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Benzaldehyde dimethyl acetal

Product Name
Benzaldehyde dimethyl acetal
CAS No.
1125-88-8
Chemical Name
Benzaldehyde dimethyl acetal
Synonyms
boronic Acid Pinacol Ester;Imidazolidinone;mide;morpholinone;carbothioamide;Isoquinolinol;l Chloride;dioxaborinane;methylbenzamide;hydroxybenzamide
CBNumber
CB7187551
Molecular Formula
C9H12O2
Formula Weight
152.19
MOL File
1125-88-8.mol
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Benzaldehyde dimethyl acetal Property

Melting point:
87-89 C
Boiling point:
87-89 °C/18 mmHg (lit.)
Density 
1.014 g/mL at 25 °C (lit.)
FEMA 
2128 | BENZALDEHYDE DIMETHYL ACETAL
refractive index 
n20/D 1.493(lit.)
Flash point:
157 °F
storage temp. 
Inert atmosphere,2-8°C
form 
Liquid
color 
Clear colorless
Odor
at 100.00 %. green earthy rooty nutty vegetable spinach potato fungal almond winey
Odor Type
green
biological source
synthetic
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
JECFA Number
837
BRN 
2044501
InChIKey
HEVMDQBCAHEHDY-UHFFFAOYSA-N
LogP
2.24
CAS DataBase Reference
1125-88-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzaldehyde dimethyl acetal(1125-88-8)
EPA Substance Registry System
Benzene, (dimethoxymethyl)- (1125-88-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
23-24/25
RTECS 
CU5774000
F 
10-21
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29110000
Toxicity
LD50 orally in Rabbit: 1220 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W212806
Product name
Benzaldehyde dimethyl acetal
Purity
≥98%, FG
Packaging
1kg
Price
$191
Updated
2024/03/01
Sigma-Aldrich
Product number
W212806
Product name
Benzaldehyde dimethyl acetal
Purity
≥98%, FG
Packaging
5kg
Price
$806
Updated
2024/03/01
Sigma-Aldrich
Product number
226076
Product name
Benzaldehyde dimethyl acetal
Purity
99%
Packaging
100g
Price
$51.3
Updated
2024/03/01
Sigma-Aldrich
Product number
226076
Product name
Benzaldehyde dimethyl acetal
Purity
99%
Packaging
500g
Price
$140
Updated
2024/03/01
TCI Chemical
Product number
B1197
Product name
Benzaldehyde Dimethyl Acetal
Purity
>98.0%(GC)
Packaging
25mL
Price
$26
Updated
2024/03/01
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Benzaldehyde dimethyl acetal Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Chemical Properties

Benzaldehyde dimethyl acetal has a sweet, floral note; also reminiscent of almond

Occurrence

Reported found in rhubarb and potato.

Uses

Benzaldehyde dimethyl acetal used as an effective reagent for the construction of selenocarbonyl compounds.

Uses

Benzaldehyde dimethyl acetal is suitable for use in the synthesis of 4,6-dihydroxy sugar, required for the total synthesis of Porphyromonas gingivalis 381 derived lipid A. It may be used in the preparation of 1-O-methyl-2,3-di-O-galloyl-β-D-glucose.

Uses

Benzaldehyde dimethyl acetal may be used as an analytical reference standard for the quantification of the analyte in fresh and canned fish and Cinnamomum zeylanicum using gas-chromatography coupled to mass spectrometry (GC-MS).

Definition

ChEBI: (Dimethoxymethyl)benzene is a benzyl ether.

Preparation

From benzaldehyde and methanol in the presence of calcium chloride and HCl; from benzaldehyde and tetramethylorthosilicate in the presence of anhydrous HCl in methanol

Preparation

A mixture of ethylenediamine (1.2 g, 20 mmol), Ph3SbO (1.0 mmol), and P4S10 (2.0 mmol) was autoclaved under a pressure of CO2 (4.9 MPa). Imidazolidinone was isolated by column chromatography (silica gel; eluent: ethyl acetate/hexane, 1:1, v/v); yield 1.5 g (85%).

Taste threshold values

Taste characteristics at 25 ppm: green, nutty, brown and sweet

General Description

The abstraction of α-hydrogen atoms from benzaldehyde dimethyl acetal by active bromine at 80°C has been investigated.

