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3,3'-Dibromo-2,2'-bithiophene

Product Name
3,3'-Dibromo-2,2'-bithiophene
CAS No.
51751-44-1
Chemical Name
3,3'-Dibromo-2,2'-bithiophene
Synonyms
Na ≥2TH-2Bra;-bithiophenyl;5-Triiodo-β-Bi-p-anisidine;-Oxy-venetoclax;-Dicyanobiphenyl;-Diformylbiphenyl;-Dibromodiphenyl-d8;-Dithiobis-L-valine
CBNumber
CB71262620
Molecular Formula
C8H4Br2S2
Formula Weight
324.06
MOL File
51751-44-1.mol
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3,3'-Dibromo-2,2'-bithiophene Property

Melting point:
103°C
Boiling point:
318.6±37.0 °C(Predicted)
Density 
1.951±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Toluene
form 
powder
color 
White to Yellow to Orange
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Safety

Hazard Codes 
T
Risk Statements 
25-41
Safety Statements 
26-39
RIDADR 
2811
WGK Germany 
3
HazardClass 
IRRITANT
PackingGroup 
Ⅲ
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
733725
Product name
3,3′-Dibromo-2,2′-bithiophene
Purity
97%
Packaging
5g
Price
$311
Updated
2024/03/01
Sigma-Aldrich
Product number
733725
Product name
3,3′-Dibromo-2,2′-bithiophene
Purity
97%
Packaging
1g
Price
$70.1
Updated
2023/06/20
TCI Chemical
Product number
D3798
Product name
3,3'-Dibromo-2,2'-bithiophene
Purity
>98.0%(GC)
Packaging
1g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
D3798
Product name
3,3'-Dibromo-2,2'-bithiophene
Purity
>98.0%(GC)
Packaging
5g
Price
$232
Updated
2024/03/01
TCI Chemical
Product number
D3798
Product name
3,3'-Dibromo-2,2'-bithiophene
Purity
>98.0%(GC)
Packaging
25g
Price
$792
Updated
2024/03/01
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3,3'-Dibromo-2,2'-bithiophene Chemical Properties,Usage,Production

Chemical Properties

Colorless solid

Uses

3,3’-Dibromo-2,2’-dithiophene is used in the preparation of benzothiadiazole copolymers which direct charge transport in thin-film transistors. Used in the synthesis of solar cells which are dithienopyrrole / anthracene based.

Uses

suzuki reaction

Uses

3,3'-Dibromo-2,2'-dithiophene is used in the preparation of benzothiadiazole copolymers which direct charge transport in thin-film transistors. Used in the synthesis of solar cells which are dithienop yrrole / anthracene based.

Application

3,3'-Dibromo-2,2'-bithiophene can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and pharmaceutical and chemical production processes.

Synthesis


The freshly prepared LDA solution (prepared by the addition ofn-BuLi (2.5 M in hexanes, 100 mmol, 40 mL) and diisopropylamine(11.1 g, 110 mmol) in 50 mL of anhydrous THF (78 C to roomtemperature)) was added drop wise to a solution of 3-bromothiophene (16.30 g, 100 mmol) in anhydrous THF (100 mL)at 78 C under nitrogen atmosphere. The reaction mixture wasstirred for 1 h at 78 C and CuCl2 (14.11 g, 105 mmol)was added inone portion. The reaction mixture was allowed towarm up to roomtemperature and treated with aqueous HCl. The organic phaseseparated was collected and the aqueous phase was extracted withdiethyl ether several times. The combined organic phase was driedover anhydrous Na2SO4 and the solution was filtered, concentratedand the residue was purified by silica gel column chromatography(hexane eluent) to afford a the required compound as white solid(yield 85%).1H NMR (500 MHz, CDCl3, d ppm): 7.08 (d, J 5.0 Hz, 2H), 7.40(d, J 5.0 Hz, 2H).

