ChemicalBook > CAS DataBase List > 2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE

2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE

Product Name
2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE
CAS No.
828-81-9
Chemical Name
2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE
Synonyms
5-(2-Chlorophenyl);VITAS-BB TBB000090;IFLAB-BB F1386-0067;5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOL-2-AMINE;2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE;1,3,4-Thiadiazol-2-aMine, 5-(2-chlorophenyl)-;5-(2-CHLORO-PHENYL)-[1,3,4]THIADIAZOL-2-YLAMINE
CBNumber
CB7162141
Molecular Formula
C8H6ClN3S
Formula Weight
211.67
MOL File
828-81-9.mol
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2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE Property

Melting point:
192-195 °C
Boiling point:
393.8±44.0 °C(Predicted)
Density 
1.461±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
solid
pka
2.28±0.10(Predicted)
Appearance
Light yellow to brown Solid
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Safety

Hazard Codes 
Xi,T
Risk Statements 
25
Safety Statements 
45
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

TRC
Product number
C350815
Product name
5-(2-Chlorophenyl)-1,3,4-thiadiazol-2-amine
Packaging
250mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
009946
Product name
5-(2-Chloro-phenyl)-[1,3,4]thiadiazol-2-ylamine
Packaging
1g
Price
$113
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0033140
Product name
2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE
Purity
95.00%
Packaging
1G
Price
$721.57
Updated
2021/12/16
AK Scientific
Product number
V7899
Product name
5-(2-Chlorophenyl)-1,3,4-thiadiazol-2-amine
Packaging
10g
Price
$824
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0033140
Product name
2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE
Purity
95.00%
Packaging
2.5G
Price
$983.88
Updated
2021/12/16
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2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE Chemical Properties,Usage,Production

Synthesis

79-19-6

118-91-2

828-81-9

5.1.1 Synthesis of 5-(2-chlorophenyl)-1,3,4-thiadiazol-2-amine (68): 2-chlorobenzoic acid (5.18 g, 25 mmol) and aminothiourea (2.28 g, 25 mmol) were dissolved in POCl3 (7 ml) and stirred vigorously for 0.5 hr at 75 °C. After completion of the reaction, H2O (30 ml) was added and the mixture was heated to reflux for 4 hours. Subsequently, the reaction mixture was adjusted with 50% NaOH solution to pH 8. The precipitate was collected by filtration and the filter cake was purified by recrystallization from ethanol to give the yellow crystalline product 68 in a yield of 3.90 g, 88% yield, melting point 190-192 °C (EtOH). The product was analyzed by ESI-MS, m/z: 212.1 [M + H]+; 1H NMR (CDCl3) δ 7.45-7.50 (m, 4H), 7.60-7.62 (m, 1H), 7.99-8.01 (m, 1H). Compounds 60-81 were synthesized in the same way.

References

[1] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 8, p. 998 - 1001
[2] Bioorganic and Medicinal Chemistry, 2014, vol. 22, # 21, p. 5766 - 5775
[3] Medicinal Chemistry Research, 2018, vol. 27, # 7, p. 1800 - 1821
[4] Medicinal Chemistry Research, 2012, vol. 21, # 6, p. 816 - 824
[5] Journal of Chemical Research, 2014, vol. 38, # 6, p. 347 - 350

2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE Suppliers

Shanghai Sunway Pharmaceutical Technology Co., Ltd
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18270980682
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China
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ShangHai YuanYe Biotechnology Co., Ltd.
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Bide Pharmatech Ltd.
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Nanjing Chalf-Pharm Technology Co., Ltd.
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Amadis Chemical Company Limited
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Aikon International Limited
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Yujinpharma(Tianjin) Technology Co.,Ltd.
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China
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Jinan Liheng Biotechnology Co., Ltd.
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0531-18763987518 18763987518
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ANHUI WITOP BIOTECH CO., LTD
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View Lastest Price from 2-AMINO-5-(2-CHLOROPHENYL)-1,3,4-THIADIAZOLE manufacturers

Honest Joy Holdings Limited
Product
5-(2-Chlorophenyl)-1,3,4-thiadiazol-2-amine 828-81-9
Price
US $0.00/KG
Min. Order
1KG
Purity
97.6%
Supply Ability
100 tons
Release date
2022-02-20