1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI)

Product Name: 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI)
CAS No.: 790667-43-5
Chemical Name: 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI)
Synonyms: tert-butyl (R)-2-methyl-4-oxopiperidine-1-carboxylate;(R)-tert-butyl 2-methyl-4-oxopiperidine-1-carboxylate;(2R)-2-Methyl-4-oxo-piper...;(R)-1-Boc-2-methyl-4-piperidinone;1-N-boc-2(R)-Methyl-piperidin-4-one;(R)-tert-Butyl 2-methyl-4-oxopiperidine-1;tert-butyl (2R)-2-methyl-4-oxopiperidine-1-carboxylate;(R)-2-Methyl-4-oxopiperidine-1-carboxylic acid tert-butyl ester;(2R)-2-Methyl-4-oxo-piperidine-1-carboxylic acid tert-butyl ester;1-Piperidinecarboxylic acid, 2-methyl-4-oxo-, 1,1-dimethylethyl ester, (2R)-
CBNumber: CB71289746
Molecular Formula: C11H19NO3
Formula Weight: 213.27
MOL File: 790667-43-5.mol

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1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) Property

Melting point:: 57.7 °C
Boiling point:: 298.8±33.0 °C(Predicted)
Density: 1.060±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: -1.52±0.40(Predicted)
Appearance: White to off-white Solid
InChI: InChI=1S/C11H19NO3/c1-8-7-9(13)5-6-12(8)10(14)15-11(2,3)4/h8H,5-7H2,1-4H3/t8-/m1/s1
InChIKey: HQMYWQCBINPHBB-MRVPVSSYSA-N
SMILES: N1(C(OC(C)(C)C)=O)CCC(=O)C[C@H]1C

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Biosynth Carbosynth

Product number: FB168805
Product name: (R)-tert-Butyl 2-methyl-4-oxopiperidine-1
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB168805
Product name: (R)-tert-Butyl 2-methyl-4-oxopiperidine-1
Packaging: 250mg
Price: $125
Updated: 2021/12/16

AK Scientific

Product number: 2366AC
Product name: (R)-tert-Butyl2-methyl-4-oxopiperidine-1-carboxylate
Packaging: 250mg
Price: $131
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB168805
Product name: (R)-tert-Butyl 2-methyl-4-oxopiperidine-1
Packaging: 500mg
Price: $200
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB168805
Product name: (R)-tert-Butyl 2-methyl-4-oxopiperidine-1
Packaging: 1g
Price: $300
Updated: 2021/12/16

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1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) Chemical Properties,Usage,Production

Synthesis

190906-92-4

790667-43-5

790667-49-1

Tert-butyl (R)-2-methyl-4-oxopiperidine-1-carboxylate and 1-N-Boc-2(S)-methyl-piperidin-4-one were synthesized by chiral chromatographic separation using 1-Boc-2-methyl-piperidone as starting material. The procedure was as follows: using a CHIRALPAK ADTM column (size: 4.6×250 mm) with anhydrous ethanol as the mobile phase, the flow rate was set at 1.0 mL/min, and the elution was carried out at the UV detection wavelength of 220 nm. The racemic tert-butyl 2-methyl-4-oxopiperidine-1-carboxylate (15.0 g) was separated to finally obtain isomer 1 ((R)-tert-butyl 2-methyl-4-oxopiperidine-1-carboxylate, 5.28 g, 35% yield) and isomer 2 (1-N-Boc-2(S)-methyl-piperidin-4-one, 5.01 g, 33% yield). The 1H NMR (CDCl3) data of the two isomers were in agreement as follows: δ 4.7 (m, 1H), 4.2 (m, 1H), 3.3 (m, 1H), 2.7 (m, 1H), 2.5 (m, 1H), 2.3 (m, 1H), 2.2 (m, 1H), 1.5 (s, 9H), 1.2 (d, 3H).

References

[1] Patent: WO2004/94380, 2004, A1. Location in patent: Page 26-27

1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) 790667-43-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-09-24

Shaanxi Dideu New Materials Co. Ltd

Product: 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) 790667-43-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
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Release date: 2025-06-28

Career Henan Chemical Co

Product: 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) 790667-43-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1lg; 2kg; 5kg; 10kg; 100kg
Release date: 2019-08-31

790667-43-5, 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI)Related Search:

1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2S)-(9CI) (2-Aza-spiro[3.3]hept-6-yl)-carbamic acid tert-butyl ester 1-Azetidinecarboxylic aci... 1-BOC-3-METHYLAMINOAZETIDINE 2-(tert-Butoxycarbonyl)-2,7-diazaspiro[3.5]nonane tert-butyl (cis-3-aminocy... tert-butyl 6-oxo-2-azaspiro[3.3]heptane-2-carboxylate N-Boc-9-azabicyclo[3.3.1]nonan-3-one N-Boc-Nortropinone tert-butyl 8-oxo-5-azaspiro[3.5]nonane-5-carboxylate TERT-BUTYL 4-OXO-1-AZASPIRO[5.5]UNDECANE-1-CARBOXYLATE 1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI) (R)-1-tert-butyl 2-methyl 4-oxopiperidine-1,2-dicarboxylate (S)-1-tert-butyl 2-methyl 4-oxopiperidine-1,2-dicarboxylate TERT-BUTYL (2R)-2-BENZYL-4-OXOPIPERIDINE-1-CARBOXYLATE N-BOC-NORTROPINONE EPOXIDE (2S)-N-BOC-4-OXOPIPECOLIC ACID (2S)-2-ISOPROPYL-4-OXOPIPERIDINE, N-BOC PROTECTED

1-Piperidinecarboxylicacid,2-methyl-4-oxo-,1,1-dimethylethylester,(2R)-(9CI)

(2R)-2-Methyl-4-oxo-piper...

(2R)-2-Methyl-4-oxo-piperidine-1-carboxylic acid tert-butyl ester

1-N-boc-2(R)-Methyl-piperidin-4-one

tert-butyl (2R)-2-methyl-4-oxopiperidine-1-carboxylate

1-Piperidinecarboxylic acid, 2-methyl-4-oxo-, 1,1-dimethylethyl ester, (2R)-

(R)-tert-butyl 2-methyl-4-oxopiperidine-1-carboxylate

(R)-2-Methyl-4-oxopiperidine-1-carboxylic acid tert-butyl ester

(R)-tert-Butyl 2-methyl-4-oxopiperidine-1

(R)-1-Boc-2-methyl-4-piperidinone

tert-butyl (R)-2-methyl-4-oxopiperidine-1-carboxylate

790667-43-5

METHYL