ChemicalBook > CAS DataBase List > (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

Product Name
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS No.
158923-09-2
Chemical Name
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
Synonyms
JOSIPHOS SL-J004-1;OSIPHOS SL-J004-1;(R)1[(1S)2(di-C-hex;(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin;R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...;(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
CBNumber
CB7211931
Molecular Formula
C36H44FeP210*
Formula Weight
594.53
MOL File
158923-09-2.mol
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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Property

alpha 
-100° ±5° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
F 
10
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
100mg
Price
$96.8
Updated
2024/03/01
Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
1g
Price
$727
Updated
2024/03/01
Strem Chemicals
Product number
26-1230
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
26-1230
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%
Packaging
500mg
Price
$375
Updated
2024/03/01
Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
500mg
Price
$442
Updated
2023/06/20
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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties,Usage,Production

Chemical Properties

Red crystal

Uses

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

  • To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
  • In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Reactions

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .

General Description

sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Suppliers

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158923-09-2, (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINERelated Search:

ETHYLDIPHENYLPHOSPHINE (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE DICYCLOHEXYLPHOSPHINE 1,3-BIS(PHOSPHINO)PROPANE TRIISOPROPYLPHOSPHINE TRIHEXYLPHOSPHINE

  • (R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
  • (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE
  • (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
  • (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin
  • (R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&
  • (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%
  • (r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas)
  • (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
  • Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS)
  • (R)1[(1S)2(di-C-hex
  • (S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino
  • JOSIPHOS SL-J004-1
  • OSIPHOS SL-J004-1
  • (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine >=97%
  • Ferrocene, 1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-, (1R)-
  • (R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
  • R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...
  • (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (ACI)
  • 158923-09-2
  • C36H44FeP2
  • C31H39P2C5H5Fe
  • Solvias Ligands
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Chiral Phosphine
  • Ferrocene Series
  • Josiphos Series
  • organophosphine ligand