BENZYLOXYACETONE
- Product Name
- BENZYLOXYACETONE
- CAS No.
- 22539-93-1
- Chemical Name
- BENZYLOXYACETONE
- Synonyms
- BENZYLOXYACETONE;1-(Benzyloxy)acetone;Benzyloxyacetone 90%;3-benzyloxypropanone;1-BENZYLOXY-2-PROPANONE;1-(Benzyloxy)propan-2-one;1-(Benzyloxy)propane-2-one;1-phenylmethoxypropan-2-one;1-phenylmethoxy-2-propanone;2-Propanone, 1-(phenylMethoxy)-
- CBNumber
- CB6736228
- Molecular Formula
- C10H12O2
- Formula Weight
- 164.2
- MOL File
- 22539-93-1.mol
BENZYLOXYACETONE Property
- Boiling point:
- 259 °C (lit.)
- Density
- 1.04 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.512(lit.)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,Room Temperature
- Appearance
- Colorless to light yellow Liquid
- InChI
- InChI=1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3
- InChIKey
- YHMRKVGUSQWDGZ-UHFFFAOYSA-N
- SMILES
- C(OCC1=CC=CC=C1)C(=O)C
Safety
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 489174
- Product name
- Benzyloxyacetone
- Purity
- 90%
- Packaging
- 5g
- Price
- $196
- Updated
- 2025/07/31
- Product number
- B289158
- Product name
- 1-(Benzyloxy)propan-2-one
- Packaging
- 500mg
- Price
- $155
- Updated
- 2021/12/16
- Product number
- 1360AB
- Product name
- 1-(Benzyloxy)propan-2-one
- Packaging
- 25g
- Price
- $1072
- Updated
- 2021/12/16
- Product number
- CHM0156481
- Product name
- BENZYLOXYACETONE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $938.28
- Updated
- 2021/12/16
- Product number
- 143289
- Product name
- 1-(Benzyloxy)propan-2-one
- Purity
- 97%
- Packaging
- 1g
- Price
- $240
- Updated
- 2021/12/16
BENZYLOXYACETONE Chemical Properties,Usage,Production
Uses
Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:
- 7-benzyloxy-6-methyl-5-hepten-1-yne
- (Z)-2-methylhept-2-en-6-yn-1-o1
- (S)-(+)-1,2-propanediol, 1-benzyl ether
General Description
Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.
Synthesis
14593-43-2
22539-93-1
To a stirred mixed solution of allyl benzyl ether (0.4 mmol) in acetonitrile (3.5 mL) and water (0.5 mL) was added palladium dichloride (PdCl2, 3.6 mg, 0.02 mmol, 5 mol%) and chromium trioxide (CrO3, 20 mg, 0.6 mmol, 0.5 eq.), in that order, at room temperature. The reaction mixture was heated to 60°C and stirred in a closed flask for the indicated time (refer to Table 5-7). Upon completion of the reaction, the mixture was filtered through a small silica gel pad and washed with ethyl acetate (EtOAc), followed by concentration of the filtrate. In some cases, the residue is almost pure in the residue and no further purification is required. In the remaining cases, the residue needs to be purified by silica gel column chromatography using petroleum ether/ethyl acetate (EtOAc) as eluent to finally obtain benzyloxyacetone.
References
[1] Tetrahedron, 2014, vol. 70, # 32, p. 4760 - 4767
[2] Journal of Organic Chemistry, 2016, vol. 81, # 5, p. 2113 - 2121
[3] Journal of Organic Chemistry, 2014, vol. 79, # 12, p. 5787 - 5793
[4] Tetrahedron Letters, 2013, vol. 54, # 19, p. 2293 - 2295
[5] Tetrahedron Letters, 2009, vol. 50, # 24, p. 2893 - 2894
BENZYLOXYACETONE Preparation Products And Raw materials
Raw materials
Preparation Products
BENZYLOXYACETONE Suppliers
- Tel
- 181-3307-5798 18017383231
- 983544897@qq.com
- Country
- China
- ProdList
- 921
- Advantage
- 58
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- +86057186818502 13588463833
- Fax
- Pls mail us for more information!
- info@sagechem.com
- Country
- China
- ProdList
- 10266
- Advantage
- 58
- Tel
- 19916721580
- Fax
- QQ：3154870176
- mafarm@126.com
- Country
- China
- ProdList
- 4542
- Advantage
- 58
- Tel
- 025-66028182 18626450290
- yftan@aikonchem.com
- Country
- China
- ProdList
- 16679
- Advantage
- 50
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51395
- Advantage
- 80
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 71826
- Advantage
- 60
- Tel
- 4009903999 13395398332
- Fax
- 0539-6365991
- sales@xiyashiji.com
- Country
- China
- ProdList
- 20794
- Advantage
- 60
View Lastest Price from BENZYLOXYACETONE manufacturers
- Product
- BENZYLOXYACETONE 22539-93-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 0.1kg
- Purity
- 98
- Supply Ability
- 100kg
- Release date
- 2023-02-28