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ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride

Product Name
ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride
CAS No.
175406-94-7
Chemical Name
ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride
Synonyms
Methyl 1-benzyl-3-oxo-4-piperidinecarboxylate;Methyl 1-benzyl-3-oxopiperidine-4-carboxylate;Methyl 3-oxo-1-(phenylmethyl)-4-piperidinecarboxylate;ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride;4-Piperidinecarboxylic acid, 3-oxo-1-(phenylmethyl)-, methyl ester
CBNumber
CB71522933
Molecular Formula
C14H17NO3
Formula Weight
247.29
MOL File
175406-94-7.mol
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ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride Property

Boiling point:
354.4±42.0 °C(Predicted)
Density 
1.177±0.06 g/cm3(Predicted)
pka
10.83±0.20(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Crysdot
Product number
CD11231725
Product name
Methyl1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95+%
Packaging
250mg
Price
$79
Updated
2021/12/16
Ambeed
Product number
A245104
Product name
Methyl1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95+%
Packaging
1g
Price
$85
Updated
2021/12/16
Chemenu
Product number
CM133177
Product name
methyl1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95%
Packaging
1g
Price
$189
Updated
2021/12/16
Alichem
Product number
175406947
Product name
Methyl1-benzyl-3-oxopiperidine-4-carboxylate
Packaging
1g
Price
$197.96
Updated
2021/12/16
Crysdot
Product number
CD11231725
Product name
Methyl1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95+%
Packaging
1g
Price
$240
Updated
2021/12/16
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ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride Chemical Properties,Usage,Production

Synthesis

40114-49-6

616-38-6

175406-94-7

To a stirred mixture of 1-benzyl-3-piperidone (72 g) and dimethyl carbonate (500 mL) was added sodium hydride (38 g, 60% oil dispersion) in batches. The reaction mixture was heated to reflux for 20 min and then the reaction was quenched by the slow addition of water (800 mL). The aqueous phase was extracted with ethyl acetate (3 x 400 mL), the organic phases were combined and dried over anhydrous sodium sulfate. The organic phase was concentrated under reduced pressure to give methyl 1-benzyl-3-oxopiperidine-4-carboxylate as a brown oil (93 g, 99% yield). lc-MS (ESI+): m/z 248 [M+H]+.

References

[1] Patent: WO2009/26241, 2009, A1. Location in patent: Page/Page column 77-78

ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride Suppliers

SynAsst Chemical.
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175406-94-7, ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochlorideRelated Search:


  • ethyl 1-benzyl-3-oxopiperidine-4-carboxylate hydrochloride
  • Methyl 1-benzyl-3-oxopiperidine-4-carboxylate
  • Methyl 1-benzyl-3-oxo-4-piperidinecarboxylate
  • 4-Piperidinecarboxylic acid, 3-oxo-1-(phenylmethyl)-, methyl ester
  • Methyl 3-oxo-1-(phenylmethyl)-4-piperidinecarboxylate
  • 175406-94-7