ChemicalBook > CAS DataBase List > 2-isopropoxyaniline

2-isopropoxyaniline

Product Name
2-isopropoxyaniline
CAS No.
29026-74-2
Chemical Name
2-isopropoxyaniline
Synonyms
o-Ipa;o-Isopropoxyaniline;ANILINE, o-ISOPROPOXY-;2-(1-Methylethoxy)aniline;2-(propan-2-yloxy)aniline;2-(1-Methylethoxy)benzenamine;o-Izopropoksyanilina [Polish];Benzenamine, 2-(1-methylethoxy)-;(2-isopropoxyphenyl)amine sulfate;(2-isopropoxyphenyl)amine(SALTDATA: HCl)
CBNumber
CB6915021
Molecular Formula
C9H13NO
Formula Weight
151.21
MOL File
29026-74-2.mol
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2-isopropoxyaniline Property

Melting point:
139-141℃
Boiling point:
273.23°C (rough estimate)
Density 
1.0406 (rough estimate)
refractive index 
1.5380 (estimate)
storage temp. 
2-8°C(protect from light)
form 
solid
pka
5.17±0.10(Predicted)
Appearance
Brown to black Liquid
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Safety

HazardClass 
IRRITANT
HS Code 
2922290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Matrix Scientific
Product number
033964
Product name
2-Isopropoxy-phenylamine
Packaging
1g
Price
$73
Updated
2021/12/16
AK Scientific
Product number
W5162
Product name
2-Isopropoxyaniline
Packaging
5g
Price
$169
Updated
2021/12/16
Matrix Scientific
Product number
033964
Product name
2-Isopropoxy-phenylamine
Packaging
5g
Price
$235
Updated
2021/12/16
AK Scientific
Product number
W5162
Product name
2-Isopropoxyaniline
Packaging
25g
Price
$454
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0032774
Product name
(2-ISOPROPOXY PHENYL)AMINE
Purity
95.00%
Packaging
1G
Price
$765.23
Updated
2021/12/16
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2-isopropoxyaniline Chemical Properties,Usage,Production

Synthesis

38753-50-3

29026-74-2

General procedure for the synthesis of 2-(1-methylethoxy)aniline from 1-isopropoxy-2-nitrobenzene: The product of Example 242A (5.00 g, 27.5 mmol) was dissolved in methanol, 10% Pd/C catalyst was added, and the catalytic hydrogenation reaction was carried out under hydrogen pressure (60 psi). Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under reduced pressure to afford 3.75 g (90% yield) of the target product 2-(1-methylethoxy)aniline in the form of a brown oil. The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 1.35 (d, 6H, J = 6.1 Hz), 3.77 (br s, 2H), 4.52 (m, 1H), 6.75 (m, 4H); the mass spectrum (DCI/NH3) showed m/e 152 (M + H)+.

References

[1] Organic Letters, 2011, vol. 13, # 16, p. 4320 - 4323
[2] Patent: US2003/229094, 2003, A1. Location in patent: Page 107
[3] Patent: WO2005/113498, 2005, A1. Location in patent: Page/Page column 16
[4] Patent: WO2014/11973, 2014, A2. Location in patent: Paragraph 0157; 0161
[5] Bioorganic and medicinal chemistry, 2004, vol. 12, # 16, p. 4511 - 4532

2-isopropoxyaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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29026-74-2, 2-isopropoxyaniline Related Search:

1',3',3'-TRIMETHYLSPIRO-8-NITRO(2H-1-BENZOPYRAN)-2',2'-INDOLINE 1,3,3-Trimethylindolinonaphthospirooxazine 2-isopropoxyaniline 1 3-DIHYDRO-1 3 3-TRIMETHYLSPIRO(INDOLE& 2-O-(O-NITROPHENYL)-ALPHA-D-N-ACETYLNEURAMINIC ACID 2,2-DIMETHYL-2,3-DIHYDRO-1-BENZOFURAN-7-AMINE 4-[(4-METHYLPHENYL)SULFONYL]-3,4-DIHYDRO-2H-1,4-BENZOXAZINE-2-CARBOXYLIC ACID 5-CHLORO-1,3-DIHYDRO-1,3,3-TRIMETHYLSPIRO[2 H-INDOLE-2,3'-[3 H]NAPHTH[2,1-B][1,4]OXAZINE] 2-(2-NITRO-PHENOXY)-PROPIONIC ACID ETHYL ESTER ACTINOMYCIN I FROM STREPTOMYCESANTIBIOTI CUS BUTTPARK 7\07-43 (AMINOMETHYLAMINO)((2,2,7-TRIMETHYL(3-OXAINDAN-4-YL))AMINO)METHANE-1-THIONE (((2,2,7-TRIMETHYL-3-OXAINDAN-4-YL)AMINO)METHYLENE)METHANE-1,1-DICARBONITRILE BUTTPARK 2\07-16 BUTTPARK 7\07-45 BUTTPARK 7\07-39 BUTTPARK 7\07-44 BUTTPARK 7\07-42

  • (2-isopropoxyphenyl)amine(SALTDATA: HCl)
  • 2-(propan-2-yloxy)aniline
  • 2-(1-Methylethoxy)aniline
  • o-Isopropoxyaniline
  • ANILINE, o-ISOPROPOXY-
  • Benzenamine, 2-(1-methylethoxy)-
  • o-Ipa
  • o-Izopropoksyanilina [Polish]
  • (2-isopropoxyphenyl)amine sulfate
  • 2-(1-Methylethoxy)benzenamine
  • 29026-74-2