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Chlorobis(cyclooctene)rhodium(I) dimer

Product Name
Chlorobis(cyclooctene)rhodium(I) dimer
CAS No.
12279-09-3
Chemical Name
Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms
[Rh(coe)2Cl]2;[RhCl(cis-cyclooctene)2]2;Chlorobis(cyclooctene)rhodium(I);CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER;Chlorobis(cyclooctene)rhodium(I)dimere;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Di-μ-chlorodirhodium-cyclooctene (1:4);Chlorobis(cyclooctene)rhodiuM(I),diMer 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;Chlorobis(cyclooctene)rhodium(I) Dimer >
CBNumber
CB2429483
Molecular Formula
C32H56Cl2Rh2
Formula Weight
717.5
MOL File
12279-09-3.mol
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Chlorobis(cyclooctene)rhodium(I) dimer Property

Melting point:
190 °C (dec.) (lit.)
storage temp. 
Freezer
form 
crystal
color 
orange to red
Sensitive 
air sensitive, store cold
CAS DataBase Reference
12279-09-3
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
250mg
Price
$127
Updated
2024/03/01
Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
1g
Price
$349
Updated
2024/03/01
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
100mg
Price
$112
Updated
2024/03/01
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
500mg
Price
$338
Updated
2024/03/01
Strem Chemicals
Product number
45-0265
Product name
Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
Packaging
250mg
Price
$117
Updated
2024/03/01
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Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties,Usage,Production

Chemical Properties

orange-brown powder

Uses

Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:

  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

Uses

Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.

Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Preparation Products

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Chlorobis(cyclooctene)rhodium(I) dimer Suppliers

J & K SCIENTIFIC LTD.
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View Lastest Price from Chlorobis(cyclooctene)rhodium(I) dimer manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $20.00/Kg
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

12279-09-3, Chlorobis(cyclooctene)rhodium(I) dimerRelated Search:


  • [RhCl(cis-cyclooctene)2]2
  • CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
  • Chlorobis(cyclooctene)rhodium(I)
  • Chlorobis(cyclooctene)rhodium(I)dimere
  • Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
  • Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
  • Chlorobis(cyclooctene)rhodium(I) dimer,98%
  • CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
  • Chlorobis(cyclooctene)rhodiuM(I) diMer, 98% 100MG
  • Chlorobis(cyclooctene)rhodiuM(I),diMer 98%
  • [Rh(coe)2Cl]2
  • Chlorobis(cyclooctene)rhodium(I) Dimer &gt
  • Chlorobis(cyclooctene)rhodium(I) dimer ISO 9001:2015 REACH
  • Di-μ-chlorodirhodium-cyclooctene (1:4)
  • 12279-09-3
  • RhClC8H1422
  • C32H56Cl2Rh2
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium