Uses
ChemicalBook > CAS DataBase List > 2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

Uses
Product Name
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
CAS No.
331465-71-5
Chemical Name
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Synonyms
TRIISOBUTYLPHOSPHATRANE;Triisobutylazaphosphatrane;2,8,9-TRIISOBUTYL-2,5,8,9-TETRA AZA-1-P&;Tri-i-butyl-tetraaza-1-phosphabicyclo-undecane;2,8,9-TRIISOBUTYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8 9-TRI-I-BUTYL-2,5,8 9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE;2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 97%;2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane,97%;2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane,97%;2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
CBNumber
CB7151853
Molecular Formula
C18H39N4P
Formula Weight
342.5
MOL File
331465-71-5.mol
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2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Property

Boiling point:
397.4±41.0 °C(Predicted)
Density 
0.964 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5020(lit.)
Flash point:
155 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.90±0.20(Predicted)
form 
Liquid
color 
Clear colorless to yellow
Sensitive 
air sensitive, moisture sensitive
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Safety

Hazard Codes 
F,Xn
Risk Statements 
36/37/38-67-66-22-19-11
Safety Statements 
26-36/37/39-16
RIDADR 
UN1155 - class 3 - PG 1 - Diethyl ether
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H319Causes serious eye irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
565881
Product name
2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Purity
97%
Packaging
1g
Price
$127
Updated
2024/03/01
Sigma-Aldrich
Product number
565881
Product name
2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Purity
97%
Packaging
5g
Price
$392
Updated
2024/03/01
Strem Chemicals
Product number
15-6020
Product name
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 97%
Packaging
250mg
Price
$51
Updated
2024/03/01
Strem Chemicals
Product number
15-6020
Product name
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 97%
Packaging
1g
Price
$117
Updated
2024/03/01
Strem Chemicals
Product number
15-6020
Product name
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 97%
Packaging
5g
Price
$466
Updated
2024/03/01
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2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Chemical Properties,Usage,Production

Uses

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.

Chemical Properties

Clear colorless to yellow liquid

Uses

Triisobutylazaphosphatrane is reported to be used as a catalyst for the preparation of biaryl and alkenylarenes via Stille cross-coupling reaction. It also acts a catalyst for the synthesis of α-aryl-substituted nitriles.

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Preparation Products And Raw materials

Raw materials

Preparation Products

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2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Suppliers

INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
CHEMOS GmbH & Co. KG
Tel
--
Fax
--
Email
chemos@chemos.de
Country
Germany
ProdList
6727
Advantage
58
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75

331465-71-5, 2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecaneRelated Search:


  • 2,8 9-TRI-I-BUTYL-2,5,8 9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-TRIISOBUTYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane,97%
  • Triisobutylazaphosphatrane
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 97%
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane solution
  • 2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
  • 4,6,11-tris(2-methylpropyl)-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane
  • TRIISOBUTYLPHOSPHATRANE
  • 2,8,9-TRIISOBUTYL-2,5,8,9-TETRA AZA-1-P&
  • Tri-i-butyl-tetraaza-1-phosphabicyclo-undecane
  • 2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane,97%
  • 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-tris(2-methylpropyl)-
  • 331465-71-5
  • C18H39N4P
  • Synthetic Reagents
  • Organic Bases
  • organophosphine ligand