Tetrabutylammonium hydrogen sulfate
- Product Name
- Tetrabutylammonium hydrogen sulfate
- CAS No.
- 32503-27-8
- Chemical Name
- Tetrabutylammonium hydrogen sulfate
- Synonyms
- TBAHS;TETRABUTYLAMMONIUM BISULFATE;IPC-TBA-HS;TETRABUTYLAMMONIUM HYDROGEN SULPHATE;hydrogen sulfate,tetrabutylazanium;ammonium hydrog;TETRA-N-BUTYLAMMONIUM HYDROGEN SULPHATE;Tetrabutylammonium Hydrogen Sulfate [Reagent for Ion-Pair Chromatography];fate;en suL
- CBNumber
- CB0414623
- Molecular Formula
- C16H37NO4S
- Formula Weight
- 339.53
- MOL File
- 32503-27-8.mol
Tetrabutylammonium hydrogen sulfate Property
- Melting point:
- 171-174 °C
- Boiling point:
- 213.3-593.92℃[at 101 325 Pa]
- Density
- 1.01
- vapor pressure
- 0Pa at 25℃
- storage temp.
- Store below +30°C.
- solubility
- H2O: soluble10% (w/v), clear, colorless
- form
- Solution
- color
- White to beige
- Specific Gravity
- 1.01
- Odor
- Amine like
- PH Range
- 1 - 2
- PH
- 1-2 (100g/l, H2O, 20℃)
- Water Solubility
- Soluble
- Sensitive
- Hygroscopic
- λmax
- λ: 210 nm Amax: 0.06
λ: 220 nm Amax: 0.05
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02 - BRN
- 3599663
- Stability:
- Stable, but moisture sensitive. Incompatible with strong oxidizing agents.
- InChIKey
- SHFJWMWCIHQNCP-UHFFFAOYSA-M
- LogP
- 0.96 at 25℃
- CAS DataBase Reference
- 32503-27-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Tetrabutylammonium hydrogen sulfate(32503-27-8)
- EPA Substance Registry System
- Tetrabutylammonium sulfate (1:1) (32503-27-8)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- F
- 8-10
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29239000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 98479
- Product name
- Tetrabutylammonium bisulfate solution
- Purity
- suitable for ion pair chromatography, LiChropur?, concentrate, ampule
- Packaging
- 6x1amp
- Price
- $597
- Updated
- 2024/03/01
- Product number
- 86853
- Product name
- Tetrabutylammonium bisulfate
- Purity
- suitable for ion pair chromatography, LiChropur?, ≥99.0%
- Packaging
- 10g
- Price
- $176
- Updated
- 2024/03/01
- Product number
- 86853
- Product name
- Tetrabutylammonium bisulfate
- Purity
- suitable for ion pair chromatography, LiChropur?, ≥99.0%
- Packaging
- 10x1g
- Price
- $572
- Updated
- 2024/03/01
- Product number
- 86853
- Product name
- Tetrabutylammonium bisulfate
- Purity
- suitable for ion pair chromatography, LiChropur?, ≥99.0%
- Packaging
- 50g
- Price
- $678
- Updated
- 2024/03/01
- Product number
- 8.18858
- Product name
- Tetra-n-butylammonium hydrogen sulfate
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $135
- Updated
- 2024/03/01
Tetrabutylammonium hydrogen sulfate Chemical Properties,Usage,Production
Chemical Properties
It is a stable, hygroscopic, white powder.
Uses
A compound that displays antibacterial properties due to the presence of the quaternary amine and the counter ion. Tetrabutylammonium hydrogen sulfate is an ion pairing reagent that is used in liquid chromatography. It is frequently utilized in the analysis of pharmaceutical compounds and metabolites.
Uses
Phase transfer catalyst Tetra-n-butylammonium hydrogen sulfate shows antibacterial properties due to the presence of the quaternary amine and the counter ion. It serves as a phase-transfer catalyst, surface-active agent, solvent, intermediate, active ingredient for conditioners, antistatic agent, detergent sanitizers, softener for textiles and paper products, emulsifying agents and pigment dispersers. Tetrabutylammonium hydrogensulfate is used as a cocatalyst in the synthesis of propionic acid and the ketones by hydrocarboxylation of ethylene. It is also used as an efficient catalyst in the N-alkylation reactions of benzanilides, cyclization of beta-amino acids to beta-lactams, conversion of nitriles to amides, dehydrohalogenation of aryl 2-haloethyl ethers to give vinyl ethers and in the oxidation of alcohols.
