TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
Uses- Product Name
- TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
- CAS No.
- 50525-27-4
- Chemical Name
- TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
- Synonyms
- Ru(bpy)3Cl2;Ru(BPY)3;Ru(bpy)3(Cl)2·6H2O;Tris(2,2;Tris(2,2'-bipyridyL;Ru(bpy)3Cl2 Hexahydrate;ororuthenium(II) hexahydrate;tris(2,2’-bipyridyl)ruthenium;Dichlorotris(2,2'-bipyridyl)ruthenium(II);Ruthenium-tris(2,2′-bipyridyl) dichloride
- CBNumber
- CB7101742
- Molecular Formula
- C30H26ClN6ORu+
- Formula Weight
- 623.1
- MOL File
- 50525-27-4.mol
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Property
- Melting point:
- >300 °C(lit.)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- powder
- color
- Red-orange to red
- Water Solubility
- Soluble in water.
- Stability:
- Stable, but may discolour upon exposure to light. Incompatible with strong oxidizing agents.
- InChI
- InChI=1S/3C10H8N2.ClH.H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;1H;1H2;/q;;;;;+2/p-1
- InChIKey
- VCIOOYXESNFDKX-UHFFFAOYSA-M
- SMILES
- [Ru+2]123(N4=CC=CC=C4C4=CC=CC=N14)(N1=CC=CC=C1C1=CC=CC=N21)N1=CC=CC=C1C1=CC=CC=N31.[Cl-].O
- CAS DataBase Reference
- 50525-27-4(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 224758
- Product name
- Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate
- Purity
- powder
- Packaging
- 1g
- Price
- $148
- Updated
- 2025/07/31
- Product number
- 224758
- Product name
- Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate
- Purity
- powder
- Packaging
- 5g
- Price
- $462
- Updated
- 2025/07/31
- Product number
- T1655
- Product name
- Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $101
- Updated
- 2025/07/31
- Product number
- T1655
- Product name
- Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $336
- Updated
- 2025/07/31
- Product number
- 44-7900
- Product name
- Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate, min. 98%
- Packaging
- 1g
- Price
- $84
- Updated
- 2024/03/01
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Chemical Properties,Usage,Production
Uses
Tris (2,2’-bipyridyl) dichlororuthenium hexahydrate (RTDP, Ru (BPY) 3) is an oxygen-sensitive fluorescent stain. It can be used to measure the oxygen concentration of microfluidic chips.
Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions, and is an important catalyst in studies towards photochemical water splitting. This product is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.
Chemical Properties
red to orange powder or crystals
Uses
suzuki reaction
Uses
Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions. It is an important catalyst in studies towards photochemical water splitting. This product can be used as a catalyst in pharmaceutical research. It is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.
General Description
Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.
reaction suitability
core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst
Synthesis
Dried RuCl3 (200 mg, 0.964 mmol) and 2,2??-bipyridine (452 mg, 2.89 mmol) were dissolved in H2O (20 mL). Saturated naapo2h2 (2 ml) was added to the mixture. The resulting mixture was heated to reflux for 30 min. The reaction mixture was filtered. Potassium chloride (6.3 g, 84.5 mmol) was added to the filtrate. The mixture was heated to boiling. The reaction mixture was allowed to cool to room temperature. The crystals obtained were collected by filtration. The mixture was washed with cold acetone and recrystallized from water to give tris(bipyridyl)ruthenium(II) chloride.
Purification Methods
Recrystallise it from water, then from MeOH [Ikezawa et al. J Am Chem Soc 108 1589 1986].
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE manufacturers
- Product
- [Ru (bpy)3] Cl2·6H2O 50525-27-4
- Price
- US $0.00/g
- Min. Order
- 1g
- Purity
- 99.90%
- Supply Ability
- 100kgs
- Release date
- 2021-09-16
- Product
- TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE 50525-27-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
- Product
- TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE 50525-27-4
- Price
- US $26.00/KG
- Min. Order
- 1KG
- Purity
- 99
- Supply Ability
- 100KG
- Release date
- 2020-11-11