ChemicalBook > CAS DataBase List > 1,2-PHENYLENE PHOSPHOROCHLORIDATE
1,2-PHENYLENE PHOSPHOROCHLORIDATE
- Product Name
- 1,2-PHENYLENE PHOSPHOROCHLORIDATE
- CAS No.
- 1499-17-8
- Chemical Name
- 1,2-PHENYLENE PHOSPHOROCHLORIDATE
- Synonyms
- o-Phenylene chlorophosphate;1,2-PHENYLENE CHLOROPHOSPHATE;o-Phenylenephosphorochloridate;1,2-PHENYLENE PHOSPHOROCHLORIDATE;Catechol cyclophosphorochloridate;O,O-(o-Phenylene) chlorophosphate;orthoisophenylchlorophosphinoacid;o-Phenylene phosphorochloridate;3,2-benzodioxaphosphole,2-chloro-2-oxide;1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.
- CBNumber
- CB8350523
- Molecular Formula
- C6H4ClO3P
- Formula Weight
- 190.52
- MOL File
- 1499-17-8.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Property
- Melting point:
- 56-62 °C
- Boiling point:
- 120 °C9 mm Hg(lit.)
- Density
- 1.57±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- form
- solid
- BRN
- 142368
- InChI
- 1S/C6H4ClO3P/c7-11(8)9-5-3-1-2-4-6(5)10-11/h1-4H
- InChIKey
- KMWSGKPLIWNTEF-UHFFFAOYSA-N
- SMILES
- ClP1(=O)Oc2ccccc2O1
- EPA Substance Registry System
- 1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide (1499-17-8)
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Safety
- Hazard Codes
- C
- Risk Statements
- 14-34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10
- TSCA
- TSCA listed
- HazardClass
- 8
- PackingGroup
- III
- Storage Class
- 8A - Combustible corrosive hazardous materials
- Hazard Classifications
- Skin Corr. 1B
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 156140
- Product name
- o-Phenylene phosphorochloridate
- Purity
- 96%
- Packaging
- 5g
- Price
- $254
- Updated
- 2023/06/20
Matrix Scientific
- Product number
- 097608
- Product name
- 2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide
- Purity
- 95+%
- Packaging
- 5g
- Price
- $471
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0156519
- Product name
- O-PHENYLENE PHOSPHOROCHLORIDATE
- Purity
- 95.00%
- Packaging
- 250MG
- Price
- $586.6
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0156519
- Product name
- O-PHENYLENE PHOSPHOROCHLORIDATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $938.67
- Updated
- 2021/12/16
Crysdot
- Product number
- CD61001213
- Product name
- 2-Chlorobenzo[d][1,3,2]dioxaphosphole2-oxide
- Purity
- 95%
- Packaging
- 1g
- Price
- $260
- Updated
- 2021/12/16
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Chemical Properties,Usage,Production
Uses
Reactant for preparation of:
- Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity
- Vinyloxy phosphorus monomers
- Phosphorylation agent
Preparation
1,2-Phenylene phosphorochloridate is prepared by heating 2,2,2-trichloro-1,3,2-benzodioxaphosphole with a slight excess of acetic anhydride.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Purification Methods
After distilling it in a vacuum, it sets to a colourless solid. It is soluble in pet ether, *benzene and slightly soluble in Et2O. [Khwaja et al. J Chem Soc (C) 2092 1970, Anschütz & Broeker Justus Liebigs Ann Chem 454 109 1927, Beilstein 6 IV 5602.]
1,2-PHENYLENE PHOSPHOROCHLORIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Suppliers
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View Lastest Price from 1,2-PHENYLENE PHOSPHOROCHLORIDATE manufacturers
Shaanxi Dideu Medichem Co. Ltd
- Product
- O-Phenylene phosphorochloridate 1499-17-8
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2020-01-16
Career Henan Chemical Co
- Product
- 1,2-PHENYLENE PHOSPHOROCHLORIDATE 1499-17-8
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-13
1499-17-8, 1,2-PHENYLENE PHOSPHOROCHLORIDATERelated Search:
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