Safety Profile

Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Benzaldehyde dimethyl acetal Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Benzaldehyde dimethyl acetal manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Benzaldehyde dimethyl acetal 1125-88-8
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-22
Hebei Mujin Biotechnology Co.,Ltd
Product
Benzaldehyde dimethyl acetal 1125-88-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-09
Hebei Yanxi Chemical Co., Ltd.
Product
Benzaldehyde dimethyl acetal 1125-88-8
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-10-16

1125-88-8, Benzaldehyde dimethyl acetalRelated Search:

Trimethyl orthobenzoate Benzaldehyde dimethyl acetal (+)-2,3-O-BENZYLIDENE-D-THREITOL Triethyl orthobenzoate 2-(3-BROMOPHENYL)-1,3-DIOXOLANE 4-(DIETHOXYMETHYL)BENZALDEHYDE 2,2-Dimethoxy-2-phenylacetophenone METHYL 4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE Fluorescamine P-ANISALDEHYDE DIMETHYL ACETAL 4-(Methoxycarbonyl)benzaldehyde dimethyl acetal 4-N-PROPYLBENZALDEHYDE DIETHYL ACETAL RARECHEM AL BP 0018 3-(2-METHYL-1,3-DIOXOLAN-2-YL)ANILINE 4-BUTYLBENZALDEHYDE DIETHYL ACETAL 4,7-DIHYDRO-2-PHENYL-1,3-DIOXEPIN 2-METHYL-2-(3-NITROPHENYL)-1,3-DIOXOLANE 4-(HYDROXYMETHYL)BENZALDEHYDE DIMETHYL ACETAL,4-(HYDROXYMETHYL)BENZALDEHYDE DIMETHYL ACETAL 98+%

  • (dimethoxymethyl)-benzen
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  • Benzaldehyde diMethyl acetal, 98% 100ML
  • Benzaldehyde diMethyl acetal, 98% 250ML
  • Benzaldehde diMethyl acetal
  • Benzaldehyde diMethyl acetal, 97.5%
  • BENZALDEHYDE DIMETHYL ACETAL FOR SYNTHES
  • Intedanib Impurity 8
  • Nitrophenethylamine Hydrochloride
  • Dipropoxybutane
  • dehyde dimethyL
  • a,a-dimethoxytoluene
  • Benzene, (dimethoxymethyl)-
  • Dimethoxyphenylmethane
  • Toluene, alpha,alpha-dimethoxy-
  • BENZALDEHYDE DIMETHYL ACETAL
  • DIMETHOXYMETHYL-BENZENE
  • FEMA 2128
  • ALPHA,ALPHA-DIMETHOXYTOLUENE
  • BENZALDEHYDE DIMETHYL ACETAL 98+%
  • BENZALDEHYDE DIMETHYL ACETAL 99%
  • Benzaldehyde dimethyl acetal, 99+%
  • à,à-dimethoxytoluene
  • α,α-Dimethoxytoluene
  • Benzaldehyde Dimethyl Acetal (BADMA)
  • Benzylidenebis(methyl ether)
  • 1-(Dimethoxymethyl)-benzene
  • benzaldehyde dimethyl acettal
  • Dihydroxybenzoate
  • Cyanoethanesulfonyl Chloride
  • Methoxyphenyl Bromide)
  • benzodioxaborole
  • ylmethyl Carbamimidothioate Hydrochloride
  • phosphine Complex
  • amine Trifluoroacetate
  • ketohexanoate
  • hydroxy-2-naphthalenesulfonic Acid
  • dioxaborinane
  • Trifluoro-benzeneacetic acid methyl ester
  • Nitrophenylhydrazine (wet with 30% water w/w), 97%
  • -phenol O-&alpha
  • Nitrophenyl Isocyanate
  • dicarboxylate|(1,4-Cyclohexanedicarboxylic Dimethyl Ester)
  • Difluorocyclohexanol
  • Fluorophenyl Isocyanate
  • m) Salt
  • Methylnaphthalene-D10
  • mide
  • methylbenzamide
  • ylpropanoic Acid Hydrochloride
  • methyloctyl)cyclohexyl-1,2-dicarboxylate
  • Imidazolidinone
  • diol ethoxylate (Avg Mn 465-485)
  • Aminoquinaldine
  • 2-Dimethylcyclobutanamine Hydrochloride
  • hydroxypentyl) Phthalate
  • Dimethylphenol-13C3|(1,3,5-Xylenol-13C3)
  • m Hexafluorophosphate