(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
- Product Name
- (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
- CAS No.
- 866100-14-3
- Chemical Name
- (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid
- Synonyms
- (9,9-Dimethyl-9H-flu;9,9-dimethyl-2,7-diboronic acid;9,9-Dimethyl-2,7-fluorenediboronicacid;9,9-diMethyl-9H-fluorene-2,7-diyldiboronic acid;(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid;Boronicacid,(9,9-dimethyl-9H-fluorene-2,7-diyl)b;(9,9-diMethyl-9H-fluoren-2,7-diyl)bisboronic acid;(9,9-dimethyl-9H-fluorene-2,7-diyl)bisboronic acid;9,9-Dimethyl-9H-fluoren-2,7-diyl-2,7-diboronic acid;(9,9-DIMETHYL-9H-FLUOROENE-2,7-DIYL)BISBORONIC ACID
- CBNumber
- CB6812405
- Molecular Formula
- C15H16B2O4
- Formula Weight
- 281.91
- MOL File
- 866100-14-3.mol
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Property
- storage temp.
- Store at room temperature
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2931900090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D4701
- Product name
- (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1G
- Price
- $136
- Updated
- 2025/07/31
- Product number
- D486780
- Product name
- (9,9-Dimethyl-9h-fluorene-2,7-diboronicacid
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- D486780
- Product name
- (9,9-Dimethyl-9h-fluorene-2,7-diboronicacid
- Packaging
- 500mg
- Price
- $115
- Updated
- 2021/12/16
- Product number
- 094305
- Product name
- (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic acid
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- CS-W000989
- Product name
- 9,9-Dimethylfluorene-2,7-diboronicacid
- Packaging
- 5g
- Price
- $210
- Updated
- 2021/12/16
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Chemical Properties,Usage,Production
Chemical Properties
Off-white powder
Synthesis
5419-55-6
28320-32-3
866100-14-3
The general procedure for the synthesis of 9,9-dimethylfluorene-2,7-diboronic acid from triisopropyl borate and 2,7-dibromo-9,9-dimethylfluorene was as follows: 2,7-dibromo-9,9-dimethylfluorene (14.8 g, 42.4 mmol) was placed in a three-necked flask, 100 mL of tetrahydrofuran (THF) was added, and the reaction was cooled under nitrogen protection to -78 °C and maintained for 30 min. Subsequently, 21 mL of n-butyllithium (2.5 M) solution was added slowly and reacted for 1 hour. Next, triisopropyl borate (14 g) was added and the reaction was continued at low temperature for 1 hour, after which it was gradually warmed to room temperature. After completion of the reaction, the pH was adjusted to 4-5 by adding 2 M hydrochloric acid to the reaction mixture. the aqueous layer was extracted with ethyl acetate, the organic layers were combined and dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give Intermediate A1 (9.5 g, 80% yield).
References
[1] Patent: CN106699780, 2017, A. Location in patent: Paragraph 0047; 0048; 0049; 0050
[2] Patent: US8058450, 2011, B2. Location in patent: Page/Page column 43-44
[3] Luminescence, 2015, vol. 30, # 5, p. 549 - 555
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
(9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid Suppliers
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- sales@ajchem.in
- Country
- India
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View Lastest Price from (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid manufacturers
- Product
- (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid 866100-14-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-04-07
- Product
- (9,9-Dimethyl-9H-fluoren-2,7-diyl)diboronic acid 866100-14-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-30
- Product
- (9,9-Dimethyl-9H-fluorene-2,7-diyl)diboronic acid 866100-14-3
- Price
- US $188.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-05