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TERT-BUTYL 4-BROMOBENZYLCARBAMATE

Product Name
TERT-BUTYL 4-BROMOBENZYLCARBAMATE
CAS No.
68819-84-1
Chemical Name
TERT-BUTYL 4-BROMOBENZYLCARBAMATE
Synonyms
N-BOC-4-broMobenzylaMine;4-Bromo-N-BOC-benzylamine;TERT-BUTYL 4-BROMOBENZYLCARBAMATE;tert-Butyl 4-bromobenzylcarbamate 98%;tert-Butyl N-(4-bromobenzyl)carbamate;tert-butyl N-[(4-bromophenyl)methyl]carbamate;N-(4-Bromobenzyl)carbamic acid tert-butyl ester;(4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester;N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester
CBNumber
CB6838195
Molecular Formula
C12H16BrNO2
Formula Weight
286.16
MOL File
68819-84-1.mol
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TERT-BUTYL 4-BROMOBENZYLCARBAMATE Property

Melting point:
86-88℃
Boiling point:
374.3±25.0 °C(Predicted)
Density 
1.319±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
pka
12.05±0.46(Predicted)
color 
Off-white
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Safety

Hazard Codes 
Xn
Risk Statements 
22
HS Code 
2924297099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

TRC
Product number
B694555
Product name
tert-Butyl4-Bromobenzylcarbamate
Packaging
100mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB155794
Product name
tert-Butyl 4-bromobenzylcarbamate
Packaging
1g
Price
$80
Updated
2021/12/16
ChemScene
Product number
CS-W005364
Product name
tert-Butyl4-bromobenzylcarbamate
Purity
99.98%
Packaging
10g
Price
$110
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB155794
Product name
tert-Butyl 4-bromobenzylcarbamate
Packaging
2g
Price
$130
Updated
2021/12/16
Apolloscientific
Product number
OR315540
Product name
tert-Butyl4-bromobenzylcarbamate
Purity
98%
Packaging
5g
Price
$166
Updated
2021/12/16
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TERT-BUTYL 4-BROMOBENZYLCARBAMATE Chemical Properties,Usage,Production

Synthesis

Tert-Butyl 4-bromobenzylcarbamate is prepared by the reaction of di-tert-butyl dicarbonate and 4-bromobenzylamine hydrochloride. The specific synthesis steps are as follows:
To a stirred suspension of 4-bromo-benzylamine hydrochloride (968mg, 4.35mmol) and triethylamine (0.666ml, 4.79mmol) in chloroform (15ml) was added di-tert-butyldicarbonate (949mg, 4.35mmol). The resulting solution was stirred at ambient temperature for 2h and then diluted with DCM (40ml). The organic solution was washed sequentially with 10% aqueous citric acid (40ml) and brine (40ml). The organic phase was dried over anhydrous magnesium sulfate and the filtrate evaporated at reduced pressure to afford Tert-Butyl 4-bromobenzylcarbamate (1.23g, 99%). 1H NMR 7.48-7.43 (2H, m), 7.18 (2H, d, 8.4), 4.84 (1H, br s), 4.27 (2H, d, 5.7), 1.46 (9H, s).

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL 4-BROMOBENZYLCARBAMATE Suppliers

China 100 India 1 United Kingdom 2 United States 10 Global 113
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View Lastest Price from TERT-BUTYL 4-BROMOBENZYLCARBAMATE manufacturers

Career Henan Chemical Co
Product
TERT-BUTYL 4-BROMOBENZYLCARBAMATE 68819-84-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-02

68819-84-1, TERT-BUTYL 4-BROMOBENZYLCARBAMATERelated Search:

N-Boc-4-(Cyclopropylmethyl)piperazine 1-BOC-4-(1-PYRROLIDINYL)-3,6-DIHYDRO-2H-PYRIDINE 2(1H)-ISOQUINOLINECARBOXYLIC ACID, 3,4-DIHYDRO-7-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-, 1,1-DIMETHYLETHYL ESTER tert-butyl 4-(2-bromo-5-fluoropyridin-4-yl)-4-hydroxypiperidine-1-carboxylate 1-N-Boc-4-(Phenylamino)piperidine tert-butyl 4-(2-aminoethyl)-3,3-difluoropiperidine-1-carboxylate 4-(3-AMINO-PHENYL)-PIPERIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER 1-Boc-4-(2-hydroxyethyl)piperidine tert-butyl 4-(3-cyano-4-(methoxycarbonyl)phenyl)piperazine-1-carboxylate tert-butyl 5-tert-butylisoxazol-3-ylcarbamate 1-Piperazinecarboxylic acid, 4-[3-bromo-4-(methoxycarbonyl)phenyl]-, 1,1-dimethylethyl ester 5H-Pyrrolo[3,2-c]pyridine-5-carboxylic acid, 1,4,6,7-tetrahydro-4-oxo-2-(4-pyridinyl)-, 1,1-dimethylethyl ester INDEX NAME NOT YET ASSIGNED Pentanoic acid, 4,5-diamino-5-oxo-, 1,1-dimethylethyl ester Boc-4-Bromo-L-beta-phenylalanine Boc-4-Bromo-D-beta-phenylalanine (4-Bromophenyl)-tert-butoxycarbonylaminoacetic acid methyl ester (R,S)-Boc-3-amino-3-(4-bromophenyl)-propionic acid

  • TERT-BUTYL 4-BROMOBENZYLCARBAMATE
  • tert-Butyl 4-bromobenzylcarbamate 98%
  • Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester
  • (4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER
  • N-BOC-4-broMobenzylaMine
  • 4-Bromo-N-BOC-benzylamine
  • N-(4-Bromobenzyl)carbamic acid tert-butyl ester
  • tert-Butyl N-(4-bromobenzyl)carbamate
  • Carbamic acid, N-[(4-bromophenyl)methyl]-, 1,1-dimethylethyl ester
  • tert-butyl N-[(4-bromophenyl)methyl]carbamate
  • N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester
  • 68819-84-1
  • amine|alkyl bromide| carboxylic ester