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METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE

Product Name
METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE
CAS No.
62451-84-7
Chemical Name
METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE
Synonyms
Methyl 2-(3-(;AURORA KA-6005;Methyl 2-(3-(trifluoromethyl);METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE;Methyle3-(trifluoromethyl)phenylacetate;Methyl3-(trifluoromethyl)phenylacetate,95%;Methyl 2-[3-(trifluoromethyl)phenyl]acetate;Methyl 3-(trifluoromethyl)phenylacetate,97%;Methyl 3-(trifluoromethyl)phenylacetate 97%;(3-TRIFLUOROMETHYLPHENYL) ACETIC ACID METHYL ESTER
CBNumber
CB7225114
Molecular Formula
C10H9F3O2
Formula Weight
218.17
MOL File
62451-84-7.mol
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METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE Property

Boiling point:
211℃
Density 
1.24
refractive index 
1.45-1.452
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
HazardClass 
IRRITANT
HS Code 
29163900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
EME00055
Product name
Methyl 2-[3-(trifluoromethyl)phenyl]acetate
Packaging
1G
Price
$36.7
Updated
2025/07/31
TRC
Product number
M332153
Product name
Methyl3-(trifluoromethyl)phenylacetate
Packaging
250mg
Price
$55
Updated
2021/12/16
AK Scientific
Product number
9411AB
Product name
Methyl2-(3-(trifluoromethyl)phenyl)acetate
Packaging
1g
Price
$67
Updated
2021/12/16
AK Scientific
Product number
9411AB
Product name
Methyl2-(3-(trifluoromethyl)phenyl)acetate
Packaging
5g
Price
$99
Updated
2021/12/16
Apolloscientific
Product number
PC4391
Product name
Methyl3-(trifluoromethyl)phenylacetate
Packaging
25g
Price
$135
Updated
2021/12/16
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METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Synthesis

67-56-1

351-35-9

62451-84-7

Concentrated sulfuric acid (50 mL) was added slowly to a solution of methanol (1200 mL) of m-trifluoromethylphenylacetic acid (1.0 mol). The reaction mixture was heated to reflux and the reaction was stirred overnight. Upon completion of the reaction, the reaction solution was concentrated to dryness under reduced pressure. Water (600 mL) was added to the residue and extracted with ethyl acetate (3 x 400 mL). The organic layers were combined and washed with water until neutral. The organic layer was dried with anhydrous sodium sulfate, filtered and concentrated. The crude product was purified by column chromatography (eluent: ethyl acetate/petroleum ether=1:20) to afford methyl 3-trifluoromethylphenylacetate (108 g, 100% yield) as a yellow oil.

References

[1] Bioorganic and Medicinal Chemistry, 2003, vol. 11, # 13, p. 2843 - 2866
[2] Patent: US2005/234046, 2005, A1. Location in patent: Page/Page column 97
[3] Helvetica Chimica Acta, 1971, vol. 54, p. 868 - 897
[4] Tetrahedron Letters, 2018, vol. 59, # 22, p. 2161 - 2166
[5] Patent: US2479295, 1946,

METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE Suppliers

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62451-84-7, METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATERelated Search:

Methyl phenylacetate Phenylacetic acid Benzyl ɑ-cyano-2-nitro-5-(trifluoromethyl)phenylacetate, 95% ETHYL 3,5-BIS(TRIFLUOROMETHYL)PHENYL ACETATE METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE ethyl 2-(2-fluoro-5-(trifluoromethyl)phenyl)acetate DIMETHYL 2-[2-NITRO-5-(TRIFLUOROMETHYL)PHENYL]MALONATE 3-OXO-3-(3-TRIFLUOROMETHYLPHENYL)PROPIONIC ACID ETHYL ESTER ethyl 2-(2,5-bis(trifluoromethyl)phenyl)acetate DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE ethyl 2-(2-fluoro-3-(trifluoromethyl)phenyl)acetate DIETHYL 3-TRIFLUOROMETHYLPHENYL MALONATE ETHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE ETHYL 2-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-2-OXOACETATE 3,3,3-TRIFLUORO-2-HYDROXY-2-(3-TRIFLUOROMETHYLPHENYL)PROPIONIC ACID ETHYL ESTER 2-[(3-CYANO-2-THIENYL)AMINO]-2-OXOETHYL 2-[3-(TRIFLUOROMETHYL)PHENYL]ACETATE ETHYL 2-CYANO-2-[2-NITRO-5-(TRIFLUOROMETHYL)PHENYL]ACETATE DIMETHYL 2-ALLYL-2-[2-NITRO-5-(TRIFLUOROMETHYL)PHENYL]MALONATE

  • (3-TRIFLUOROMETHYLPHENYL) ACETIC ACID METHYL ESTER
  • METHYL 3-(TRIFLUOROMETHYL)PHENYLACETATE
  • AURORA KA-6005
  • Methyl 3-(trifluoromethyl)phenylacetate 97%
  • Methyl 3-(trifluoromethyl)phenylacetate,97%
  • Methyl 2-[3-(trifluoromethyl)phenyl]acetate
  • Methyle3-(trifluoromethyl)phenylacetate
  • Methyl 2-(3-(
  • 3-(Trifluoromethyl)phenylacetic acid methyl ester, 3-(2-Methoxy-2-oxoethyl)benzotrifluoride
  • Methyl 2-(3-(trifluoromethyl)
  • 2-[3-(trifluoromethyl)phenyl]acetic acid methyl ester
  • Benzeneacetic acid, 3-(trifluoromethyl)-, methyl ester
  • Methyl3-(trifluoromethyl)phenylacetate,95%
  • 62451-84-7
  • C10H9F3O2