ChemicalBook > CAS DataBase List > 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID

1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID

Product Name: 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID
CAS No.: 72934-37-3
Chemical Name: 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID
Synonyms: EOS-60319;TIMTEC-BB SBB003583;RARECHEM AL BO 1115;1-(p-chlorophenyl)cyclopropanecarboxylic acid;1-(4-CHLOROPHENYL)CYCLOPROPANECARBOXYLIC ACID;1-(p-Dhlorophenyl)cyclopropanecarboxylic acid.;1-(4-Chlorophenyl)cyclopropan-1-carboxylic acid;1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID;cyclopropanecarboxylic acid, 1-(4-chlorophenyl)-;1-(4-Chlorophenyl)-1-cyclopropanecarboxylic acid,99%
CBNumber: CB7138306
Molecular Formula: C10H9ClO2
Formula Weight: 196.63
MOL File: 72934-37-3.mol

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1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID Property

Melting point:: 152-155 °C
Boiling point:: 152-155°C
Density: 1.2040 (rough estimate)
refractive index: 1.5152 (estimate)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol
pka: 4.14±0.20(Predicted)
form: Crystalline Powder
color: White
InChI: InChI=1S/C10H9ClO2/c11-8-3-1-7(2-4-8)10(5-6-10)9(12)13/h1-4H,5-6H2,(H,12,13)
InChIKey: YAHLWSGIQJATGG-UHFFFAOYSA-N
SMILES: C1(C2=CC=C(Cl)C=C2)(C(O)=O)CC1
CAS DataBase Reference: 72934-37-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36/37/38-20/22-41
Safety Statements: 37/39-26
HazardClass: IRRITANT
HS Code: 29163900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: C2954
Product name: 1-(4-Chlorophenyl)-1-cyclopropanecarboxylic Acid
Purity: >98.0%(T)
Packaging: 5g
Price: $53
Updated: 2025/07/31

TCI Chemical

Product number: C2954
Product name: 1-(4-Chlorophenyl)-1-cyclopropanecarboxylic Acid
Purity: >98.0%(T)
Packaging: 25g
Price: $179
Updated: 2025/07/31

TRC

Product number: C428135
Product name: 1-(4-Chlorophenyl)cyclopropanecarboxylicacid
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC120240
Product name: 1-(4-Chlorophenyl)cyclopropanecarboxylic acid
Packaging: 250mg
Price: $57.5
Updated: 2021/12/16

Matrix Scientific

Product number: 061156
Product name: 1-(4-Chlorophenyl)cyclopropanecarboxylic acid
Packaging: 1g
Price: $63
Updated: 2021/12/16

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1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Synthesis

64399-27-5

72934-37-3

The general procedure for the synthesis of 1-(4-chlorophenyl)-1-cyclopropanecarboxylic acid from 1-(4-chlorophenyl)-1-cyclopropanecarbonitrile is as follows: 1-(4-chlorophenyl)-1-cyclopropanecarbonitrile (18 g) obtained in Example 1 was added to 20% sulfuric acid solution (184 mL). The temperature was slowly raised to reflux and the reaction was maintained for 10-12 hours. Upon completion of the reaction, the reaction mixture was extracted using ethyl acetate. Subsequently, the carboxylic acid product in the organic layer was transferred to 20% sodium hydroxide solution for extraction. The aqueous phase was acidified to pH 2-4 with concentrated hydrochloric acid and a white solid product was precipitated. The solid was collected by filtration and washed with distilled water. After drying, 1-(4-chlorophenyl)-1-cyclopropanecarboxylic acid was obtained in 90-95% yield, 99.4% purity by HPLC and 152-155°C melting point.

References

[1] Patent: WO2009/150660, 2009, A1. Location in patent: Page/Page column 16
[2] Patent: WO2016/178092, 2016, A2. Location in patent: Page/Page column 63; 64
[3] Patent: WO2017/64628, 2017, A1. Location in patent: Page/Page column 33; 34
[4] Chemische Berichte, 1979, vol. 112, p. 3914 - 3933
[5] Patent: US2009/312558, 2009, A1. Location in patent: Page/Page column 6

1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID manufacturers

Career Henan Chemical Co

Product: 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID 72934-37-3
Price: US $2.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: ask
Release date: 2020-01-08

72934-37-3, 1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACIDRelated Search:

1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID Cyclopropyl carbinol CYCLOPROPYLBENZENE tert-Butylbenzene 2-Phenylbutyric acid 2-Bromophenylacetic acid 2-Methyl-1-butanol beta-Methylphenethyl alcohol Phenylacetaldehyde (S)-(+)-2-Methylbutyric acid Cyclopropanecarboxylic acid (S)-(+)-2-Phenylpropionic acid Butyric Acid (S)-(-)-2-PHENYL-1-PROPANOL 1-(4-CHLOROPHENYL)-1-CYCLOPROPANEMETHANOL 1-tert-Butyl-4-chlorobenzene 4-Chlorophenethylalcohol (4-CHLOROMETHYLPHENYL)ACETIC ACID

RARECHEM AL BO 1115

TIMTEC-BB SBB003583

1-(4-CHLOROPHENYL)CYCLOPROPANECARBOXYLIC ACID

1-(4-CHLOROPHENYL)-1-CYCLOPROPANECARBOXYLIC ACID

1-(p-Dhlorophenyl)cyclopropanecarboxylic acid.

cyclopropanecarboxylic acid, 1-(4-chlorophenyl)-

1-(4-chlorophenyl)cyclopropanecarboxylic acid(SALTDATA: FREE)

1-(4-Chlorophenyl)-1-cyclopropanecarboxylic acid, 99% 10GR

1-(p-chlorophenyl)cyclopropanecarboxylic acid

1-(4-Chlorophenyl)-1-cyclopropanecarboxylic acid,99%

EOS-60319

1-(4-Chlorophenyl)-1-cyclopropanecarboxylic Acid &gt

1-(4-Chlorophenyl)cyclopropan-1-carboxylic acid

72934-37-3

C10H8ClO2

C10H9ClO2

pharmacetical

Carboxylic Acids

Ring Systems