ChemicalBook > CAS DataBase List > 1,2-PHENYLENE PHOSPHOROCHLORIDATE

1,2-PHENYLENE PHOSPHOROCHLORIDATE

Product Name
1,2-PHENYLENE PHOSPHOROCHLORIDATE
CAS No.
1499-17-8
Chemical Name
1,2-PHENYLENE PHOSPHOROCHLORIDATE
Synonyms
o-Phenylene chlorophosphate;1,2-PHENYLENE CHLOROPHOSPHATE;o-Phenylenephosphorochloridate;1,2-PHENYLENE PHOSPHOROCHLORIDATE;Catechol cyclophosphorochloridate;O,O-(o-Phenylene) chlorophosphate;3,2-benzodioxaphosphole,2-chloro-2-oxide;1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.;2-Chloro-2-oxo-1,3,2-benzodioxaphosphole;2-Chloro-1,3-dioxa-2-phosphaindan 2-oxide
CBNumber
CB8350523
Molecular Formula
C6H4ClO3P
Formula Weight
190.52
MOL File
1499-17-8.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Property

Melting point:
56-62 °C
Boiling point:
120 °C9 mm Hg(lit.)
Density 
1.57±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
BRN 
142368
EPA Substance Registry System
1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide (1499-17-8)
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
156140
Product name
o-Phenylene phosphorochloridate
Purity
96%
Packaging
5g
Price
$254
Updated
2023/06/20
Matrix Scientific
Product number
097608
Product name
2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide
Purity
95+%
Packaging
5g
Price
$471
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0156519
Product name
O-PHENYLENE PHOSPHOROCHLORIDATE
Purity
95.00%
Packaging
250MG
Price
$586.6
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0156519
Product name
O-PHENYLENE PHOSPHOROCHLORIDATE
Purity
95.00%
Packaging
5G
Price
$938.67
Updated
2021/12/16
Crysdot
Product number
CD61001213
Product name
2-Chlorobenzo[d][1,3,2]dioxaphosphole2-oxide
Purity
95%
Packaging
1g
Price
$260
Updated
2021/12/16
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Chemical Properties,Usage,Production

Uses

Reactant for preparation of:

  • Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity
  • Vinyloxy phosphorus monomers

  • Phosphorylation agent

Purification Methods

After distilling it in a vacuum, it sets to a colourless solid. It is soluble in pet ether, *benzene and slightly soluble in Et2O. [Khwaja et al. J Chem Soc (C) 2092 1970, Anschütz & Broeker Justus Liebigs Ann Chem 454 109 1927, Beilstein 6 IV 5602.]

1,2-PHENYLENE PHOSPHOROCHLORIDATE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2-PHENYLENE PHOSPHOROCHLORIDATE Suppliers

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View Lastest Price from 1,2-PHENYLENE PHOSPHOROCHLORIDATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
O-Phenylene phosphorochloridate 1499-17-8
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16
Career Henan Chemical Co
Product
1,2-PHENYLENE PHOSPHOROCHLORIDATE 1499-17-8
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-13

1499-17-8, 1,2-PHENYLENE PHOSPHOROCHLORIDATERelated Search:


  • 3,2-benzodioxaphosphole,2-chloro-2-oxide
  • o-Phenylenephosphorochloridate
  • 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE 2-OXIDE
  • 1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.
  • 1,2-PHENYLENE PHOSPHOROCHLORIDATE
  • 1,2-PHENYLENE CHLOROPHOSPHATE
  • 2-Chloro-1,3,2-benzodioxaphosphole 2-oxide, o-Phenylene chlorophosphate
  • o-Phenylene chlorophosphate
  • 8-chloro-7,9-dioxa-8$l^{5}-phosphabicyclo[4.3.0]nona-1,3,5-triene 8-oxide
  • 2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide
  • 2-Chloro-1,3-dioxa-2-phosphaindan 2-oxide
  • Catechol cyclophosphorochloridate
  • O,O-(o-Phenylene) chlorophosphate
  • o-Phenylene phosphorochloridate technical grade
  • 2-Chloro-2-oxo-1,3,2-benzodioxaphosphole
  • 1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide
  • 1499-17-8
  • C6H4ClO3P
  • Phosphorus Compounds
  • Phosphorus Precursors
  • Catalysis and Inorganic Chemistry