ChemicalBook > CAS DataBase List > Di-tert-butylchlorophosphane

Di-tert-butylchlorophosphane

Product Name
Di-tert-butylchlorophosphane
CAS No.
13716-10-4
Chemical Name
Di-tert-butylchlorophosphane
Synonyms
DI-TERT-BUTYLCHLOROPHOSPHINE;Chlorodi-tert-butylphosphine;Di-t-butyL;AURORA KA-1319;(tert-C4H9)2PCl;98% [(CH3)3C]2PCl;DI-TERT-BUTYLCHLOROPHO;Phosphonous dichloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHOSPHANE
CBNumber
CB2200163
Molecular Formula
C8H18ClP
Formula Weight
180.66
MOL File
13716-10-4.mol
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Di-tert-butylchlorophosphane Property

Melting point:
2-3°C
Boiling point:
48 °C/3 mmHg (lit.)
Density 
0.951 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.482(lit.)
Flash point:
142 °F
solubility 
Miscible with terahydrofuran.
form 
Liquid
Specific Gravity
0.951
color 
Clear colorless
Sensitive 
Air & Moisture Sensitive
InChIKey
MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference
13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference
Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-25
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301558
Product name
Di-tert-butylchlorophosphine
Purity
96%
Packaging
5g
Price
$113
Updated
2024/03/01
Sigma-Aldrich
Product number
301558
Product name
Di-tert-butylchlorophosphine
Purity
96%
Packaging
25g
Price
$441
Updated
2024/03/01
TCI Chemical
Product number
D3632
Product name
Di-tert-butylchlorophosphine
Purity
>95.0%(GC)
Packaging
5g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
D3632
Product name
Di-tert-butylchlorophosphine
Purity
>95.0%(GC)
Packaging
25g
Price
$244
Updated
2024/03/01
Alfa Aesar
Product number
B20998
Product name
Di-tert-butylchlorophosphine, 96%
Packaging
5g
Price
$118
Updated
2024/03/01
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Di-tert-butylchlorophosphane Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.

Uses

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Application

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Precautions

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Di-tert-butylchlorophosphane Preparation Products And Raw materials

Raw materials

Nitrogen tert-Butyllithium 2-Chloro-2-methylpropane Sodium Pentane Phosphorus trichloride Tetrahydrofuran Magnesium

Preparation Products

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1'-Bis(di-tert-butylphosphino)ferrocene DI-T-BUTYLMETHYLPHOSPHINE 1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&
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View Lastest Price from Di-tert-butylchlorophosphane manufacturers

Shanghai UCHEM Inc.
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $85.00-515.00/g
Min. Order
25g
Purity
0.96
Supply Ability
25kg
Release date
2023-12-21
Hebei Yanxi Chemical Co., Ltd.
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $10.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-26
Hebei Mojin Biotechnology Co., Ltd
Product
Di-tert-butylchlorophosphane 13716-10-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-11-10

13716-10-4, Di-tert-butylchlorophosphaneRelated Search:

DI-T-BUTYLPHOSPHINE OXIDE 2-Di-t-butylphosphino-4-Methoxy-3,5,6-triMethyl-2',4',6'-tri-i-propylbiphenyl, Min. 98% [~1:1 Mixture with regioisoMer, 2-Di-t-butylphosphino-5-Methoxy-3,4,6-triMethyl-2',4',6'-tri-i-propylbiphenyl] Lithium Aluminum Hydride Tetrakis(hydroxymethyl)phosphonium sulfate T-BUTYLPHOSPHINE DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DI-1-ADAMANTYLPHOSPHINIC CHLORIDE DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX Di-tert-butylchlorophosphane DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER AURORA KA-1706 DICHLORO(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DIMER AURORA KA-1182

  • AURORA KA-1319
  • Bis(1,1-dimethylethyl)-phosphinous chloride
  • DI-T-BUTYLCHLOROPHOSPHINE
  • DI-T-BUTYLPHOSPHINOUS CHLORIDE
  • DI-TERT-BUTYLPHOSPHORUS CHLORIDE
  • DI-TERT-BUTYLCHLOROPHOSPHANE
  • DI-TERT-BUTYLCHLOROPHOSPHINE
  • DI-TERT-BUTYLCHLOROPHO
  • (tert-C4H9)2PCl
  • Chlorodi-tert-butylphosphine
  • Di-tert-Butylphosphinous chloride
  • Phosphinous chloride, di-tert-butyl-
  • DI-TERT-BUTYLCHLOROPHOSPHINE (DTBCP)
  • Di-t-butylchlorophosphine,min.98%
  • Phosphonous dichloride
  • Di-tert-B-butylchlorophosphine, 96%
  • Di-t-butylchlorophosphine, min. 98%
  • Di-tert-butylchlorophosphine,96%
  • Phosphonous Dichloride, Bis[1,1-dimethylethyl]-
  • Di-t-butylchlorophosphine, 98+%
  • Di-tert-butylchlorophosphine, 96% 25ML
  • 98% [(CH3)3C]2PCl
  • Di-tert-butylchlorophosphine, 96%, AcroSeal
  • Di-tert-butylchlorophosphine, AcroSeal, 96%
  • Di-tert-butylchlorophosphanec
  • Di-tert-butylchlorophosphine 96%
  • Di-t-butylchlorophosphine,98% [(CH3)3C]2PCl
  • Di-tert-butylchlorophosphane Bis(1,1-dimethylethyl)-phosphinous chloride
  • Di-tert-butylchlorophosphine&gt
  • Di-t-butyL
  • Phosphinous chloride, P,P-bis(1,1-dimethylethyl)-
  • Di-tert-butylchlorophosphine, 96%, AcroSeal&trade
  • 13716-10-4
  • 13716-01-4
  • CH33C2PCl
  • C8H18ClP
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • organophosphine halide
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • Phosphines
  • Ligand
  • Chlorophosphines
  • Achiral Phosphine
  • Alkyl Phosphine
  • P-Cl