METHYL 3-HYDROXY-2-NITROBENZOATE

Product Name: METHYL 3-HYDROXY-2-NITROBENZOATE
CAS No.: 89942-77-8
Chemical Name: METHYL 3-HYDROXY-2-NITROBENZOATE
Synonyms: METHYL 3-HYDROXY-2-NITROBENZOATE;3-Hydroxy-2-nitro-benzoic acid methyl ester;Benzoic acid, 3-hydroxy-2-nitro-, methyl ester;3-hydroxy-2-nitro-Benzoic acid methyl ester (6CI 7CI 9CI ACI);Benzoic acid, 3-hydroxy-2-nitro-, methyl ester (6CI, 7CI, 9CI, ACI);3-(Methoxycarbonyl)-2-nitrophenol, 2-Hydroxy-6-(methoxycarbonyl)nitrobenzene
CBNumber: CB71484259
Molecular Formula: C8H7NO5
Formula Weight: 197.14
MOL File: 89942-77-8.mol

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METHYL 3-HYDROXY-2-NITROBENZOATE Property

Melting point:: 108-110℃
Boiling point:: 310.0±22.0 °C(Predicted)
Density: 1.432±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
pka: 6.38±0.10(Predicted)
color: Off white
InChI: InChI=1S/C8H7NO5/c1-14-8(11)5-3-2-4-6(10)7(5)9(12)13/h2-4,10H,1H3
InChIKey: FHCNMPYMCKHBTK-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC(O)=C1[N+]([O-])=O

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Safety

HS Code: 2918290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P234Keep only in original container.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P390Absorb spillage to prevent material damage.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M323383
Product name: Methyl3-hydroxy-2-nitrobenzoate
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: M323383
Product name: Methyl3-hydroxy-2-nitrobenzoate
Packaging: 1g
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-1-Y2
Product name: Methyl 3-hydroxy-2-nitrobenzoate
Packaging: 250mg
Price: $40
Updated: 2021/12/16

Matrix Scientific

Product number: 116393
Product name: Methyl 3-hydroxy-2-nitrobenzoate
Purity: >97%
Packaging: 1g
Price: $68
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-1-Y2
Product name: Methyl 3-hydroxy-2-nitrobenzoate
Packaging: 1g
Price: $130
Updated: 2021/12/16

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METHYL 3-HYDROXY-2-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

602-00-6

89942-77-8

Sulfoxide chloride (SOCl2, 0.6 mL) was slowly added dropwise to anhydrous methanol (MeOH, 10 mL) at 0 °C. The reaction mixture was stirred continuously for 0.5 h at this temperature. Subsequently, 3-hydroxy-2-nitrobenzoic acid (0.6 g, 3.2 mmol) was added to the mixture. The reaction system was heated to reflux and maintained for 4 hours. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of petroleum ether: ethyl acetate = 1:1) to confirm the completion of the reaction. After completion of the reaction, the mixture was concentrated under vacuum to afford the target product methyl 2-nitro-3-hydroxybenzoate (0.63 g, 100% yield) as a brown solid.

References

[1] Patent: WO2007/125405, 2007, A2. Location in patent: Page/Page column 24; 72-73
[2] Nippon Kagaku Zasshi, 1953, vol. 74, p. 251
[3] Chem.Abstr., 1954, p. 3959
[4] Patent: US2002/52397, 2002, A1
[5] Patent: US5756510, 1998, A

METHYL 3-HYDROXY-2-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-HYDROXY-2-NITROBENZOATE Suppliers

China 66 India 2 United Kingdom 3 United States 10 Global 81

Accela ChemBio Inc.

Tel: +1(858) 699-3322
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Alchem Pharmtech,Inc.

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Aladdin Scientific

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Aceschem Inc.

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United States Biological

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Combi-Blocks Inc.

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SynQuest Laboratories, Inc.

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Matrix Scientific

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ProdList: 6632
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View Lastest Price from METHYL 3-HYDROXY-2-NITROBENZOATE manufacturers

Qingdao RENAS Polymer Material Co., Ltd.

Product: methyl 3-hydroxy-2-nitrobenzoate 89942-77-8
Price: US $0.00/kg
Min. Order: 10kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2025-05-11

Career Henan Chemical Co

Product: METHYL 3-HYDROXY-2-NITROBENZOATE 89942-77-8
Price: US $0.01/KG
Min. Order: 1KG
Purity: 98%; 99%
Supply Ability: 500g； 1kg; 25kg
Release date: 2020-01-10

Career Henan Chemical Co

Product: METHYL 3-HYDROXY-2-NITROBENZOATE 89942-77-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-25

89942-77-8, METHYL 3-HYDROXY-2-NITROBENZOATERelated Search:

2-Nitropyridine-4-carboxylic acid 2-nitro-5-pyridinecarboxylic acid 2-NITRO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE 2-NITROTHIOANISOLE 2-NITRO-5-PHENYLPYRIDINE 5,6-DIMETHOXY-7-NITRO-3 H-ISOBENZOFURAN-1-ONE Methyl 2-nitro-3,4,5-trimethoxybenzoate METHYL 3-METHOXY-2-NITROBENZOATE METHYL 3-HYDROXY-2-NITROBENZOATE RARECHEM AL BI 0983 RARECHEM AL BF 0983 3-BROMO-5-METHOXY-2,6-DINITRO-BENZOIC ACID METHYL ESTER RARECHEM AL BI 0677 ETHYL 3-HYDROXY-2-NITROBENZOATE 3-BROMO-5-BENZYLOXY-2,6-DINITROBENZOIC ACID BENZYL ESTER

METHYL 3-HYDROXY-2-NITROBENZOATE

3-(Methoxycarbonyl)-2-nitrophenol, 2-Hydroxy-6-(methoxycarbonyl)nitrobenzene

3-Hydroxy-2-nitro-benzoic acid methyl ester

Benzoic acid, 3-hydroxy-2-nitro-, methyl ester

Benzoic acid, 3-hydroxy-2-nitro-, methyl ester (6CI, 7CI, 9CI, ACI)

3-hydroxy-2-nitro-Benzoic acid methyl ester (6CI 7CI 9CI ACI)

89942-77-8

Aromatic Esters