3,3'-Dibromo-2,2'-bithiophene Preparation Products And Raw materials

Raw materials

Preparation Products

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3,3'-Dibromo-2,2'-bithiophene Suppliers

Americas 1 Belgium 1 Canada 2 China 213 Europe 1 India 6 Japan 2 Lithuania 1 Slovakia 2 South Korea 1 The Netherlands 1 United Kingdom 5 United States 26 Global 262
Specs
Tel
--
Fax
--
Email
info@specs.net
Country
The Netherlands
ProdList
6833
Advantage
70
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View Lastest Price from 3,3'-Dibromo-2,2'-bithiophene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
3,3'-Dibromo-2,2'-bithiophene 51751-44-1
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
99%
Supply Ability
2000tons
Release date
2019-12-31
Zhuozhou Wenxi import and Export Co., Ltd
Product
3,3"-Dibromo-2,2"-bithiophene 51751-44-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
3,3"-Dibromo-2,2"-bithiophene 51751-44-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

51751-44-1, 3,3'-Dibromo-2,2'-bithiopheneRelated Search:

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  • 3-bromo-2-(3-bromothiophen-2-yl)thiophene
  • 3,3'-Dibromo-2,2'-bithiophene 97%
  • 2TH-2Bra
  • -bithiophenyl
  • -Sulfonylbis(N-(4-cyano-3-(trifluoromethyl)phenyl)-2-hydroxy-2-methylpropanamide)|(Mixture of Diastereomers)
  • 5-Triiodo-N-hydroxy-L-thyronine
  • -(Propane-1,3-diyl)bis(7,8-dimethoxy-4,5-dihydro-1H-benzo[d]azepin-2(3H)-one)
  • -diyl Bis(trifluoromethanesulfonate)
  • -diphenyl-9-ethyloxacarbocyanine Betaine Sodium Salt
  • -Dipropylthiadicarbocyanine iodide
  • -Diethyloxacarbocyanine Iodide
  • -((2-Hydroxypropane-1,3-diyl)bis(oxy))bis(4-chlorobenzoic acid) Diethyl Ester
  • -Dibromodiphenyl-d8
  • 5-Triiodo-&beta
  • -hydroxy-D/L-thyronine
  • -[(4-Hydroxyphenyl)methylene]bis[4-hydroxybenzaldehyde
  • -Dichlorobenzidine-13C12
  • -Disulfanediylbis(4-amino-N-methylbenzenesulfonamide)
  • -Diethyloxadicarbocyanine Iodide
  • -Bi-p-anisidine
  • 5-Trichlorobisphenol A
  • -Pyridyl)-D-alanine 99+%
  • -Dipentyloxacarbocyanine iodide
  • -Thiodipropanoic Acid
  • -(Propane-1,3-diyl)bis(1-(prop-1-en-2-yl)-1H-benzo[d]imidazol-2(3H)-one)
  • -(Naphthalene-1,3-diyl)bis(N-methyl-3-(thiophen-2-yl)propan-1-amine) Dihydrochloride
  • -Dithiobis-L-valine
  • -Methylene-bis(4-hydroxycoumarin)
  • -Dichlorobenzidine-d6
  • -Dicyanobiphenyl
  • -(Propane-1,3-diyl)bis(2-oxo-2,3-dihydro-1H-benzo[d]imidazole-1-carboxylate) Di-tertbutyl Ester
  • -[(4-Methoxyphenyl)methylene]bis[4-methoxybenzaldehyde
  • -Dithiobis[6-nitrobenzoic acid] bis(succinimide) ester
  • -(Butane-1,4-diyl)bis(1-vinyl-3-imidazolium) bis(trifluoromethanesulfonyl)imide
  • 5-Triiodothyronamine Hydrochloride
  • -Dibutylthiacarbocyanine Iodide
  • -Bisdemethylpinoresinol
  • -Methylenedisalicylic Acid-13C12
  • -Methylenebis[5-bromo-saligenin
  • -Diindolyl Disulphide
  • 5-Triiodo thyroacetic acid
  • -(Propane-1,3-diyl)bis(7,8-dimethoxy-1H-benzo[d]azepin-2(3H)-one)
  • -Diaminobenzidine tetrahydrochloride hydrate &ge
  • -Diindolyl disulfide
  • -(Propane-1,3-diyl)bis(1-(prop-1-en-2-yl)-1H-benzo[d]imidazol-2(3H)-one)-d6
  • -Trifluoromethylphenyl)propanol
  • -Pyridyl)-DL-alanine 99+% (HPLC)
  • -(Propane-1,3-diyl)bis(7,8-dimethoxy-4,5-dihydro-1H-benzo[d]azepin-2(3H)-one)-d6
  • 4-Pentachlorobiphenyl
  • -((Methylenebis(4,1-phenylene))bis(oxy))bis(1-(trityloxy)propan-2-ol)
  • -Diaminobenzidine 99+%
  • 5-Triiodo-L-thyronine&middot
  • Na &ge
  • -Hepta-O-pivaloyl-&alpha
  • -Diethylthiatricarbocyanine iodide