ChemicalBook > CAS DataBase List > BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Product Name
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
CAS No.
12246-51-4
Chemical Name
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
Synonyms
[IrCl(COE)2]2;Chlorobis(cyclooctene)iridium(I);Bis(cyclooctene)iridium(I) chloride;Chlorobis(cyclooctene)iridium dimer;Bis(cyclooctene)di-μ-chloroiridium(I);Chlorobis(cyclooctene)iridium(Ⅰ) dimer;Di-mu-chlorobis(cyclooctene)iridium(I);CHLOROBIS(CYCLOOCTENE)IRIDIUM (I) DIMER;Chlorobis(cyclooctene)iridium(I)Dimer>Chlorobis(cyclooctene)iridium(I)dimer 97%
CBNumber
CB7171622
Molecular Formula
C32H56Cl2Ir28*
Formula Weight
896.13
MOL File
12246-51-4.mol
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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Property

Melting point:
160-165 °C (dec.) (lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Soluble in organic solvents.
form 
crystal
color 
yellow
Sensitive 
moisture sensitive, store cold
InChI
InChI=1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChIKey
WBRREXQCZAFSKS-XFCUKONHSA-L
SMILES
C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.Cl[Ir].Cl[Ir] |^1:3,4,11,12,19,20,27,28|
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377155
Product name
Chlorobis(cyclooctene)iridium(I) Dimer
Purity
97%
Packaging
1g
Price
$603
Updated
2025/07/31
Sigma-Aldrich
Product number
377155
Product name
Chlorobis(cyclooctene)iridium(I) Dimer
Purity
97%
Packaging
5g
Price
$1970
Updated
2025/07/31
TCI Chemical
Product number
C2985
Product name
Chlorobis(cyclooctene)iridium(I) Dimer
Purity
>97.0%(T)
Packaging
200mg
Price
$178
Updated
2025/07/31
Strem Chemicals
Product number
77-0250
Product name
Chlorobis(cyclooctene)iridium(I) dimer, 97%
Packaging
250mg
Price
$55
Updated
2024/03/01
Strem Chemicals
Product number
77-0250
Product name
Chlorobis(cyclooctene)iridium(I) dimer, 97%
Packaging
1g
Price
$163
Updated
2024/03/01
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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Chemical Properties,Usage,Production

Chemical Properties

Yellow solid

Uses

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

reaction suitability

core: iridium
reagent type: catalyst

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Suppliers

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View Lastest Price from BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER manufacturers

Henan Fengda Chemical Co., Ltd
Product
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER 12246-51-4
Price
US $10.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-28
henan kanbei chemical co.,ltd
Product
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER 12246-51-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Career Henan Chemical Co
Product
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER 12246-51-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

12246-51-4, BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMERRelated Search:


  • Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%
  • Chlorobis(cyclooctene)iridium dimer
  • Chlorobis(cyclooctene)iridium(Ⅰ) dimer
  • Chlorobis(cyclooctene)iridiuM(Ⅰ) diMer, 43% Ir, Product of UMicore
  • Chlorobis(cyclooctene)iridium(I)dimer 97%
  • Di-μ-chloro(tetramethyl)diiridium - (1Z)-cyclooctene (1:4)
  • Chlorobis(cyclooctene)iridium(I)
  • CHLOROBIS(CYCLOOCTENE)IRIDIUM (I) DIMER
  • DI-MU-CHLOROTETRAKIS(CYCLOOCTENE)DIIRIDIUM
  • BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
  • Bis(cyclooctene)iridium(I) chloride
  • Chlorobis(cyclooctene)iridium(I)dimer,97%
  • di-μ-chlorotetrakis(cyclooctene)diiridium
  • Chlorobis(cyclooctene)iridium(I) dimer, 43% Ir, Product of Umicore
  • Chlorobis(cyclooctene)iridium(I)Dimer&gt
  • Di-mu-chlorobis(cyclooctene)iridium(I)
  • Di-mu-chlorotetrakis(cyclooctene)diiridium(I)
  • BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER ISO 9001:2015 REACH
  • Di( μ -chloro)tetrakis(cyclooctene)diiridium(I)
  • [IrCl(COE)2]2
  • Bis(cyclooctene)di-μ-chloroiridium(I)
  • 12246-51-4
  • C32H56Cl2Ir2
  • 4C8H142ClIr
  • IrClC8H1422
  • IrCOE2Cl2
  • C36H68Cl2Ir2
  • Catalysis and Inorganic Chemistry
  • Iridium
  • Ir
  • organometallic complex