2,3,4,6-Tetra-O-benzyl-D-glucopyranose

Product Name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
CAS No.: 4132-28-9
Chemical Name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Synonyms: (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)Methyl)tetrahydro-2H-pyran-2-ol;2,3,4, 6-4-o-benzyl-d-pyranoglucose;ucopyranose;Voglibose Impurity 4;2,3,4,6-Tetra-O-benz;Garlic oil 8000-78-0;benzyl-D-glucopyranose;Voglibose Intermediates;2,3,4,6-TETRABENZYL-D-GLUCOSE;Tetra-O-benzyl-D-glucopyranose
CBNumber: CB7194124
Molecular Formula: C34H36O6
Formula Weight: 540.65
MOL File: 4132-28-9.mol

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2,3,4,6-Tetra-O-benzyl-D-glucopyranose Property

Melting point:: 145-149 °C(lit.)
Boiling point:: 672.4±55.0 °C(Predicted)
Density: 1.22±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Store in freezer, under -20°C
solubility: Soluble in chloroform
pka: 11.87±0.70(Predicted)
form: Solid
color: White to Off-White
optical activity: [α]20/D +49±2°, c = 2% in dioxane
InChI: InChI=1S/C34H36O6/c35-34-33(39-24-29-19-11-4-12-20-29)32(38-23-28-17-9-3-10-18-28)31(37-22-27-15-7-2-8-16-27)30(40-34)25-36-21-26-13-5-1-6-14-26/h1-20,30-35H,21-25H2/t30-,31-,32+,33-,34?/m1/s1
InChIKey: OGOMAWHSXRDAKZ-BKJHVTENSA-N
SMILES: OC1O[C@H](COCC2=CC=CC=C2)[C@@H](OCC2=CC=CC=C2)[C@H](OCC2=CC=CC=C2)[C@H]1OCC1=CC=CC=C1
CAS DataBase Reference: 4132-28-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-24/25
WGK Germany: 3
HS Code: 29400090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 86730
Product name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Purity: ≥98.0% (TLC)
Packaging: 1g
Price: $26
Updated: 2024/03/01

Sigma-Aldrich

Product number: 86730
Product name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Purity: ≥98.0% (TLC)
Packaging: 5g
Price: $60.5
Updated: 2024/03/01

TCI Chemical

Product number: T1914
Product name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $43
Updated: 2024/03/01

TCI Chemical

Product number: T1914
Product name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Purity: >97.0%(HPLC)
Packaging: 5g
Price: $117
Updated: 2024/03/01

Alfa Aesar

Product number: H27888
Product name: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose, 98+%
Packaging: 1g
Price: $45.65
Updated: 2024/03/01

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2,3,4,6-Tetra-O-benzyl-D-glucopyranose Chemical Properties,Usage,Production

Description

2,3,4,6-Tetra-O-benzyl-D-glucopyranose is an important D-glucopyranose derivative, which is often used as a pharmaceutical intermediate in the synthesis of derivatives for the treatment of Alzheimer's disease, diabetes, and cancer.

Chemical Properties

White Crystaline Solid

Uses

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (cas# 4132-28-9) is a compound useful in organic synthesis. For example, it enables the preparation of α-glucopyranosyl chloride as well as 1-C-α-D-glucopyranosyl derivatives; it can also be used in the preparation of important D-glucopyranosyl derivatives for glucosylation and other reactions.

Synthesis

Add 19.4g of 2,3,4,6-tetra-O-benzyl-β-D-glucosinolate to 500mL of acetone, and add 18.7g of N-bromosuccinyl in batches with stirring Imine (NBS), after the addition, react at 25°C for 0.5h. Most of the acetone was evaporated under reduced pressure, and a white solid was precipitated, which was diluted by adding 200 mL of 1mol/L hydrochloric acid and allowed to stand at -18°C for 3h. After suction filtration, the filter cake was washed with cold absolute ethanol, and recrystallized with absolute ethanol-cyclohexane to obtain 15.6 g of white flocculent solid 2,3,4,6-Tetra-O-benzyl-D-glucopyranose with a yield of 96.6%.

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,4,6-Tetra-O-benzyl-D-glucopyranose Suppliers

Canada 1 China 353 Czech 1 Germany 7 India 22 Japan 2 Slovakia 1 Switzerland 5 United Kingdom 14 United States 36 Global 442

Huangshi Healthday Pharmaceutical Technology Co.,Ltd.

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View Lastest Price from 2,3,4,6-Tetra-O-benzyl-D-glucopyranose manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 4132-28-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-24

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 4132-28-9
Price: US $10.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2021-04-28

Henan Aochuang Chemical Co.,Ltd.

Product: 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 4132-28-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-29

4132-28-9, 2,3,4,6-Tetra-O-benzyl-D-glucopyranoseRelated Search:

Tetrahydropyran Centchroman Benzyl benzoate BENZYL GLYCIDYL ETHER Benzyltrimethylammonium chloride N,N-Dimethylbenzylamine 2,3,4,6-TETRA-O-BENZYL-ALPHA-D-GLUCOPYRANOSE Dibenzylideneacetone Benzyl chloride Benzyl alcohol Benzyltriethylammonium chloride Benzyl bromide DEXTROSE 2,3,4,6-TETRA-O-BENZOYL-BETA-D-GLUCOPYRANOSYL ISOTHIOCYANATE (R)-Valiolamine Voglibose (2S,3S,4S,5S)-5-Hydroxy-2,3,4-tris(phenylMethoxy)-5-[(phenylMethoxy)Methyl]-cyclohexanone Valiolamine (S)-Valiolamine Voglibose

2,3,4,6-Tetra-O-benzyl-D-glucopyranose(for Voglibose)

Voglibose Impurity 4

2,3,4, 6-4-o-benzyl-d-pyranoglucose

2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSE , MIXTURE OF ANOMERS

3,4,5-Tris(benzyloxy)-6-(benzyloxymethyl)

3,4,5-TRIS(BENZYLOXY)-6-[(BENZYLOXY)METHYL]OXAN-2-OL

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]oxan-2-ol

2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSE, 98%, MIXTURE OF ANOMERS

3,4,5-Tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-ol

2,3,4,6-TETRA-O-BENZYL-D -GLUCOPYRANOSE CRYSTALLINE

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

2,3,4,6-TETRABENZYL-D-GLUCOSE

D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-

2,3,4,6-TETRA-O-BENZYL-A-D-GLUCOPYRANOSIDE

2,3,4,6-Tetra-O-benzyl-D-glucopyranose, 98+%

2,3,4,6-Tetra-O-benzyl-α-D-glucopyranose ,97%

2,3,4,6-Tetrakis-O-(phenylmethyl)-D-glucopyranose

2,3,4,6-Tetra-O-benz

Tetra-O-benzyl-D-glucopyranose

benzyl-D-glucopyranose

(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)Methyl)tetrahydro-2H-pyran-2-ol

ucopyranose

Tetra-O-Benzyl-D-Glucopyranose(2,3,4,6-Tetra-O-benzyl-D-glucopyranose)

2,3,4,6-Tetra-O-benzyl-D-glucopyranose ISO 9001：2015 REACH

2,3,4,6-Tetra-O-benzyl-O-glucopyranose

(3R,4S,5R,6R)-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-ol

Garlic oil 8000-78-0

Voglibose Intermediates

2,3,4,6-Tetrabenzyl-D-Glucopyranose

2,3,4,6-Tetra-O-benzyl-D-glucopyranose,NA

2,3,4,6-Tetra -0- benzyl- α -D- gluco pyranose

2,3,4,6-Tetrakis-O-benzyl-D-glucopyranose

4132-28-9

4132-28-9 6564-72-3

4231-28-9

Halogenated Heterocycles ,Pyrazoles

Biochemistry

Glucose

O-Substituted Sugars

Sugars

aldehydes

Carbohydrates & Derivatives

Carbohydrate Synthesis

Monosaccharides

Specialty Synthesis

Carbohydrates

Carbohydrates A to

Carbohydrates P-ZBiochemicals and Reagents

Monosaccharide

13C & 2H Sugars

Glycon Biochem