ChemicalBook > CAS DataBase List > (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

Product Name
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS No.
158923-09-2
Chemical Name
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
Synonyms
JOSIPHOS SL-J004-1;OSIPHOS SL-J004-1;(R)1[(1S)2(di-C-hex;(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin;R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...;(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
CBNumber
CB7211931
Molecular Formula
C36H44FeP210*
Formula Weight
594.53
MOL File
158923-09-2.mol
More
Less

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Property

alpha 
-100° ±5° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
More
Less

Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
F 
10
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
100mg
Price
$96.8
Updated
2024/03/01
Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
1g
Price
$727
Updated
2024/03/01
Strem Chemicals
Product number
26-1230
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
26-1230
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%
Packaging
500mg
Price
$375
Updated
2024/03/01
Sigma-Aldrich
Product number
88723
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
Purity
≥97%
Packaging
500mg
Price
$442
Updated
2023/06/20
More
Less

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties,Usage,Production

Chemical Properties

Red crystal

Uses

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

  • To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
  • In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Reactions

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .

General Description

sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Suppliers

China 60 Germany 2 India 1 Norway 1 Switzerland 1 United States 5 Global 70
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Shanghai Holy Biohemdeviser Co., Ltd
Tel
021-61551100
Fax
021-61551100
Country
China
ProdList
444
Advantage
57
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
Advantage
62
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
305
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3013
Advantage
58

158923-09-2, (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINERelated Search:

ETHYLDIPHENYLPHOSPHINE (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE DICYCLOHEXYLPHOSPHINE 1,3-BIS(PHOSPHINO)PROPANE TRIISOPROPYLPHOSPHINE TRIHEXYLPHOSPHINE

  • (R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
  • (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE
  • (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
  • (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin
  • (R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&
  • (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%
  • (r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas)
  • (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
  • Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS)
  • (R)1[(1S)2(di-C-hex
  • (S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino
  • JOSIPHOS SL-J004-1
  • OSIPHOS SL-J004-1
  • (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine >=97%
  • Ferrocene, 1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-, (1R)-
  • (R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
  • R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...
  • (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (ACI)
  • 158923-09-2
  • C36H44FeP2
  • C31H39P2C5H5Fe
  • Solvias Ligands
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Chiral Phosphine
  • Ferrocene Series
  • Josiphos Series
  • organophosphine ligand