ChemicalBook > CAS DataBase List > LITHIUM METABORATE

LITHIUM METABORATE

Product Name
LITHIUM METABORATE
CAS No.
13453-69-5
Chemical Name
LITHIUM METABORATE
Synonyms
Boricacidlithiumsalt;SPECTROMELT C 20;SPECTROMELT A 20;Lithiummetaborat;ithium metaborate;LITHIUM METABORATE;SPECTROMELT(R) C20;LITHIUM BORATE (META);LITHIUM METABORATE AR;lithium metaborate, acs
CBNumber
CB7208760
Molecular Formula
BH2LiO2
Formula Weight
51.76
MOL File
13453-69-5.mol
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LITHIUM METABORATE Property

Melting point:
845 °C (lit.)
Density 
1,4 g/cm3
bulk density
1300kg/m3
storage temp. 
Store at +5°C to +30°C.
solubility 
soluble in ethanol.
form 
Powder
Specific Gravity
1.4
color 
White
Water Solubility 
Soluble in water(27.5g/L).
Sensitive 
Hygroscopic
Exposure limits
ACGIH: TWA 2 mg/m3; STEL 6 mg/m3
Stability:
Stable.
CAS DataBase Reference
13453-69-5(CAS DataBase Reference)
EPA Substance Registry System
Lithium metaborate (13453-69-5)
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Safety

Risk Statements 
20/21/22-41
Safety Statements 
24/25
WGK Germany 
1
F 
3
TSCA 
Yes
HS Code 
2840 20 90
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
205524
Product name
Lithium metaborate
Purity
99.9% trace metals basis
Packaging
100g
Price
$123
Updated
2024/03/01
Sigma-Aldrich
Product number
205524
Product name
Lithium metaborate
Purity
99.9% trace metals basis
Packaging
500g
Price
$471
Updated
2024/03/01
Sigma-Aldrich
Product number
1.12996
Product name
Spectromelt A 20
Purity
lithium metaborate
Packaging
1kg
Price
$899
Updated
2024/03/01
Alfa Aesar
Product number
010739
Product name
Lithium metaborate, Puratronic?, 99.997% (metals basis)
Packaging
100g
Price
$302
Updated
2024/03/01
Alfa Aesar
Product number
010739
Product name
Lithium metaborate, Puratronic?, 99.997% (metals basis)
Packaging
25g
Price
$88.1
Updated
2023/06/20
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LITHIUM METABORATE Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Lithium Metaborate is commonly used as a fused compound or a component for an assay. It has been used for the analysis of wild rice for silicon, calcium, magnesium and potassium. Lithium metaborate was used to fuse with solid samples for decomposition.

Uses

Lithium metaborate is used for flux.

Preparation

Lithium metaborate, LiBO2, may be prepared by fusing together either lithium hydroxide or lithium carbonate and boric acid in the proper stoichiometric ratio. Recrystallization from water at about room temperature yields lithium metaborate- octahydrate, LiBO2·8H2O. The octahydrate may be dried to yield a dihydrate, LiBO2-2H2O, or a half-hydrate, LiBO2·0.5H2O.

General Description

Lithium metaborate (LiBO2) is the lithium salt of boric acid. It can be synthesized by reacting orthoboric acid with lithium carbonate. Its crystals belong to the monoclinic crystal system having space group P21/c. Three polymorphic forms have been identified on ambient pressure devitrification of LiBO2: α-, γ- and β′-LiBO2.

Flammability and Explosibility

Not classified

Structure and conformation

Lithium metaborate has several crystal forms. 
Below 100 °C, LiBO2·8H2O is firstly dehydrated to a lower hydrate LiBO2·2H2O [1].
When the temperature is higher than 190°C, the dehydrated amorphous hydrate could crystallize into other poorly crystalline phases designated as LiBO2·xH2O (x=0.3/0.5)[2]. 
An anhydrous monoclinic α-LiBO2 could be obtained when the baking temperature reaches 600 °C. The α form consists of infinite chains of trigonal planar metaborate anions [BO2O-]n.
At 950 °C, by applying 15 kbar of pressure to a LiCl flux containing α-LiBO2, α-LiBO2 could be converted to metastable γ-LiBO2 crystals which were small, but of high quality[3]. γ-LiBO2 has tetragonal symmetry with lattice parameter a=4.1961 ?, c=6.5112 ?, space group I-42d and a density of 2.882 g/cm3.

References

[1] E.I.Kamitsos, A.P.Patsis, M.A.Karakassides, G.D.Chryssikos, Infrared reflectance spectra of lithium borate glasses, Journal of Non-Crystalline Solids, 1990, 126, 52-67.
[2] Li Lei, Duanwei He, Kai He, Jiaqian Qin, Shanmin Wang, Pressure-induced coordination changes in LiBO2, Journal of Solid State Chemistry, 2009, 182, 3041-3048.
[3] Colin D. McMillen, Henry G. Giesber, Joseph W. Kolis, The hydrothermal synthesis, growth, and optical properties of γ-LiBO2, Journal of Crystal Growth, 310, 2008, 299-305.

LITHIUM METABORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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LITHIUM METABORATE Suppliers

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View Lastest Price from LITHIUM METABORATE manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
LITHIUM METABORATE 13453-69-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-31
Shandong Deshang Chemical Co., Ltd.
Product
LITHIUM METABORATE 13453-69-5
Price
US $6.00-3.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-08-15
Hebei Weibang Biotechnology Co., Ltd
Product
LITHIUM METABORATE 13453-69-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-13

13453-69-5, LITHIUM METABORATERelated Search:

BARIUM METAPHOSPHATE Lithium sulfide Barium boron oxide Lithium tetraborate Strontium carbonate Lithium bromide Sodium metaborate Metaphosphoric acid Magnesium titanium oxide Aluminum metaphosphate SODIUM METASILICATE PENTAHYDRATE AMMONIUM (META)TUNGSTATE HYDRATE Sodium metavanadate METABORIC ACID Lithium hydroxide Lithium hydroxide monohydrate LITHIUM METABORATE DIHYDRATE Lithium

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  • LiBO28H2O
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