cis-Cyclooctene
- Product Name
- cis-Cyclooctene
- CAS No.
- 931-88-4
- Chemical Name
- cis-Cyclooctene
- Synonyms
- CYCLOOCTENE;Cyclooctene >CYCLOOCTENE 95%;Cyclooctene,99%;CIS-CYCLOOCTENE;CYCLOOCTENE, STANDARD FOR GC;cis-Cyclooctene ISO 9001：2015 REACH
- CBNumber
- CB4193267
- Molecular Formula
- C8H14
- Formula Weight
- 110.2
- MOL File
- 931-88-4.mol
cis-Cyclooctene Property
- Melting point:
- −16 °C(lit.)
- Boiling point:
- 32-34 °C12 mm Hg(lit.)
- Density
- 0.848 g/mL at 20 °C(lit.)
- refractive index
- n20/D 1.470
- Flash point:
- 77 °F
- Water Solubility
- Insoluble in water
- color
- Colorless to Almost colorless
- BRN
- 1901031
- LogP
- 3.930
- CAS DataBase Reference
- 931-88-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclooctene(931-88-4)
- EPA Substance Registry System
- Cyclooctene (931-88-4)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 10-65
- Safety Statements
- 29-33-62-16
- RIDADR
- UN 3295 3/PG 3
- WGK Germany
- 3
- HS Code
- 2902.19.0050
- HazardClass
- 3.2
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H304May be fatal if swallowed and enters airways
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331Do NOT induce vomiting.
N-Bromosuccinimide Price
- Product number
- 29648
- Product name
- Cyclooctene
- Purity
- analytical standard
- Packaging
- 1ml
- Price
- $52.4
- Updated
- 2022/05/15
- Product number
- C0506
- Product name
- Cyclooctene
- Purity
- >95.0%(GC)
- Packaging
- 25mL
- Price
- $50
- Updated
- 2024/03/01
- Product number
- C0506
- Product name
- Cyclooctene
- Purity
- >95.0%(GC)
- Packaging
- 500mL
- Price
- $319
- Updated
- 2024/03/01
- Product number
- FC164961
- Product name
- Cyclooctene
- Packaging
- 1kg
- Price
- $550
- Updated
- 2021/12/16
- Product number
- FC164961
- Product name
- Cyclooctene
- Packaging
- 2Kg
- Price
- $1000
- Updated
- 2021/12/16
cis-Cyclooctene Chemical Properties,Usage,Production
Purification Methods
The cis-isomer is freed from the trans-isomer by fractional distillation through a spinning-band column, followed by preparative gas chromatography on a Dowex 710-Chromosorb W GLC column. It is passed through a short alumina column immediately before use [Collman et al. J Am Chem Soc 108 2588 1986]. It has also been distilled in a dry N2 glove box from powdered fused NaOH through a Vigreux column (p 11), then passed through activated neutral alumina before use [Wong et al. J Am Chem Soc 109 4328 1987]. Alternatively it can be purified via the AgNO3 salt. This salt is obtained from crude cyclooctene (40 mL) by shaking at 70-80o with 50% w/w AgNO3 (2 x 15 mL) to remove cyclooctadienes (aqueous layer). Extraction is repeated at 40o (4 x 20 mL, of 50% AgNO3). Three layers are formed each time. The middle layer contains the AgNO3 adduct of cyclooctene which crystallises on cooling the layer to room temperature. The adduct (complex 2:1) is highly soluble in MeOH (at least 1g/mL) from which it crystallises in large flat needles when cooled at 0o. It is dried under slight vacuum for 1 week in the presence of CaCl2 and paraffin wax soaked in cyclooctene. It has m 51o and loses hydrocarbon on exposure to air. cis-Cyclooctene can be recovered by steam distillation of the salt, collected, dried (CaCl2) and distilled in vacuum. [Braude et al. J Chem Soc 4711 1957, AgNO3: Jones J Chem Soc 1808 1954, Cope & Estes J Am Chem Soc 72 1128 1950, Beilstein 5 I 35, 5 IV 263.] FLAMMABLE LIQUID.
cis-Cyclooctene Preparation Products And Raw materials
Raw materials
Preparation Products
cis-Cyclooctene Suppliers
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View Lastest Price from cis-Cyclooctene manufacturers
- Product
- cis-Cyclooctene 931-88-4
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
- Product
- Cyclooctene 931-88-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2020-01-06
- Product
- cis-Cyclooctene 931-88-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%HPLC
- Supply Ability
- 10t
- Release date
- 2019-12-23