ChemicalBook > CAS DataBase List > METHYL 3-OXOTETRADECANOATE
METHYL 3-OXOTETRADECANOATE
Synthesis- Product Name
- METHYL 3-OXOTETRADECANOATE
- CAS No.
- 22348-97-6
- Chemical Name
- METHYL 3-OXOTETRADECANOATE
- Synonyms
- Orlistat Impurity 61;Metyl lauroyl acetate;Methyl β-KetoMyristate;Methyl b-ketomyristate;Methyl Lauroyl Acetate;METHYL 3-OXOTETRADECANOATE;METHYL 3-KETOTETRADECANOATE;3-Oxomyristic acid methyl ester;3-Ketomyristic acid methyl ester;3-Oxotetradecanoic acid methyl ester
- CBNumber
- CB7187955
- Molecular Formula
- C15H28O3
- Formula Weight
- 256.38
- MOL File
- 22348-97-6.mol
More
Less
METHYL 3-OXOTETRADECANOATE Property
- Melting point:
- 29-30°C
- Boiling point:
- 137-139 °C(Press: 0.9 Torr)
- Density
- 0.926±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,2-8°C
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
- form
- Solid
- pka
- 10.65±0.46(Predicted)
- color
- Light Yellow to Yellow
- LogP
- 5.500 (est)
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H413May cause long lasting harmful effects to aquatic life
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
P501Dispose of contents/container to..…
More
Less
N-Bromosuccinimide Price
TRC
- Product number
- M325865
- Product name
- Methyl3-Oxotetradecanoate
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 089325
- Product name
- Methyl 3-oxotetradecanoate
- Packaging
- 1g
- Price
- $151
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 089325
- Product name
- Methyl 3-oxotetradecanoate
- Packaging
- 5g
- Price
- $670
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0067306
- Product name
- METHYL 3-OXOTETRADECANOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $739.2
- Updated
- 2021/12/16
AK Scientific
- Product number
- Q506
- Product name
- Methyl3-Oxotetradecanoate
- Packaging
- 5g
- Price
- $873
- Updated
- 2021/12/16
More
Less
METHYL 3-OXOTETRADECANOATE Chemical Properties,Usage,Production
Synthesis
The carboxylic acid (13.8 g, 69 mmol, 1.0 equivalents) was dissolved in dry THF under an inert atmosphere and cooled to 0 ºC. CDI (13.4 g, 83 mmol, 1.2 equivalents) was then added in small portions over several minutes. After 10 min, the reaction was allowed to warm slowly to room temperature and was then stirred for 1 h. In a separate flflask, monomethyl malonate (9.8g, 83 mmol, 1.2 equivalents) was dissolved in THF under an inert atmosphere and cooled to −78 ºC. To this solution was added dibutylmagnesium (1.0 M in heptane, 0.6 equivalents). A white solid formed instantly on addition of the base. After 10 min, the reaction was warmed to room temperature and stirred for 1 h. The acylimidazole was then added by cannula to the flflask containing the magnesium salt. The resulting slurry was stirred for 3 days. The reaction mixture was then concentrated on a rotary evaporator and the residue redissolved in EtOAc. The resulting solution was washed with 1.2 M HCl, saturated aqueous NaHCO3, and brine. The organic phase was dried over sodium sulfate, fifiltered, concentrated, and the residue purifified by flflash chromatography (7:1 hexanes:EtOAc) to give the β-keto ester (14.7g, 83%).
Reference: Durham, T. B.; Miller, M. J. J. Org. Chem. 2003, 68, 27–34.
Chemical Properties
Yellow Crystalline Solid
Uses
Methyl 3-Oxotetradecanoate (cas# 22348-97-6) is a compound useful in organic synthesis.
METHYL 3-OXOTETRADECANOATE Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
METHYL 3-OXOTETRADECANOATE Suppliers
- Tel
- 029-029-2148545164 17392779578
- 2148545164@qq.com
- Country
- China
- ProdList
- 4818
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 94657
- Advantage
- 76
- Tel
- 821-50328103-801 18930552037
- Fax
- 86-21-50328109
- 3bsc@sina.com
- Country
- China
- ProdList
- 15839
- Advantage
- 69
- Tel
- 400-6009262 16621234537
- Fax
- 021-64823266
- chenyj@titansci.com
- Country
- China
- ProdList
- 14103
- Advantage
- 59
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32321
- Advantage
- 50
- Tel
- 21-58388037 13472507714
- Fax
- 0086-21-56829747 Company QQ: 1589045147
- 1589045147@qq.com
- Country
- China
- ProdList
- 738
- Advantage
- 55
- Tel
- 027-87465837 19945049750
- Fax
- 027-8777-2287
- sales@finetechnology-ind.com
- Country
- China
- ProdList
- 9648
- Advantage
- 58
- Tel
- 0373-7129549; 13598610367
- Fax
- QQ:2468833170
- 2841375912@qq.com
- Country
- China
- ProdList
- 2725
- Advantage
- 52
- Tel
- 028-67136579 15828051124
- sales@kamelpharm.com
- Country
- China
- ProdList
- 1912
- Advantage
- 55
- Tel
- 0512-56316828
- Fax
- 0512-56316826
- info@amateksci.com
- Country
- China
- ProdList
- 28806
- Advantage
- 58
- Tel
- 025-58851090 13611564524
- Fax
- (6)02557626880
- lwan@aikonchem.com
- Country
- China
- ProdList
- 15951
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57423
- Advantage
- 58
- Tel
- +8615866703830
- figo.gao@foxmail.com
- Country
- China
- ProdList
- 8497
- Advantage
- 58
- Tel
- 0371-0371-55055611 18137792234
- Fax
- QQ：3002694073
- 3002694073@qq.com
- Country
- China
- ProdList
- 10447
- Advantage
- 58
- Tel
- meitaochem@126.com
- meitaochem@126.com
- Country
- China
- ProdList
- 19103
- Advantage
- 58
- Tel
- +86-27-87465837 +8618971612321
- Fax
- 86 27 87772287
- info@finetechnology-ind.com
- Country
- China
- ProdList
- 9639
- Advantage
- 58
- Tel
- +86-0571-81612335 +8613336028439
- sales@nextpeptide.com
- Country
- China
- ProdList
- 19908
- Advantage
- 58
- Tel
- 571-88938639 +8617705817739
- Fax
- +86-571-88938652，+86-571- 88492614
- info@dycnchem.com
- Country
- China
- ProdList
- 52849
- Advantage
- 58
- Tel
- 021-51698675
- jiejiegroup@126.com
- Country
- China
- ProdList
- 4290
- Advantage
- 58
- Tel
- 021-58461859 15821823057
- service@aiviche.com
- Country
- China
- ProdList
- 49312
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- Fax
- 0086-371-86658258
- factory@coreychem.com
- Country
- China
- ProdList
- 29811
- Advantage
- 58
- Tel
- 027-19371-3712 19371278702
- Fax
- QQ：2462856504
- n17762444226@163.com
- Country
- China
- ProdList
- 3011
- Advantage
- 58
- Tel
- 027-0185-0185-07139096-265 19371278702
- Fax
- QQ:1925957016
- 18507139096@163.com
- Country
- China
- ProdList
- 2821
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing@energy-chemical.com
- Country
- China
- ProdList
- 44918
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44458
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 39995
- Advantage
- 58
- Tel
- 0755-66853366; 13670046396
- ORDERS@QCSRM.COM
- Country
- China
- ProdList
- 24342
- Advantage
- 58
- Tel
- 400-1647117 13681763483
- product02@bidepharm.com
- Country
- China
- ProdList
- 62075
- Advantage
- 58
- Tel
- 15870833005
- 2232044025@qq.com
- Country
- China
- ProdList
- 8206
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39653
- Advantage
- 58
- Tel
- 13129948835
- 2756772312@qq.com
- Country
- China
- ProdList
- 5007
- Advantage
- 58
- Tel
- 2122619822
- czbjpharma@126.com
- Country
- China
- ProdList
- 18478
- Advantage
- 58
- Tel
- +86-027-59232304 15387063101
- 2881924050@qq.com
- Country
- China
- ProdList
- 9956
- Advantage
- 58
- Tel
- 029-87576359 15353716720
- 1039@dideu.com
- Country
- China
- ProdList
- 10009
- Advantage
- 58
- Tel
- 021-50706066 15221275939
- shenlinxing@macklin.cn
- Country
- China
- ProdList
- 29902
- Advantage
- 58
- Tel
- 18951783565 18951783565
- sales@popebiotech.com
- Country
- China
- ProdList
- 1120
- Advantage
- 58
- Tel
- 010-57903446 15869909019
- 168931144@qq.com
- Country
- China
- ProdList
- 4965
- Advantage
- 58
- Tel
- 010-50973130 17801761073
- Gsiyu@solarbio.com
- Country
- China
- ProdList
- 50464
- Advantage
- 58
- Tel
- 021-57520305 15221441005
- wangkang@jskchem.com
- Country
- China
- ProdList
- 49234
- Advantage
- 58
- Tel
- 15552437730
- 1701654643@qq.com
- Country
- China
- ProdList
- 9167
- Advantage
- 58
- Tel
- 029-15596886083 15596886083
- 739383595@qq.com
- Country
- China
- ProdList
- 3901
- Advantage
- 58
- Tel
- +86-18521732826
- market@aladdin-e.com
- Country
- China
- ProdList
- 48461
- Advantage
- 58
- Tel
- 86-13349903920; 13349903920
- Fax
- -
- 869523959@qq.com
- Country
- China
- ProdList
- 9693
- Advantage
- 58
- Tel
- 15866847540
- dengyt2000@163.com
- Country
- China
- ProdList
- 4100
- Advantage
- 58
- Tel
- 18317763565 18317763565
- 18317763565@163.com
- Country
- China
- ProdList
- 10042
- Advantage
- 58
- Tel
- 18171205315
- 1213219329@qq.com
- Country
- China
- ProdList
- 5112
- Advantage
- 58
- Tel
- 15553348166
- m15553348166@163.com
- Country
- China
- ProdList
- 15200
- Advantage
- 58
- Tel
- +8613817748580
- Fax
- 021-50175322
- cooperation@kean-chem.com
- Country
- China
- ProdList
- 40066
- Advantage
- 58
- Tel
- +86-2552131256 +86-18251840740
- sales@bicbiotech.com
- Country
- China
- ProdList
- 5994
- Advantage
- 58
- Tel
- +86-755-89396905 +86-15013857715
- admin@nexconn.com
- Country
- China
- ProdList
- 10311
- Advantage
- 58
More
Less
View Lastest Price from METHYL 3-OXOTETRADECANOATE manufacturers
Career Henan Chemical Co
- Product
- METHYL 3-OXOTETRADECANOATE 22348-97-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%HPLC
- Supply Ability
- 10t
- Release date
- 2019-12-24
22348-97-6, METHYL 3-OXOTETRADECANOATERelated Search:
BUTYL LAURATE
ISOPROPYL LAURATE
Dodecanamide
Lauroyl chloride
Sodium lauroyl glutamate
METHYL 3-OXOTETRADECANOATE
methyl 3-oxooctadecanoate
TRIMETHYLOLPROPANE TRIISOOCTADECANOATE
ETHYL 3-OXOTETRADECANOATE
methyl 3-oxohexadecanoate
3-OCTADECANOYLUMBELLIFERONE
ETHYL STEAROYLACETATE
LEVORIN A2
RK-682
METHYL-ALPHA-OCTADECANOYL ACETATE
trichorabdal C
trichorabdal B