ChemicalBook > CAS DataBase List > 4,7-DIMETHYL-1H-INDENE

4,7-DIMETHYL-1H-INDENE

Product Name
4,7-DIMETHYL-1H-INDENE
CAS No.
6974-97-6
Chemical Name
4,7-DIMETHYL-1H-INDENE
Synonyms
Nsc22051;4,7-Dimethylindene;4,7-DIMETHYL-1H-INDENE;1H-Indene, 4,7-dimethyl-;3-pyridin-4-yl-1-propanethiol
CBNumber
CB7129698
Molecular Formula
C11H12
Formula Weight
144.21
MOL File
6974-97-6.mol
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4,7-DIMETHYL-1H-INDENE Property

Boiling point:
230℃
Density 
0.998
Flash point:
87℃
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
J54994
Product name
4,7-Dimethyl-1H-indene
Packaging
250mg
Price
$35
Updated
2021/12/16
Oakwood
Product number
034861
Product name
4,7-Dimethyl-1H-indene
Purity
97%
Packaging
5g
Price
$215
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0079463
Product name
4,7-DIMETHYL-1H-INDENE
Purity
95.00%
Packaging
5G
Price
$909.56
Updated
2021/12/16
Oakwood
Product number
034861
Product name
4,7-Dimethyl-1H-indene
Purity
97%
Packaging
100g
Price
$2995
Updated
2021/12/16
Ambeed
Product number
A148811
Product name
4,7-Dimethyl-1H-indene
Purity
97%
Packaging
1g
Price
$15
Updated
2021/12/16
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4,7-DIMETHYL-1H-INDENE Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6627, 1994 DOI: 10.1016/S0040-4039(00)73452-6

Synthesis

542-92-7

110-13-4

6974-97-6

The general procedure for the synthesis of 4,7-dimethyl-1H-indene from cyclopentadiene and 2,5-hexanedione was as follows: sodium filaments (426 mmol, 9.8 g) were pressed into a three-necked flask under argon protection, and about 100 mL of dry methanol was added slowly until the sodium filaments were completely dissolved. Subsequently, freshly distilled cyclopentadiene (260 mmol, 21.2 mL) and 2,5-hexanedione (170 mmol, 26.5 mL) were added, and the reaction mixture was stirred for 24 h, during which time bubbles were observed. Upon completion of the reaction, 50 mL of water was added to quench the reaction. After removal of the methanol solvent by steam distillation, the pH of the reaction solution was adjusted to neutral with dilute hydrochloric acid. The aqueous phase was extracted three times with 200 mL of petroleum ether, and the organic phases were combined, dried over anhydrous magnesium sulfate and filtered. The solvent was removed by rotary evaporation to give a dark brown liquid. The liquid was distilled under reduced pressure and the 76-80 °C fraction was collected at a pressure of 4 mmHg to give a final 21.5 g of yellow oily liquid product.

References

[1] Patent: CN106565404, 2017, A. Location in patent: Paragraph 0076; 0077; 0078
[2] Tetrahedron, 1995, vol. 51, # 15, p. 4347 - 4358
[3] Tetrahedron Letters, 1994, vol. 35, # 36, p. 6627 - 6630
[4] Patent: US5194619, 1993, A

4,7-DIMETHYL-1H-INDENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4,7-DIMETHYL-1H-INDENE manufacturers

Career Henan Chemical Co
Product
4,7-DIMETHYL-1H-INDENE 6974-97-6
Price
US $1.00/KG
Min. Order
1G
Purity
98%
Supply Ability
100KG
Release date
2018-08-15

6974-97-6, 4,7-DIMETHYL-1H-INDENERelated Search:


  • 4,7-DIMETHYL-1H-INDENE
  • 1H-Indene, 4,7-dimethyl-
  • Nsc22051
  • 4,7-Dimethylindene
  • 3-pyridin-4-yl-1-propanethiol
  • 6974-97-6
  • Indanone & Indene