Tetrabutylammonium nitrate
- Product Name
- Tetrabutylammonium nitrate
- CAS No.
- 1941-27-1
- Chemical Name
- Tetrabutylammonium nitrate
- Synonyms
- TETRA-N-BUTYLAMMONIUM NITRATE;Tetrabutylazanium nitrate;SKL1623;N4,4,4,4NO3;Tetrabutylammonium n;etrabutylazanium,nitrate;tetrabutyl-ammoniunitrate;TETRABUTYLAMMONIUM NITRATE;Tetrabutylammonium nitrate,98%;Tetrabutylammonium nitrate 97%
- CBNumber
- CB4676560
- Molecular Formula
- C16H36N2O3
- Formula Weight
- 304.48
- MOL File
- 1941-27-1.mol
Tetrabutylammonium nitrate Property
- Melting point:
- 116-118 °C (lit.)
- Boiling point:
- 445.28°C (rough estimate)
- Density
- 0.9580 (rough estimate)
- refractive index
- 1.5500 (estimate)
- solubility
- acetonitrile: 0.1 g/mL, clear, colorless
- form
- Fine Crystalline Powder
- color
- White
- Water Solubility
- <2 g/100 mL
- Sensitive
- Hygroscopic
- BRN
- 3921016
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents. Hygroscopic - protect from moisture.
- CAS DataBase Reference
- 1941-27-1(CAS DataBase Reference)
- EPA Substance Registry System
- 1-Butanaminium, N,N,N-tributyl-, nitrate (1941-27-1)
Safety
- Hazard Codes
- O,Xi
- Risk Statements
- 8-36/37/38-9
- Safety Statements
- 17-26-37/39
- RIDADR
- UN 1479 5.1/PG 2
- WGK Germany
- 3
- RTECS
- BS5475000
- TSCA
- Yes
- HazardClass
- 5.1
- PackingGroup
- III
- HS Code
- 29239000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 359173
- Product name
- Tetrabutylammonium nitrate
- Purity
- 97%
- Packaging
- 2g
- Price
- $34.4
- Updated
- 2024/03/01
- Product number
- 359173
- Product name
- Tetrabutylammonium nitrate
- Purity
- 97%
- Packaging
- 10g
- Price
- $107
- Updated
- 2024/03/01
- Product number
- T3651
- Product name
- Tetrabutylammonium Nitrate
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $34
- Updated
- 2024/03/01
- Product number
- T3651
- Product name
- Tetrabutylammonium Nitrate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $93
- Updated
- 2024/03/01
- Product number
- 043342
- Product name
- Tetra-n-butylammonium nitrate
- Purity
- 98%
- Packaging
- 5g
- Price
- $45.65
- Updated
- 2024/03/01
Tetrabutylammonium nitrate Chemical Properties,Usage,Production
Chemical Properties
white powder
Uses
Tetra-n-butylammonium nitrate is used in coatings, printing ink, rubber, glass, leather and cosmetics. It serves as a supporting electrolyte in liquid ammonia. It is also used in the preparation of nitrates from triflates. It is employed in the inversion of configuration of alcohols through tosylates. It is also a source of NO3- used in nucleophilic substitution reactions. Further, it is used in the conversion of halides into ketones. In addition to this, it is used as a source of nitronium ions for the nitration of olefins, amides, ribonucleosides, glycols and aromatic compounds.
Preparation
Tetrabutylammonium nitrate (TBAN) is prepared from tetrabutylammonium bromide by passing through Amberlite anionic exchange resin with potassium nitrate. The filtrate is evaporated to dryness and recrystallized from benzene to give pure TBAN as a white crystalline solid.
Purification Methods
Crystallise it from *benzene (7mL/g), EtOH or EtOAc (m 121-122o); dry it in a vacuum over P2O5 at 60o for 2 days. [Beilstein 4 IV 558.]
Tetrabutylammonium nitrate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tetrabutylammonium nitrate manufacturers
- Product
- Tetrabutylammonium nitrate 1941-27-1
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99.10%
- Supply Ability
- 50000kg
- Release date
- 2024-04-26
- Product
- Tetrabutylammonium nitrate 1941-27-1
- Price
- US $36.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000 tons
- Release date
- 2023-02-02
- Product
- Tetrabutylammonium nitrate 1941-27-1
- Price
- US $500.00/g
- Min. Order
- 100g
- Purity
- 99%
- Supply Ability
- 200ton
- Release date
- 2023-08-08