ChemicalBook > CAS DataBase List > 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE

2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE

Product Name
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
CAS No.
14812-59-0
Chemical Name
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
Synonyms
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxa-phosphol;2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE;1,3,2-Dioxaphospholane, 2-chloro-4,4,5,5-tetramethyl-;2-Chloro-4,4,5,5-tetraMethyl-1,3,2-dioxaphospholane 95%
CBNumber
CB7178429
Molecular Formula
C6H12ClO2P
Formula Weight
182.59
MOL File
14812-59-0.mol
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2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Property

Boiling point:
81.5-82 °C13 mm Hg(lit.)
Density 
1.149 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.471(lit.)
Flash point:
>230 °F
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
22-26-27-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
447536
Product name
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
Purity
95%
Packaging
1g
Price
$226
Updated
2024/03/01
Sigma-Aldrich
Product number
447536
Product name
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
Purity
95%
Packaging
5g
Price
$802
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
HCH0067215
Product name
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
Purity
95.00%
Packaging
5G
Price
$1219.42
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0067215
Product name
2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
Purity
95.00%
Packaging
1G
Price
$731.29
Updated
2021/12/16
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2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Chemical Properties,Usage,Production

Description

2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane is an organic reagent commonly used in chemical and experimental research as a reagent for the phosphorylation of alcohols and heteroatoms for the formation of glycosyl donors and ligands, and in analytical studies of derivatised lignin samples. It is also used as a catalyst in CuO/TiO2 catalysed lignin oxidation studies.

Chemical Properties

2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane is an organic reagent in the physical state of a solid. Molecular weight: 182.59, Density: 1.149 g/cm3, Boiling point: 81.5-82° C (lit.) at 13 mmHg, Flash point: 113 °C, Refractive index: n20/D 1.471 (lit.), Store at 10°C-25°C, keep dry, under inert gas nitrogen.

Uses

2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (TMDP) can be used:

  • As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.
  • As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.

2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Suppliers

Riedel-de Haen AG
Tel
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Fax
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Country
United States
ProdList
6773
Advantage
87
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View Lastest Price from 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-Chloro-4,4,5,5-tetraMethyl-1,3,2-dioxaphospholane 14812-59-0
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-01-17

14812-59-0, 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANERelated Search:


  • 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxa-phosphol
  • 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE
  • 2-Chloro-4,4,5,5-tetraMethyl-1,3,2-dioxaphospholane 95%
  • 1,3,2-Dioxaphospholane, 2-chloro-4,4,5,5-tetramethyl-
  • 14812-59-0
  • C6H12ClO2P
  • Phosphorus Precursors
  • Phosphorus Compounds
  • Catalysis and Inorganic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors