CYCLOPENTEN-1-YLBORONIC ACID
- Product Name
- CYCLOPENTEN-1-YLBORONIC ACID
- CAS No.
- 850036-28-1
- Chemical Name
- CYCLOPENTEN-1-YLBORONIC ACID
- Synonyms
- openten-1-yL;1-Boronocyclopent-1-ene;Cyclopenten-1-ylboronic;Cyclopentenylboronic acid;1-Cyclopenteneboronic Acid;1-Cyclopentenylboronic acid;Cyclopentene-1-boronic acid;CYCLOPENTEN-1-YLBORONIC ACID;Cyclopent-1-ene-1-boronic acid;1-CYCLOPENTEN-1-YLBORONIC ACID
- CBNumber
- CB7230602
- Molecular Formula
- C5H9BO2
- Formula Weight
- 111.93
- MOL File
- 850036-28-1.mol
CYCLOPENTEN-1-YLBORONIC ACID Property
- Melting point:
- 134-140°C
- Boiling point:
- 246.7±33.0 °C(Predicted)
- Density
- 1.08±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- pka
- 9.44±0.20(Predicted)
- form
- solid
- color
- white to pale yellow
- InChI
- 1S/C5H9BO2/c7-6(8)5-3-1-2-4-5/h3,7-8H,1-2,4H2
- InChIKey
- UZBHNSVUMGIKLU-UHFFFAOYSA-N
- SMILES
- OB(O)C1=CCCC1
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-41-37/38
- Safety Statements
- 26-36/37/39-39
- WGK Germany
- WGK 3
- Hazard Note
- Harmful/Irritant/Keep Cold
- TSCA
- No
- HS Code
- 29319090
- Storage Class
- 11 - Combustible Solids
- Hazard Classifications
- Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- C2893
- Product name
- 1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $63
- Updated
- 2026/03/19
- Product number
- C2893
- Product name
- 1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $186
- Updated
- 2026/03/19
- Product number
- C991468
- Product name
- Cyclopenten-1-ylboronicacid
- Packaging
- 5g
- Price
- $1100
- Updated
- 2021/12/16
- Product number
- CS-W000981
- Product name
- (Cyclopent-1-en-1-yl)boronicacid
- Purity
- >97.0%
- Packaging
- 1g
- Price
- $20
- Updated
- 2021/12/16
- Product number
- FC137349
- Product name
- Cyclopenten-1-ylboronic acid
- Packaging
- 250mg
- Price
- $62.5
- Updated
- 2021/12/16
CYCLOPENTEN-1-YLBORONIC ACID Chemical Properties,Usage,Production
Chemical Properties
Off-white powder
Uses
suzuki reaction
Synthesis
Cyclopenten-1-ylboronic acid is prepared as follows:
The first step of the raw material 1-chlorocyclopentene preparation: to a 2L four-necked bottle equipped with magnetic stirring, thermometer, condenser tube and exhaust gas alkali absorption device, add 374.2 (1.818mol, 1.05) phosphorus pentachloride, 863g of n-heptane, warming to 70 , drop 151.4g (1.803mol, 1eq) cyclopentanone, about 2 hours after the drop, and continue the reaction Half an hour, after cooling down to 0 , dropwise addition of 6 mol / L sodium hydroxide solution 0.69 kg, stirring for one hour, separation of the upper organic layer, the organic layer was washed once with saturated sodium bicarbonate, to obtain 1-chlorocyclopentene n-hexane solution 799 g, the internal standard yield of 81.1%;
The second step of preparation of cyclopenten-1-ylboronic acid: to a 5L four-necked flask equipped with mechanical stirring, thermometer, argon protection and reflux condenser tube was added T2215.5g (1.608mol, 1.1eq), lithium metal 22.6g (3.216mol, 2.2eq), tetrahydrofuran 678g, cooled down to -10C, and dropwise addition of 1-chlorocyclopentene's Heptane solution (1eq), titration is completed insulation -10 stirring 11 hours, GC control, the end of the reaction, add 1.3kg6N hydrochloric acid adjust PH = 2 ~ 3, stratification, the aqueous layer and then 400g of ethyl acetate extracted once, combined with the organic layer, 40 distillation under reduced pressure, to not flow, precipitation of solids, add 200g of n-heptane-10 pulp, filtration, drying to obtain the white solid cyclopentene -1-ylboronic acid 89.3g, yield 54.5%.
CYCLOPENTEN-1-YLBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
CYCLOPENTEN-1-YLBORONIC ACID Suppliers
- Tel
- 400-0066400 13621662912
- Fax
- 021-55660885
- sales@jonln.com
- Country
- China
- ProdList
- 1995
- Advantage
- 65
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44802
- Advantage
- 61
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9254
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- marketing@accelachem.com
- Country
- China
- ProdList
- 10977
- Advantage
- 64
- Tel
- 025-83697070 13770331960
- Fax
- +86-25-83453306
- info@chemlin.com.cn
- Country
- China
- ProdList
- 16027
- Advantage
- 64
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- 021-56491756 13512199871
- 2819742715@qq.com
- Country
- China
- ProdList
- 3999
- Advantage
- 55
View Lastest Price from CYCLOPENTEN-1-YLBORONIC ACID manufacturers
- Product
- 1-Cyclopentenylboronic acid 850036-28-1
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-07-02
- Product
- CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09