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Tetrabutylammonium nitrite

Product Name
Tetrabutylammonium nitrite
CAS No.
26501-54-2
Chemical Name
Tetrabutylammonium nitrite
Synonyms
97.0% (NT);etrabutylazanium,nitrite;tetrabutylazanium:nitrite;TETRABUTYLAMMONIUM NITRITE;Tetrabutylammonium nitrite purum;Tetrabutylaminium·nitrous acid anion;TetrabutylaMMoniuM nitrite >=97.0% (NT);Tetrabutylammonium nitrite purum, >=97.0% (NT)
CBNumber
CB7113491
Molecular Formula
C16H36N2O2
Formula Weight
288.47
MOL File
26501-54-2.mol
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Tetrabutylammonium nitrite Property

Melting point:
99-103 °C
BRN 
6285720
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
3-10
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
86884
Product name
Tetrabutylammonium nitrite
Purity
≥97.0% (NT)
Packaging
10g
Price
$142
Updated
2024/03/01
Sigma-Aldrich
Product number
86884
Product name
Tetrabutylammonium nitrite
Purity
≥97.0% (NT)
Packaging
50g
Price
$569
Updated
2024/03/01
Usbiological
Product number
291810
Product name
Tetrabutylammonium Nitrite
Packaging
1g
Price
$305
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0156988
Product name
TETRABUTYLAMMONIUM NITRITE
Purity
95.00%
Packaging
10G
Price
$1188.86
Updated
2021/12/16
AK Scientific
Product number
0748BB
Product name
Tetrabutylammonium nitrite
Packaging
25g
Price
$1244
Updated
2021/12/16
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Tetrabutylammonium nitrite Chemical Properties,Usage,Production

Uses

Tetrabutylammonium nitrite is a tosylate salt. It reversibly binds to copper ions, forming a copper complex that is activated by the presence of nitroalkanes. The binding of tetrabutylammonium nitrite to glycosidic bonds in sugar residues, such as the hemoglobin molecule, leads to the formation of reactive oxygen species (ROS), which are responsible for cell damage. It has been shown to reduce infarct size and improve cardiac function in animal models following ischemic reperfusion injury. This compound also has antioxidant properties due to its ability to scavenge ROS and protect against oxidative stress.

Application

A Tetrabutylammonium nitrite (Bu4NNO2) - acetic anhydride (Ac2O) system was demonstrated to be remarkably efficient for the deanilidation of phosphoranilidates in an oligonucleotide synthesis, i.e., the reaction is over almost instantly[1].

References

[1] S. Akai. “Tetrabutylammonium nitrite - acetic anhydride system, tetrabutylammonium nitrite, tetrabutylammonium acetate, and cesium acetate - 18-crown-6 for efficient unmasking of alkyl N-phenylcarbamates.” Tetrahedron Letters 39 1 (1998): 5583–5586.

Tetrabutylammonium nitrite Preparation Products And Raw materials

Raw materials

Preparation Products

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26501-54-2, Tetrabutylammonium nitriteRelated Search:


  • TETRABUTYLAMMONIUM NITRITE
  • Tetrabutylaminium·nitrous acid anion
  • Tetrabutylammonium nitrite purum, >=97.0% (NT)
  • TetrabutylaMMoniuM nitrite >=97.0% (NT)
  • tetrabutylazanium:nitrite
  • etrabutylazanium,nitrite
  • 97.0% (NT)
  • Tetrabutylammonium nitrite purum
  • 26501-54-2
  • C16H36NNO2
  • CH3CH2CH2CH24NNO2
  • Ammonium Salts
  • Phase Transfer Catalysts
  • Synthetic Reagents
  • Ammonium Salts
  • AmmoniumGreener Alternatives: Catalysis
  • Chemical Synthesis
  • Ionic Liquids
  • Phase Transfer Catalysts
  • Ammonium
  • Ammonium Salts
  • Chemical Synthesis
  • Ionic Liquids
  • Phase Transfer Catalysts
  • Specialty Synthesis
  • Synthetic Reagents