ChemicalBook > CAS DataBase List > Z-GLN(TRT)-OH

Z-GLN(TRT)-OH

Product Name: Z-GLN(TRT)-OH
CAS No.: 132388-60-4
Chemical Name: Z-GLN(TRT)-OH
Synonyms: Z-GLN(TRT)-OH;CBZ-GLN(TRT)-OH;Z-L-Gln(Trt)-OH;Cbz-L-Gln(Trt)-OH;Z-GLUTAMINE(TRT)-OH;Z-L-GLUTAMINE (TRITYL);CBZ-L-GLUTAMINE(TRITYL);Z-GLN(TRT)-OH USP/EP/BP;Nα-Z-Nδ-trityl-L-glutamine;N-Cbz-N'-trityl-L-glutamine
CBNumber: CB6776543
Molecular Formula: C32H30N2O5
Formula Weight: 522.59
MOL File: 132388-60-4.mol

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Z-GLN(TRT)-OH Property

Boiling point:: 792.6±60.0 °C(Predicted)
Density: 1.237±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form: Solid
pka: 3.82±0.10(Predicted)
Appearance: White to off-white Solid
CAS DataBase Reference: 132388-60-4(CAS DataBase Reference)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: G410195
Product name: Z-Gln(trt)-oh
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 093522
Product name: N-Cbz-N'-trityl-L-glutamine
Purity: 95+%
Packaging: 1g
Price: $68
Updated: 2021/12/16

AK Scientific

Product number: J97342
Product name: Z-Gln(Trt)-OH
Packaging: 250mg
Price: $10
Updated: 2021/12/16

Chem-Impex

Product number: 03846
Product name: Nα-Z-Nδ-trityl-L-glutamine,99.5%(ChiralHPLC)
Purity: 99.5%(ChiralHPLC)
Packaging: 1G
Price: $16.8
Updated: 2021/12/16

AK Scientific

Product number: X6687
Product name: Z-Gln(Trt)-OH
Packaging: 10g
Price: $129
Updated: 2021/12/16

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Z-GLN(TRT)-OH Chemical Properties,Usage,Production

Chemical Properties

White powder

Synthesis

76-84-6

2650-64-8

132388-60-4

Acetic anhydride (7.50 mL, 80.00 mmol) and concentrated sulfuric acid were added to glacial acetic acid (120 mL) as (S)-5-amino-2-(((benzyloxy)carbonyl)amino)-5-oxopentanoic acid (11.20 g, 40.00 mmol) and triphenylmethanol (20.80 g, 80.00 mmol). The mixture was stirred in an ice bath and then gradually warmed up to 50 °C for 2 hours of reaction. Upon completion of the reaction, the reaction mixture was slowly poured into ice (800 g) and a white precipitate precipitated. The precipitate was collected by filtration and redissolved in ethyl acetate (600 mL). The resulting solution was washed sequentially with water (3 x 200 mL), dried over anhydrous sodium sulfate, filtered and concentrated. Finally, the white solid N-Cbz-N'-trityl-L-glutamine (14.70 g, 70% yield) was obtained by solvent crystallization from ethyl acetate/petroleum ether mixture.

References

[1] Journal of the American Chemical Society, 2013, vol. 135, # 35, p. 12998 - 13007
[2] Journal of Peptide Science, 2010, vol. 16, # 7, p. 364 - 374
[3] Journal of Medicinal Chemistry, 1998, vol. 41, # 15, p. 2786 - 2805
[4] Synthetic Communications, 2017, vol. 47, # 12, p. 1136 - 1141
[5] Tetrahedron Letters, 1991, vol. 32, # 6, p. 739 - 742

Z-GLN(TRT)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Z-GLN(TRT)-OH manufacturers

Career Henan Chemical Co

Product: Z-GLN(TRT)-OH 132388-60-4
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2018-08-15

Career Henan Chemical Co

Product: Z-GLN(TRT)-OH 132388-60-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20kg
Release date: 2018-08-15

132388-60-4, Z-GLN(TRT)-OHRelated Search:

N-Carbobenzyloxy-L-glutamine Z-GLN-OSU Z-GLN-GLY-OH Z-GLN-OME Z-GLN-ONP (S)-2-Benzyloxycarbonylamino-pentanedioic acid 5-benzyl ester Z-GLN(MTT)-OH Z-ORN-OH H-GLN(TRT)-OH,H-L-Gln(Trt)-OH (R)-(+)-N-ACETYL-1-METHYLBENZYLAMINE Z-GLN(TRT)-OH FMOC-BETA-GLN(TRT)-OH BOC-GLN(TRT)-OH FMOC-D-GLN(TRT)-OH FMOC-GLN(TRT)-OH 98.5+%,FMOC-N-TRITYL-L-GLUTAMINE (FMOC-L-GLN(TRT)-OH),FMOC-GLN(TRT)-OH,FMOC-L-GLN(TRT)-OH TRT-GLN(TRT)-OH DEA AC-GLN(TRT)-OH Z-D-GLN(TRT)-OH

N-ALPHA-CARBOBENZOXY-N-GAMMA-TRITYL-L-GLUTAMINE

N-ALPHA-CBZ-GAMMA-TRITYL-L-GLUTAMINE

Z-GLN(TRT)-OH

Z-GLUTAMINE(TRT)-OH

Z-N-DELTA-TRITYL-L-GLUTAMINE

Z-L-GLUTAMINE (TRITYL)

CBZ-GLN(TRT)-OH

CBZ-L-GLUTAMINE(TRITYL)

N-.ALPHA.-CBZ-N-.DELTA.-TRITYL-L-GLUTAMINE

N-Carbobenzyloxy-N-γ-trityl-L-glutamine

(S)-2-(Benzyloxycarbonylamino)-5-oxo-5-(tritylamino)pentanoic acid

N-Cbz-N'-trityl-L-glutamine

N-α-Z-N-δ-trityl-L-glutamine

(2S)-2-{[(benzyloxy)carbonyl]amino}-4-[(triphenylmethyl)carbamoyl]butanoic acid

5-amino-5-oxo-2-[phenylmethoxycarbonyl-(triphenylmethyl)amino]pentanoic acid

Z-L-Gln(Trt)-OH

N^a-Benzyloxycarbonyl-N^d-trityl-L-glutaMine, 98%

Cbz-L-Gln(Trt)-OH

Nα-Z-Nδ-trityl-L-glutamine≥ 99% (HPLC)

Nalpha-Benzyloxycarbonyl-Ndelta-trityl-L-glutamine

L-Glutamine, N2-[(phenylmethoxy)carbonyl]-N-(triphenylmethyl)-

N^a-Benzyloxycarbonyl-N^d-trityl-L-glutamine,98%

(2S)-5-oxo-2-(phenylmethoxycarbonylamino)-5-(tritylamino)pentanoicaci

Z-GLN(TRT)-OH USP/EP/BP

Nα-Z-Nδ-trityl-L-glutamine

(2S)-5-oxo-2-(phenylmethoxycarbonylamino)-5-(tritylamino)pentanoic acid

N-α-Cbz-N-δ-trityl-L-glutamine

N^a-Benzyloxycarbonyl-N^d-trityl-L-glutamine

132388-60-4

32388-60-4

Glutamine [Gln, Q]

Z-Amino Acids and Derivatives

Z-Amino acid series