(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE

Application

Product Name: (1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE
CAS No.: 207129-35-9
Chemical Name: (1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE
Synonyms: QCI;QUINCORINE;Quincorine >Quincorine (QCI);(1S 2S 5R)-2-HYDROXYMETHYL-5-VINYL- &;(2S,4S,5R)-5-VINYLQUINUCLIDINE-2-METHANOL;(1S,2S,5S)-5-VINYL-2-QUINUCLIDINEMETHANOL;(1S,2S,5R)-5-Vinyl-2-quinuclidinemethanol;((1S,2S,5S)-5-Vinylquinuclidin-2-yl)methanol;(1S,2S,5R)-2-Hydroxymethyl-5-vinylquinuclidine
CBNumber: CB7205941
Molecular Formula: C10H17NO
Formula Weight: 167.25
MOL File: 207129-35-9.mol

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(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE Property

Melting point:: 25-27 °C(lit.)
Boiling point:: 270 °C(lit.)
Density: 1.051 g/mL at 20 °C(lit.)
refractive index: 39 ° (C=1, MeOH)
storage temp.: 2-8°C
pka: 14.70±0.10(Predicted)
form: powder to lump to clear liquid
color: White or Colorless to Yellow

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
HS Code: 2933.99.9701

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: Q0074
Product name: Quincorine
Purity: >98.0%(GC)
Packaging: 1g
Price: $456
Updated: 2024/03/01

TCI Chemical

Product number: Q0074
Product name: Quincorine
Purity: >98.0%(GC)
Packaging: 100mg
Price: $75
Updated: 2024/03/01

TRC

Product number: Q670305
Product name: Quincorine
Packaging: 100mg
Price: $310
Updated: 2021/12/16

AK Scientific

Product number: 4019AL
Product name: (1S,2S,5S)-2-(Hydroxymethyl)-5-vinylquinuclidine
Packaging: 100mg
Price: $230
Updated: 2021/12/16

AK Scientific

Product number: 4019AL
Product name: (1S,2S,5S)-2-(Hydroxymethyl)-5-vinylquinuclidine
Packaging: 1g
Price: $926
Updated: 2021/12/16

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(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE Chemical Properties,Usage,Production

Application

In 1820, it was first isolated and purified from quina bark powder and proved to be an effective drug for treating malaria. In addition to its medicinal value, quinine is also an important chiral catalyst in the field of organic synthesis and is widely used in the field of asymmetric catalysis of small organic molecules.

Synthesis

TBAF (1M solution of THF, 37 ??L, 0.037 mmol) was added to a solution of 21c (8 mg, 0.028 mmol) in THF (1 mL) at 0 ??C. The solution was allowed to warm to ambient temperature. concentrated after 12 h. (1S,2S,5S)-2-(hydroxymethyl)-5-vinylquinuclidine ring (21b, 5.1 mg, 78%) was obtained by preparative TLC (CH2Cl2 / MeOH 2:1) as an anhydrous oil.

(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE Suppliers

China 50 India 2 Japan 1 Switzerland 1 United Kingdom 1 United States 7 Global 62

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207129-35-9, (1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINERelated Search:

QUINIDINE GLUCONATE (1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE O-Desmethyl Quinine CINCHONIDINE SULFATE QUININE BISULFATE HEPTAHYDRATE QUININE FORMATE QUININE VALERATE Quinine N-Benzylcinchonidinium chloride Quinine hydrochloride dihydrate Quinine sulfate dihydrate QUININE SULFATE Cinchonidine Quinine hydrochloride QUININE GLUCONATE QUININE GLYCEROPHOSPHATE CINCHONIDINE HYDROCHLORIDE QUININE ACETATE

(1S,2S,5S)-5-VINYL-2-QUINUCLIDINEMETHANOL

(1S,2S,5S)-2-(HYDROXYMETHYL)-5-VINYLQUINUCLIDINE

(2S,4S,5R)-5-VINYLQUINUCLIDINE-2-METHANOL

(2S,4S,5R)-2-HYDROXYMETHYL-5-VINYLQUINUCLIDINE

QCI

QUINCORINE

(1S 2S 5R)-2-HYDROXYMETHYL-5-VINYL- &

(1S,2S,5R)-2-Hydroxymethyl-5-vinylquinuclidine

(1S,2S,5R)-5-Vinyl-2-quinuclidinemethanol

(1S,2S,5R)-5-Vinyl-2-quinuclidinemethanol,(sum of enantiomers,GC)

(1S,2S,5S)-2-(Hydroxymethyl)-5-vinylquinuclidine (1S,2S,5S)-5-Vinyl-2-quinuclidinemethanol

1-Azabicyclo[2.2.2]octane-2-Methanol,5-ethenyl-, (1S,2S,4S,5R)-

((1S,2S,5S)-5-Vinylquinuclidin-2-yl)methanol

(1S,2S,4S,5R)-5-Ethenyl-1-azabicyclo[2.2.2]octane-2-methanol

Quincorine &gt

Quincorine (QCI)

207129-35-9