ChemicalBook > CAS DataBase List > Z-GLN(TRT)-OH

Z-GLN(TRT)-OH

Product Name
Z-GLN(TRT)-OH
CAS No.
132388-60-4
Chemical Name
Z-GLN(TRT)-OH
Synonyms
Z-GLN(TRT)-OH;CBZ-GLN(TRT)-OH;Z-L-Gln(Trt)-OH;Cbz-L-Gln(Trt)-OH;Z-GLUTAMINE(TRT)-OH;Z-L-GLUTAMINE (TRITYL);CBZ-L-GLUTAMINE(TRITYL);Z-GLN(TRT)-OH USP/EP/BP;Nα-Z-Nδ-trityl-L-glutamine;N-Cbz-N'-trityl-L-glutamine
CBNumber
CB6776543
Molecular Formula
C32H30N2O5
Formula Weight
522.59
MOL File
132388-60-4.mol
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Z-GLN(TRT)-OH Property

Boiling point:
792.6±60.0 °C(Predicted)
Density 
1.237±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form 
Solid
pka
3.82±0.10(Predicted)
Appearance
White to off-white Solid
CAS DataBase Reference
132388-60-4(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
G410195
Product name
Z-Gln(trt)-oh
Packaging
500mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
093522
Product name
N-Cbz-N'-trityl-L-glutamine
Purity
95+%
Packaging
1g
Price
$68
Updated
2021/12/16
AK Scientific
Product number
J97342
Product name
Z-Gln(Trt)-OH
Packaging
250mg
Price
$10
Updated
2021/12/16
Chem-Impex
Product number
03846
Product name
Nα-Z-Nδ-trityl-L-glutamine,99.5%(ChiralHPLC)
Purity
99.5%(ChiralHPLC)
Packaging
1G
Price
$16.8
Updated
2021/12/16
AK Scientific
Product number
X6687
Product name
Z-Gln(Trt)-OH
Packaging
10g
Price
$129
Updated
2021/12/16
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Z-GLN(TRT)-OH Chemical Properties,Usage,Production

Chemical Properties

White powder

Synthesis

76-84-6

2650-64-8

132388-60-4

Acetic anhydride (7.50 mL, 80.00 mmol) and concentrated sulfuric acid were added to glacial acetic acid (120 mL) as (S)-5-amino-2-(((benzyloxy)carbonyl)amino)-5-oxopentanoic acid (11.20 g, 40.00 mmol) and triphenylmethanol (20.80 g, 80.00 mmol). The mixture was stirred in an ice bath and then gradually warmed up to 50 °C for 2 hours of reaction. Upon completion of the reaction, the reaction mixture was slowly poured into ice (800 g) and a white precipitate precipitated. The precipitate was collected by filtration and redissolved in ethyl acetate (600 mL). The resulting solution was washed sequentially with water (3 x 200 mL), dried over anhydrous sodium sulfate, filtered and concentrated. Finally, the white solid N-Cbz-N'-trityl-L-glutamine (14.70 g, 70% yield) was obtained by solvent crystallization from ethyl acetate/petroleum ether mixture.

References

[1] Journal of the American Chemical Society, 2013, vol. 135, # 35, p. 12998 - 13007
[2] Journal of Peptide Science, 2010, vol. 16, # 7, p. 364 - 374
[3] Journal of Medicinal Chemistry, 1998, vol. 41, # 15, p. 2786 - 2805
[4] Synthetic Communications, 2017, vol. 47, # 12, p. 1136 - 1141
[5] Tetrahedron Letters, 1991, vol. 32, # 6, p. 739 - 742

Z-GLN(TRT)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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Z-GLN(TRT)-OH Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
GL Biochem (Shanghai) Ltd
Tel
21-61263452 13641803416
Fax
86-21-61263399
Email
ymbetter@glbiochem.com
Country
China
ProdList
9981
Advantage
64
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
15402
Advantage
60
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11705
Advantage
57
ChemPep, Inc.
Tel
+1 (888) 615-9178 / (561) 791-8787
Fax
+1 (561) 791-8728
Email
service@chempep.com
Country
United States
ProdList
2138
Advantage
57
T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
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View Lastest Price from Z-GLN(TRT)-OH manufacturers

Career Henan Chemical Co
Product
Z-GLN(TRT)-OH 132388-60-4
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2018-08-15
Career Henan Chemical Co
Product
Z-GLN(TRT)-OH 132388-60-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20kg
Release date
2018-08-15

132388-60-4, Z-GLN(TRT)-OHRelated Search:


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  • N-ALPHA-CBZ-GAMMA-TRITYL-L-GLUTAMINE
  • Z-GLN(TRT)-OH
  • Z-GLUTAMINE(TRT)-OH
  • Z-N-DELTA-TRITYL-L-GLUTAMINE
  • Z-L-GLUTAMINE (TRITYL)
  • CBZ-GLN(TRT)-OH
  • CBZ-L-GLUTAMINE(TRITYL)
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  • Cbz-L-Gln(Trt)-OH
  • Nα-Z-Nδ-trityl-L-glutamine≥ 99% (HPLC)
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  • N^a-Benzyloxycarbonyl-N^d-trityl-L-glutamine,98%
  • (2S)-5-oxo-2-(phenylmethoxycarbonylamino)-5-(tritylamino)pentanoicaci
  • Z-GLN(TRT)-OH USP/EP/BP
  • Nα-Z-Nδ-trityl-L-glutamine
  • (2S)-5-oxo-2-(phenylmethoxycarbonylamino)-5-(tritylamino)pentanoic acid
  • N-α-Cbz-N-δ-trityl-L-glutamine
  • N^a-Benzyloxycarbonyl-N^d-trityl-L-glutamine
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  • 32388-60-4
  • Glutamine [Gln, Q]
  • Z-Amino Acids and Derivatives
  • Z-Amino acid series