ChemicalBook > CAS DataBase List > Chlorobis(cyclooctene)rhodium(I) dimer

Chlorobis(cyclooctene)rhodium(I) dimer

Product Name
Chlorobis(cyclooctene)rhodium(I) dimer
CAS No.
12279-09-3
Chemical Name
Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms
[Rh(coe)2Cl]2;[RhCl(cis-cyclooctene)2]2;Chlorobis(cyclooctene)rhodium(I);CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER;Chlorobis(cyclooctene)rhodium(I)dimere;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Di-μ-chlorodirhodium-cyclooctene (1:4);Chlorobis(cyclooctene)rhodiuM(I),diMer 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;Chlorobis(cyclooctene)rhodium(I) Dimer >
CBNumber
CB2429483
Molecular Formula
C32H56Cl2Rh2
Formula Weight
717.5
MOL File
12279-09-3.mol
More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Property

Melting point:
190 °C (dec.) (lit.)
storage temp. 
Freezer
form 
crystal
color 
orange to red
Sensitive 
air sensitive, store cold
CAS DataBase Reference
12279-09-3
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
No
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
250mg
Price
$127
Updated
2024/03/01
Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
1g
Price
$349
Updated
2024/03/01
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
100mg
Price
$112
Updated
2024/03/01
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
500mg
Price
$338
Updated
2024/03/01
Strem Chemicals
Product number
45-0265
Product name
Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
Packaging
250mg
Price
$117
Updated
2024/03/01
More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties,Usage,Production

Chemical Properties

orange-brown powder

Uses

Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:

  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

Uses

Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.

Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
More
Less

View Lastest Price from Chlorobis(cyclooctene)rhodium(I) dimer manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $20.00/Kg
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

12279-09-3, Chlorobis(cyclooctene)rhodium(I) dimerRelated Search:


  • [RhCl(cis-cyclooctene)2]2
  • CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
  • Chlorobis(cyclooctene)rhodium(I)
  • Chlorobis(cyclooctene)rhodium(I)dimere
  • Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
  • Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
  • Chlorobis(cyclooctene)rhodium(I) dimer,98%
  • CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
  • Chlorobis(cyclooctene)rhodiuM(I) diMer, 98% 100MG
  • Chlorobis(cyclooctene)rhodiuM(I),diMer 98%
  • [Rh(coe)2Cl]2
  • Chlorobis(cyclooctene)rhodium(I) Dimer &gt
  • Chlorobis(cyclooctene)rhodium(I) dimer ISO 9001:2015 REACH
  • Di-μ-chlorodirhodium-cyclooctene (1:4)
  • 12279-09-3
  • RhClC8H1422
  • C32H56Cl2Rh2
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium