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Di-tert-butylchlorophosphane

Product Name
Di-tert-butylchlorophosphane
CAS No.
13716-10-4
Chemical Name
Di-tert-butylchlorophosphane
Synonyms
DI-TERT-BUTYLCHLOROPHOSPHINE;Chlorodi-tert-butylphosphine;Di-t-butyL;AURORA KA-1319;(tert-C4H9)2PCl;98% [(CH3)3C]2PCl;DI-TERT-BUTYLCHLOROPHO;Phosphonous dichloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHOSPHANE
CBNumber
CB2200163
Molecular Formula
C8H18ClP
Formula Weight
180.66
MOL File
13716-10-4.mol
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Di-tert-butylchlorophosphane Property

Melting point:
2-3°C
Boiling point:
48 °C/3 mmHg (lit.)
Density 
0.951 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.482(lit.)
Flash point:
142 °F
solubility 
Miscible with terahydrofuran.
form 
Liquid
Specific Gravity
0.951
color 
Clear colorless
Sensitive 
Air & Moisture Sensitive
InChIKey
MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference
13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference
Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-25
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301558
Product name
Di-tert-butylchlorophosphine
Purity
96%
Packaging
5g
Price
$113
Updated
2024/03/01
Sigma-Aldrich
Product number
301558
Product name
Di-tert-butylchlorophosphine
Purity
96%
Packaging
25g
Price
$441
Updated
2024/03/01
TCI Chemical
Product number
D3632
Product name
Di-tert-butylchlorophosphine
Purity
>95.0%(GC)
Packaging
5g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
D3632
Product name
Di-tert-butylchlorophosphine
Purity
>95.0%(GC)
Packaging
25g
Price
$244
Updated
2024/03/01
Alfa Aesar
Product number
B20998
Product name
Di-tert-butylchlorophosphine, 96%
Packaging
5g
Price
$118
Updated
2024/03/01
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Di-tert-butylchlorophosphane Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.

Uses

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Application

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Precautions

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Di-tert-butylchlorophosphane Preparation Products And Raw materials

Raw materials

Nitrogen tert-Butyllithium 2-Chloro-2-methylpropane Sodium Pentane Phosphorus trichloride Tetrahydrofuran Magnesium

Preparation Products

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1'-Bis(di-tert-butylphosphino)ferrocene DI-T-BUTYLMETHYLPHOSPHINE 1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&
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Di-tert-butylchlorophosphane Suppliers

Americas 1 Austria 1 Belgium 4 Canada 1 China 180 Europe 2 France 2 Germany 9 India 6 Japan 6 Norway 1 Russia 1 Slovakia 3 South Korea 1 Switzerland 3 The Netherlands 1 United Kingdom 10 United States 46 Global 278
He' nan ruisiqi new material co., ltd
Tel
18903931628
Email
researchvip@163.com
Country
China
ProdList
215
Advantage
58
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
391
Advantage
55
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-8910800 18236056670
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
549
Advantage
64
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
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View Lastest Price from Di-tert-butylchlorophosphane manufacturers

Shanghai UCHEM Inc.
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $85.00-515.00/g
Min. Order
25g
Purity
0.96
Supply Ability
25kg
Release date
2023-12-21
Hebei Yanxi Chemical Co., Ltd.
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $10.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-26
Hebei Mojin Biotechnology Co., Ltd
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-11-10

13716-10-4, Di-tert-butylchlorophosphaneRelated Search:

DI-T-BUTYLPHOSPHINE OXIDE 2-Di-t-butylphosphino-4-Methoxy-3,5,6-triMethyl-2',4',6'-tri-i-propylbiphenyl, Min. 98% [~1:1 Mixture with regioisoMer, 2-Di-t-butylphosphino-5-Methoxy-3,4,6-triMethyl-2',4',6'-tri-i-propylbiphenyl] Lithium Aluminum Hydride Tetrakis(hydroxymethyl)phosphonium sulfate T-BUTYLPHOSPHINE DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DI-1-ADAMANTYLPHOSPHINIC CHLORIDE DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX Di-tert-butylchlorophosphane DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER AURORA KA-1706 DICHLORO(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DIMER AURORA KA-1182

  • AURORA KA-1319
  • Bis(1,1-dimethylethyl)-phosphinous chloride
  • DI-T-BUTYLCHLOROPHOSPHINE
  • DI-T-BUTYLPHOSPHINOUS CHLORIDE
  • DI-TERT-BUTYLPHOSPHORUS CHLORIDE
  • DI-TERT-BUTYLCHLOROPHOSPHANE
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  • (tert-C4H9)2PCl
  • Chlorodi-tert-butylphosphine
  • Di-tert-Butylphosphinous chloride
  • Phosphinous chloride, di-tert-butyl-
  • DI-TERT-BUTYLCHLOROPHOSPHINE (DTBCP)
  • Di-t-butylchlorophosphine,min.98%
  • Phosphonous dichloride
  • Di-tert-B-butylchlorophosphine, 96%
  • Di-t-butylchlorophosphine, min. 98%
  • Di-tert-butylchlorophosphine,96%
  • Phosphonous Dichloride, Bis[1,1-dimethylethyl]-
  • Di-t-butylchlorophosphine, 98+%
  • Di-tert-butylchlorophosphine, 96% 25ML
  • 98% [(CH3)3C]2PCl
  • Di-tert-butylchlorophosphine, 96%, AcroSeal
  • Di-tert-butylchlorophosphine, AcroSeal, 96%
  • Di-tert-butylchlorophosphanec
  • Di-tert-butylchlorophosphine 96%
  • Di-t-butylchlorophosphine,98% [(CH3)3C]2PCl
  • Di-tert-butylchlorophosphane Bis(1,1-dimethylethyl)-phosphinous chloride
  • Di-tert-butylchlorophosphine&gt
  • Di-t-butyL
  • Phosphinous chloride, P,P-bis(1,1-dimethylethyl)-
  • Di-tert-butylchlorophosphine, 96%, AcroSeal&trade
  • 13716-10-4
  • 13716-01-4
  • CH33C2PCl
  • C8H18ClP
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • organophosphine halide
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • Phosphines
  • Ligand
  • Chlorophosphines
  • Achiral Phosphine
  • Alkyl Phosphine
  • P-Cl