2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
- Product Name
- 2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
- CAS No.
- 1479-22-7
- Chemical Name
- 2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
- Synonyms
- Ethyl 2-fluoro-3-oxo-3-phenylpropanoate;2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER;Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester;Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester;R,S-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester;(R,S)-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester
- CBNumber
- CB6744898
- Molecular Formula
- C11H11FO3
- Formula Weight
- 210.2
- MOL File
- 1479-22-7.mol
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Property
- Melting point:
- 33-35 °C
- Boiling point:
- 116°C 0,3mm
- Density
- 1.169±0.06 g/cm3(Predicted)
- pka
- 8.20±0.26(Predicted)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- E900075
- Product name
- Ethyl2-Benzoyl-2-fluoroacetate
- Packaging
- 10g
- Price
- $1230
- Updated
- 2021/12/16
- Product number
- HCH0142396
- Product name
- 2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
- Purity
- 97.00%
- Packaging
- 25G
- Price
- $1645.88
- Updated
- 2021/12/16
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Chemical Properties,Usage,Production
Uses
Ethyl 2-Benzoyl-2-fluoroacetate is used in the chemoselective preparation of α-chloro- and α-fluoro-β-keto esters by chlorination or fluorination with N-chlorosuccinimide or Selectfluor in the presence of titanium catalysts such as (cyclopentadienyl)titanium trichloride.
Synthesis Reference(s)
The Journal of Organic Chemistry, 56, p. 273, 1991 DOI: 10.1021/jo00001a052
Tetrahedron Letters, 37, p. 653, 1996 DOI: 10.1016/0040-4039(95)02224-4
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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