Chlorobis(cyclooctene)rhodium(I) dimer
- Product Name
- Chlorobis(cyclooctene)rhodium(I) dimer
- CAS No.
- 12279-09-3
- Chemical Name
- Chlorobis(cyclooctene)rhodium(I) dimer
- Synonyms
- [Rh(coe)2Cl]2;[RhCl(cis-cyclooctene)2]2;Chlorobis(cyclooctene)rhodium(I);CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER;Chlorobis(cyclooctene)rhodium(I)dimere;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Di-μ-chlorodirhodium-cyclooctene (1:4);Chlorobis(cyclooctene)rhodiuM(I),diMer 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;Chlorobis(cyclooctene)rhodium(I) Dimer >
- CBNumber
- CB2429483
- Molecular Formula
- C32H56Cl2Rh2
- Formula Weight
- 717.5
- MOL File
- 12279-09-3.mol
Chlorobis(cyclooctene)rhodium(I) dimer Property
- Melting point:
- 190 °C (dec.) (lit.)
- storage temp.
- Freezer
- form
- crystal
- color
- orange to red
- Sensitive
- air sensitive, store cold
- CAS DataBase Reference
- 12279-09-3
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 302473
- Product name
- Chlorobis(cyclooctene)rhodium(I) Dimer
- Purity
- 98%
- Packaging
- 250mg
- Price
- $127
- Updated
- 2024/03/01
- Product number
- 302473
- Product name
- Chlorobis(cyclooctene)rhodium(I) Dimer
- Purity
- 98%
- Packaging
- 1g
- Price
- $349
- Updated
- 2024/03/01
- Product number
- C2253
- Product name
- Chlorobis(cyclooctene)rhodium(I) Dimer
- Purity
- >96.0%(T)
- Packaging
- 100mg
- Price
- $112
- Updated
- 2024/03/01
- Product number
- C2253
- Product name
- Chlorobis(cyclooctene)rhodium(I) Dimer
- Purity
- >96.0%(T)
- Packaging
- 500mg
- Price
- $338
- Updated
- 2024/03/01
- Product number
- 45-0265
- Product name
- Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
- Packaging
- 250mg
- Price
- $117
- Updated
- 2024/03/01
Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties,Usage,Production
Chemical Properties
orange-brown powder
Uses
Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
- To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
- In direct C-arylation of N-unprotected indoles and pyrroles.
- In the carboxylation of arenes via C-H bond activation.
Uses
Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
reaction suitability
core: rhodium
reagent type: catalyst
Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Chlorobis(cyclooctene)rhodium(I) dimer manufacturers
- Product
- Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
- Price
- US $20.00/Kg
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11
- Product
- Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03