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ChemicalBook > CAS DataBase List > 1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene

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Product Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
CAS No.
84680-95-5
Chemical Name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms
DTBPF;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;DBtPF;98% DtBPF;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE;1,1'-Bis(di-tert-butylphosphino)ferrocene
CBNumber
CB3689138
Molecular Formula
C26H44FeP210*
Formula Weight
474.42
MOL File
84680-95-5.mol
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1,1'-Bis(di-tert-butylphosphino)ferrocene Property

Melting point:
181-182°C (dec.)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
orange to red
Water Solubility 
Insoluble in water.
InChIKey
FPLSJBJGQLJLSV-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36/37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
1g
Price
$171
Updated
2024/03/01
Sigma-Aldrich
Product number
695149
Product name
1,1′-Bis(di-tert-butylphosphino)ferrocene
Packaging
250mg
Price
$93.8
Updated
2023/06/20
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
1g
Price
$124
Updated
2024/03/01
TCI Chemical
Product number
B2711
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene
Purity
>95.0%(T)
Packaging
100mg
Price
$23
Updated
2024/03/01
Alfa Aesar
Product number
L19759
Product name
1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%
Packaging
500mg
Price
$65.2
Updated
2021/12/16
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1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

1,1'-Bis(di-tert-butylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Bromocyclohexane 2-Butanol Ferrocene Hexane Di-tert-butylchlorophosphane N,N,N',N'-Tetramethylethylenediamine 2-Chloro-2-methylpropane 2,2'-Bipyridine Cinchonidine Phosphorus trichloride Tetrahydrofuran Ethyl acetate Dichloromethane Magnesium n-Butyllithium

Preparation Products

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1,1'-Bis(di-tert-butylphosphino)ferrocene Suppliers

Americas 1 China 211 Europe 2 Germany 3 India 4 Japan 2 Norway 1 Russia 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 4 United States 15 Global 247
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View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
1,1'-Bis(di-tert-butylphosphino)ferrocene 84680-95-5
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2020-01-14
Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price
US $100.00-30.00/kg
Min. Order
1kg
Purity
99.93%
Supply Ability
1000kg per week
Release date
2024-04-28
Hebei Mojin Biotechnology Co., Ltd
Product
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 84680-95-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-27

84680-95-5, 1,1'-Bis(di-tert-butylphosphino)ferroceneRelated Search:

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE TERT-BUTYLDIISOPROPYLPHOSPHINE 1,1'-Bis(di-tert-butylphosphino)ferrocene Ferrocene T-BUTYLPHOSPHINE 1,1''-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORI 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE DI-T-BUTYL(I-PROPYL)PHOSPHINE 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Di-tert-butylphosphine TRIISOPROPYLPHOSPHINE

  • BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON
  • 1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%
  • 1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE
  • 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%
  • 1,1'-Bis(di-tert-butylphosphin
  • 98% DtBPF
  • 1,1'-Bis(di-tert-butylphosphiNA)ferrocene
  • 1,1'-Bis[bis(1,1-diMethylethyl)phosphino]ferrocene
  • 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98%
  • 1,1'-Bis(di-t-butylphosphino)ferrocene,98% DtBPF
  • DBtPF
  • 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF
  • DTBPF
  • 1,1'-Bis(di-tert-butylphosphi
  • 1,1'-Bis(di-t-butylphosphino)ferrocene,DtBPF
  • DTBPF / 1,1'-Bis(di-tert-butylphosphino)ferrocene
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene 98%
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene &gt
  • 1,1'-Bis(di-t-butyL
  • Dehch（bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate）
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene
  • 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene
  • 84680-95-5
  • 94680-95-5
  • C26H42FeP2
  • C26H44FeP2
  • C4H92PC5H42Fe
  • 2C13H22PFe
  • C26H44FeP210
  • 2C13H23PFe
  • Metallocenes
  • Transition Metal Compounds
  • Phosphine Ligands
  • Classes of Metal Compounds
  • Ferrocenes
  • Fe (Iron) Compounds
  • Achiral Phosphine
  • Aryl Phosphine
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands