2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER

Product Name
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
CAS No.
1479-22-7
Chemical Name
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
Synonyms
Ethyl 2-fluoro-3-oxo-3-phenylpropanoate;2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER;Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester;Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester;R,S-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester;(R,S)-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester
CBNumber
CB6744898
Molecular Formula
C11H11FO3
Formula Weight
210.2
MOL File
1479-22-7.mol
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2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Property

Melting point:
33-35 °C
Boiling point:
116°C 0,3mm
Density 
1.169±0.06 g/cm3(Predicted)
pka
8.20±0.26(Predicted)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
E900075
Product name
Ethyl2-Benzoyl-2-fluoroacetate
Packaging
10g
Price
$1230
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0142396
Product name
2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
Purity
97.00%
Packaging
25G
Price
$1645.88
Updated
2021/12/16
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2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Chemical Properties,Usage,Production

Uses

Ethyl 2-Benzoyl-2-fluoroacetate is used in the chemoselective preparation of α-chloro- and α-fluoro-β-keto esters by chlorination or fluorination with N-chlorosuccinimide or Selectfluor in the presence of titanium catalysts such as (cyclopentadienyl)titanium trichloride.

Synthesis Reference(s)

The Journal of Organic Chemistry, 56, p. 273, 1991 DOI: 10.1021/jo00001a052
Tetrahedron Letters, 37, p. 653, 1996 DOI: 10.1016/0040-4039(95)02224-4

2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER Suppliers

Shanghai Qiao Chemical Science Co., Ltd
Tel
021-58892003
Email
info@qiaochem.com
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China
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5902
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JinJin Le Chemical Co., Ltd
Tel
10106090
Email
jjlchem2@163.com
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China
ProdList
9981
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Jiangsu aikang biomedical research and development co., LTD
Tel
025-66110311 13155353615
Email
qzhang@aikonchem.com
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China
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15527
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Shanghai Haohong Pharmaceutical Co., Ltd.
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4008210725 4008210725
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malulu@leyan.com
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China
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54986
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Energy Chemical
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021-58432009 400-005-6266
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021-58436166
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marketing@energy-chemical.com
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China
ProdList
44918
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TCI (Shanghai) Chemical Trading Co., Ltd.
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021-021-61109150
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021-61105897
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sales@tcisct.com
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China
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31121
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Shaanxi Dideu Medichem Co. Ltd
Tel
029-61856358 15229202216
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029-88380327
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1020@dideu.com
Country
China
ProdList
10011
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1479-22-7, 2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTERRelated Search:


  • (R,S)-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester
  • R,S-2-Fluoro-3-oxo-3-phenyl-propionicacidethylester
  • 2-FLUORO-3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER
  • Ethyl 2-fluoro-3-oxo-3-phenylpropanoate
  • Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester
  • Benzenepropanoic acid, α-fluoro-β-oxo-, ethyl ester
  • 1479-22-7