Preparation
Tetrabutylammonium hydrogen sulfate can be prepared from tetrabutylammonium azide by treating it with potassium hydrogen sulfate and 10% aqueous sulfuric acid in aqueous medium or from tetrabutylammonium thiocyanate by treating it with relatively concentrated sulfuric acid (70%) at 75 °C.
General Description
Tetrabutylammonium hydrogensulfate, a quaternary ammonium salt, is a phase-transfer reagent. It It serves as solvent for the dissolution of ruthenium(II) complex fac-[Ru(CO)2(H2O)3(C(O)C2H5)][CF3SO3]. It participates as a cocatalyst in the reaction medium for the preparation of alternating polyketones and propionic acid.
Purification Methods
The sulfate crystallises from acetone. It has been used as a phase transfer catalyst.
References
[1] H. N. KARADE M. P K M Sathe. An efficient synthesis of 1, 8-dioxo-octahydroxanthenes using tetrabutylammonium hydrogen sulfate[J]. Arkivoc, 2007, 2007 1. DOI:10.3998/ARK.5550190.0008.D28.
[2] A. J. PARDEY. New media in homogeneous catalysis: wet sodium or tetrabutylammonium hydrogensulfate salts for reppe syntheses catalyzed by a ru(ii) carbonyl complex[J]. Journal of Coordination Chemistry, 2004, 57 1: 871-882. DOI:10.1080/00928970410001721998.
[3] A. J. PARDEY. Hydrocarboxylation and stepwise alternating oligomerization of carbon monoxide and ethylene catalyzed by cis-[Rh(CO)2(amine)2](PF6) complexes in a wet liquid tetrabutylammonium hydrogensulfate[J]. Polyhedron, 2004, 23 1: 1677-1683. DOI:10.1016/J.POLY.2004.03.023.
[4] NEETU TEWARI Rama P T Namrata Dwivedi. Tetrabutylammonium hydrogen sulfate catalyzed eco-friendly and efficient synthesis of glycosyl 1,4-dihydropyridines[J]. Tetrahedron Letters, 2004, 45 49: Pages 9011-9014. DOI:10.1016/j.tetlet.2004.10.057.
Tetrabutylammonium hydrogen sulfate Preparation Products And Raw materials
Raw materials
Preparation Products
Tetrabutylammonium hydrogen sulfate Suppliers
- Tel
- 0515-81187878 13951550009
- Country
- CHINA
- ProdList
- 3
- Advantage
- 58
- Tel
- 400-1166-196 13458535857
- Fax
- QQ：800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 13350
- Advantage
- 58
- Tel
- 400-400-6206333 18521732826
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25003
- Advantage
- 65
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 133-96369453 18678026865
- Fax
- 0536-2101172
- sdfantai@163.com
- Country
- China
- ProdList
- 869
- Advantage
- 58
- Tel
- 021-69106814 13917161715
- 3007500651@qq.com
- Country
- China
- ProdList
- 80
- Advantage
- 60
- Tel
- 0536-8790166 15105445095
- weimengchem@163.com
- Country
- China
- ProdList
- 472
- Advantage
- 58
- Tel
- 18917565227
- inspo@inspochem.com
- Country
- China
- ProdList
- 150
- Advantage
- 58
- Tel
- 021-50182298 021-50180596
- Fax
- +86-21-57758967
- sales@boylechem.com
- Country
- China
- ProdList
- 2208
- Advantage
- 55
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
View Lastest Price from Tetrabutylammonium hydrogen sulfate manufacturers
- Product
- Tetrabutylammonium hydrogen sulfate 32503-27-8
- Price
- US $110.00-70.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000
- Release date
- 2024-08-14
- Product
- Tetrabutylammonium hydrogen sulfate 32503-27-8
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-08
- Product
- Tetrabutylammonium hydrogen sulfate 32503-27-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-14