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(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE

Product Name
(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE
CAS No.
205877-26-5
Chemical Name
(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE
Synonyms
4-EthynyltriphenylaMine;4-Ethynyltriphenylamine>4-Ethynyltriphenylamine,97%;4-ethynyl-N,N-diphenylaniline;4-Diphenylaminophenylacetylene;(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE;4-Ethynyl-N,N-diphenyl-Benzenamine;BenzenaMine, 4-ethynyl-N,N-diphenyl-
CBNumber
CB6820914
Molecular Formula
C20H15N
Formula Weight
269.34
MOL File
205877-26-5.mol
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(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE Property

Melting point:
109.0 to 113.0 °C
Boiling point:
406.6±28.0 °C(Predicted)
Density 
1.15±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
form 
powder to crystal
pka
-4.36±0.30(Predicted)
color 
Light orange to Yellow to Green
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Safety

HS Code 
2921.49.5000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
E0894
Product name
4-Ethynyltriphenylamine
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$248
Updated
2025/07/31
TRC
Product number
E937635
Product name
4-Ethynyl-N,N-diphenylaniline
Packaging
100mg
Price
$90
Updated
2021/12/16
ChemScene
Product number
CS-0146642
Product name
4-Ethynyl-N,N-diphenylaniline
Purity
≥97.0%
Packaging
1g
Price
$79
Updated
2021/12/16
AK Scientific
Product number
6499AL
Product name
4-Ethynyltriphenylamine
Packaging
1g
Price
$266
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0125287
Product name
(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE
Purity
95.00%
Packaging
5MG
Price
$502.17
Updated
2021/12/16
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(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE Chemical Properties,Usage,Production

Synthesis

205877-25-4

205877-26-5

1.0 g (2.93 mmol) of Intermediate 6 (1) was dissolved in 10.0 mL of tetrahydrofuran (THF), and 14.64 mL (14.64 mmol) of 1.0 M tetrabutylammonium fluoride solution in THF was added slowly and dropwise at room temperature. The reaction mixture was stirred at room temperature for 5 hours. Upon completion of the reaction, 50 mL of distilled water was added and the organic layers were combined by extracting three times with 50 mL of dichloromethane. The organic layer was dried over anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent. The residue was separated and purified by silica gel column chromatography to afford 730 mg (2.78 mmol) of intermediate 6 (2) in 93% yield. The product was identified by LC-MS with molecular formula C20H15N and molecular ion peak (M+) m/z of 270.12.

References

[1] Tetrahedron Letters, 2010, vol. 51, # 6, p. 917 - 920
[2] Tetrahedron, 2010, vol. 66, # 29, p. 5479 - 5485
[3] RSC Advances, 2013, vol. 3, # 39, p. 17914 - 17917
[4] Organic Letters, 2012, vol. 14, # 15, p. 3970 - 3973
[5] Patent: US2013/292653, 2013, A1. Location in patent: Paragraph 0136-0137

(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-ETHYNYL-PHENYL)-DIPHENYL-AMINE Suppliers

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205877-26-5, (4-ETHYNYL-PHENYL)-DIPHENYL-AMINERelated Search:


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  • 4-Ethynyl-N,N-diphenyl-Benzenamine
  • 4-Ethynyltriphenylamine&gt
  • 4-Ethynyltriphenylamine,97%
  • 205877-26-5