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1,2-PHENYLENE PHOSPHOROCHLORIDITE

Product Name
1,2-PHENYLENE PHOSPHOROCHLORIDITE
CAS No.
1641-40-3
Chemical Name
1,2-PHENYLENE PHOSPHOROCHLORIDITE
Synonyms
o-Phenylene chlorophosphite;CATECHYL PHOSPHORUS CHLORIDE;O-PHENYLENE PHOSPHOROCHLORIDITE;2-benzodioxaphosphole,2-chloro-3;Pyrocatechol phosphoryl chloride;1,2-PHENYLENE PHOSPHOROCHLORIDITE;2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE;o-Phenylene phosphorochloridite,97%;1,3,2-Benzodioxaphosphole,2-chloro-;Chloro(1,2-phenylenedioxy)phosphine
CBNumber
CB7221181
Molecular Formula
C6H4ClO2P
Formula Weight
174.52
MOL File
1641-40-3.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDITE Property

Melting point:
30-35 °C(lit.)
Boiling point:
80 °C20 mm Hg(lit.)
Density 
1.466 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.571(lit.)
Flash point:
>230 °F
storage temp. 
0-6°C
solubility 
Benzene (Slightly), Chloroform (Slightly)
form 
solid
Sensitive 
Moisture Sensitive
BRN 
135455
Stability:
Moisture Sensitive
CAS DataBase Reference
1641-40-3(CAS DataBase Reference)
EPA Substance Registry System
1,3,2-Benzodioxaphosphole, 2-chloro- (1641-40-3)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
155764
Product name
o-Phenylene phosphorochloridite
Purity
97%
Packaging
10g
Price
$53.7
Updated
2023/06/20
TRC
Product number
P320000
Product name
1,2-PhenylenePhosphorochloridite(TechnicalGrade)
Packaging
1g
Price
$50
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001494
Product name
1,2-PHENYLENE PHOSPHOROCHLORIDITE
Purity
95.00%
Packaging
5G
Price
$465
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001494
Product name
1,2-PHENYLENE PHOSPHOROCHLORIDITE
Purity
95.00%
Packaging
10G
Price
$505
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001494
Product name
1,2-PHENYLENE PHOSPHOROCHLORIDITE
Purity
95.00%
Packaging
100G
Price
$940
Updated
2021/12/16
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1,2-PHENYLENE PHOSPHOROCHLORIDITE Chemical Properties,Usage,Production

Chemical Properties

Colourless Liquid Which Solidifies at Low Temperature

Uses

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs

Uses

  • Catalyst in synthesis of bakkane sesquiterpenes
  • Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures
  • Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts
  • Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction
  • Phosphorylation agent
  • Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition

1,2-PHENYLENE PHOSPHOROCHLORIDITE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2-PHENYLENE PHOSPHOROCHLORIDITE Suppliers

Toronto Research Chemicals
Tel
--
Fax
--
Email
info@trc-canada.com
Country
Canada
ProdList
6038
Advantage
71
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View Lastest Price from 1,2-PHENYLENE PHOSPHOROCHLORIDITE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
1,2-Phenylene Phosphorochloridite 1641-40-3
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16

1641-40-3, 1,2-PHENYLENE PHOSPHOROCHLORIDITERelated Search:


  • 1,3,2-Benzodioxaphosphole,2-chloro-
  • 2-benzodioxaphosphole,2-chloro-3
  • O-PHENYLENE PHOSPHOROCHLORIDITE
  • 1,2-PHENYLENE PHOSPHOROCHLORIDITE
  • 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE
  • Catechyl phosphorus chloride~2-Chloro-1,3,2-benzodioxaphosphole
  • 1,2-Phenylene phosphorochloridite, 98+%
  • CATECHYL PHOSPHORUS CHLORIDE
  • Chloridophosphorous acid 1,2-phenylene ester
  • o-Phenylene chlorophosphite
  • o-Phenylene phosphorochloridite,97%
  • o-Phenylene phosphorochloridite,2-Chloro-1,3,2-benzodioxaphosphole
  • Chloro(1,2-phenylenedioxy)phosphine
  • Cyclic o-phenylene phosphorochloridite
  • Pyrocatechol phosphoryl chloride
  • o-Phenylene phosphorochloridite 97%
  • 2-Chloro-4,5-benzo-1,3,2-dioxaphospholane
  • Phosphorochloridous Acid Orthophenylene Ester
  • 2-chlorobenzo[d][1,3,2]dioxaphosphole
  • 1,2-Phenylene Phosphorochloridite (Technical Grade)
  • 1641-40-3
  • C6H4O2PCl
  • C6H4ClO2P
  • 80C20mmHg
  • Catalysis and Inorganic Chemistry
  • Phosphorus Precursors
  • Phosphorus Compounds
  • Phospholipids - 13C & 2H
  • Phosphorylating and Phosphitylating Agents
  • Aromatics
  • Heterocycles