Catalysts Co., Ltd.
Tel
0512-67216630 67216634
Fax
0512-56316689
Email
sales@sinocompound.com
Country
China
ProdList
280
Advantage
64
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
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View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Henan Research New Materials Co., Ltd.
Product
1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price
US $0.00/g
Min. Order
500g
Purity
98%
Supply Ability
10
Release date
2024-07-18
XINXIANG RUNYU MATERIAL CO., LTD.
Product
1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
500kg
Release date
2021-11-29
Hebei Weibang Biotechnology Co., Ltd
Product
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-11

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  • Metallocenes
  • Transition Metal Compounds
  • Phosphine Ligands
  • Classes of Metal Compounds
  • Ferrocenes
  • Fe (Iron) Compounds
  • Achiral Phosphine
  • Aryl Phosphine
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands