((S)-piperidin-3-yl)methanol
- Product Name
- ((S)-piperidin-3-yl)methanol
- CAS No.
- 144539-77-5
- Chemical Name
- ((S)-piperidin-3-yl)methanol
- Synonyms
- 3(S)-Piperidinemethanol;(3S)-3-PiperidineMethanol;(S)-Piperidine-3-methanol;3-Piperidinemethanol, (3S)-;(3S)-piperidin-3-ylMethanol;((S)-piperidin-3-yl)methanol;(S)-3-Hydroxymethyl-piperidine, 99.8%ee, 98%
- CBNumber
- CB71094069
- Molecular Formula
- C6H13NO
- Formula Weight
- 115.17
- MOL File
- 144539-77-5.mol
((S)-piperidin-3-yl)methanol Property
- Boiling point:
- 240.4±0.0 °C(Predicted)
- Density
- 0.951
- refractive index
- 1.451
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 14.93±0.10(Predicted)
- Appearance
- Colorless to light yellow Solid-liquid mixture
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- P481970
- Product name
- (S)-3-Piperidinemethanol
- Packaging
- 2.5g
- Price
- $1055
- Updated
- 2021/12/16
- Product number
- 66751
- Product name
- (S)-3-Piperidinemethanol
- Packaging
- 2.5g
- Price
- $1460
- Updated
- 2021/12/16
- Product number
- W3153
- Product name
- (S)-(Piperidin-3-yl)methanol
- Packaging
- 5g
- Price
- $745
- Updated
- 2021/12/16
- Product number
- 4H01-1-43
- Product name
- (3S)-Piperidin-3-ylmethanol
- Packaging
- 250mg
- Price
- $150
- Updated
- 2021/12/16
- Product number
- 073570
- Product name
- (S)-(Piperidin-3-yl)methanol
- Purity
- 95+%
- Packaging
- 1g
- Price
- $94
- Updated
- 2021/12/16
((S)-piperidin-3-yl)methanol Chemical Properties,Usage,Production
Uses
(S)-3-Piperidinemethanol is used to study enzymic chemoselective and enantioselective acyl transfers in hydroxymethylpiperidines.
Uses
((S)-piperidin-3-yl)methanol is used to study enzymic chemoselective and enantioselective acyl transfers in hydroxymethylpiperidines.
Synthesis
37675-18-6
4606-65-9
General procedure for the synthesis of 3-hydroxymethylpiperidine from ethyl (S)-3-piperidinecarboxylate: lithium aluminum hydride (LAH, 118 mL, 1.0 M in ether, 1.0 equiv.) was slowly added to a solution of tetrahydrofuran (THF, 250 mL) of the product of step A (18.5 g, 0.125 mmol) over a period of 20 min at 0 °C. The reaction mixture was gradually warmed to room temperature and subsequently heated to reflux for 2 hours. Upon completion of the reaction, it was cooled to room temperature and the reaction was quenched by slow addition of saturated sodium sulfate (Na2SO4) solution. The resulting slurry was dried by the addition of anhydrous sodium sulfate (Na2SO4), filtered through diatomaceous earth and concentrated to give a colorless oily product (13.7 g, 98% crude yield). The product was detected by chemical ionization mass spectrometry (CIMS) showing a molecular ion peak (MH+) of 116; the specific optical rotation ([α]20D) was -8.4° (determined by dissolving 5.0 mg of the sample in 2 mL of methanol).
References
[1] Patent: US2003/229099, 2003, A1. Location in patent: Page 174
[2] Patent: US2004/122018, 2004, A1. Location in patent: Page 208
[3] Patent: EP1140904, 2005, B1. Location in patent: Page/Page column 33
[4] Patent: EP1553074, 2005, A1. Location in patent: Page/Page column 37
[5] Patent: WO2014/173855, 2014, A1. Location in patent: Page/Page column 17
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View Lastest Price from ((S)-piperidin-3-yl)methanol manufacturers
- Product
- (S)-(Piperidin-3-yl)methanol 144539-77-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.1%
- Supply Ability
- 100 tons
- Release date
- 2022-01-26
- Product
- ((S)-piperidin-3-yl)methanol 144539-77-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000KGS
- Release date
- 2019-12-25