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CYCLOPENTEN-1-YLBORONIC ACID

Product Name
CYCLOPENTEN-1-YLBORONIC ACID
CAS No.
850036-28-1
Chemical Name
CYCLOPENTEN-1-YLBORONIC ACID
Synonyms
openten-1-yL;1-Boronocyclopent-1-ene;Cyclopenten-1-ylboronic;Cyclopentenylboronic acid;1-Cyclopenteneboronic Acid;1-Cyclopentenylboronic acid;Cyclopentene-1-boronic acid;CYCLOPENTEN-1-YLBORONIC ACID;Cyclopent-1-ene-1-boronic acid;1-CYCLOPENTEN-1-YLBORONIC ACID
CBNumber
CB7230602
Molecular Formula
C5H9BO2
Formula Weight
111.93
MOL File
850036-28-1.mol
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CYCLOPENTEN-1-YLBORONIC ACID Property

Melting point:
134-140°C
Boiling point:
246.7±33.0 °C(Predicted)
Density 
1.08±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
pka
9.44±0.20(Predicted)
form 
solid
color 
white to pale yellow
InChI
1S/C5H9BO2/c7-6(8)5-3-1-2-4-5/h3,7-8H,1-2,4H2
InChIKey
UZBHNSVUMGIKLU-UHFFFAOYSA-N
SMILES
OB(O)C1=CCCC1
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-41-37/38
Safety Statements 
26-36/37/39-39
WGK Germany 
WGK 3
Hazard Note 
Harmful/Irritant/Keep Cold
TSCA 
No
HS Code 
29319090
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
C2893
Product name
1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$63
Updated
2026/03/19
TCI Chemical
Product number
C2893
Product name
1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$186
Updated
2026/03/19
TRC
Product number
C991468
Product name
Cyclopenten-1-ylboronicacid
Packaging
5g
Price
$1100
Updated
2021/12/16
ChemScene
Product number
CS-W000981
Product name
(Cyclopent-1-en-1-yl)boronicacid
Purity
>97.0%
Packaging
1g
Price
$20
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC137349
Product name
Cyclopenten-1-ylboronic acid
Packaging
250mg
Price
$62.5
Updated
2021/12/16
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CYCLOPENTEN-1-YLBORONIC ACID Chemical Properties,Usage,Production

Chemical Properties

Off-white powder

Uses

suzuki reaction

Synthesis

Cyclopenten-1-ylboronic acid is prepared as follows:

The first step of the raw material 1-chlorocyclopentene preparation: to a 2L four-necked bottle equipped with magnetic stirring, thermometer, condenser tube and exhaust gas alkali absorption device, add 374.2 (1.818mol, 1.05) phosphorus pentachloride, 863g of n-heptane, warming to 70 , drop 151.4g (1.803mol, 1eq) cyclopentanone, about 2 hours after the drop, and continue the reaction Half an hour, after cooling down to 0 , dropwise addition of 6 mol / L sodium hydroxide solution 0.69 kg, stirring for one hour, separation of the upper organic layer, the organic layer was washed once with saturated sodium bicarbonate, to obtain 1-chlorocyclopentene n-hexane solution 799 g, the internal standard yield of 81.1%;

The second step of preparation of cyclopenten-1-ylboronic acid: to a 5L four-necked flask equipped with mechanical stirring, thermometer, argon protection and reflux condenser tube was added T2215.5g (1.608mol, 1.1eq), lithium metal 22.6g (3.216mol, 2.2eq), tetrahydrofuran 678g, cooled down to -10C, and dropwise addition of 1-chlorocyclopentene's Heptane solution (1eq), titration is completed insulation -10 stirring 11 hours, GC control, the end of the reaction, add 1.3kg6N hydrochloric acid adjust PH = 2 ~ 3, stratification, the aqueous layer and then 400g of ethyl acetate extracted once, combined with the organic layer, 40 distillation under reduced pressure, to not flow, precipitation of solids, add 200g of n-heptane-10 pulp, filtration, drying to obtain the white solid cyclopentene -1-ylboronic acid 89.3g, yield 54.5%.

CYCLOPENTEN-1-YLBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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CYCLOPENTEN-1-YLBORONIC ACID Suppliers

future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9254
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
marketing@accelachem.com
Country
China
ProdList
10977
Advantage
64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070 13770331960
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16027
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shanghai Sphchem Co., Ltd.
Tel
021-56491756 13512199871
Email
2819742715@qq.com
Country
China
ProdList
3999
Advantage
55
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View Lastest Price from CYCLOPENTEN-1-YLBORONIC ACID manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
1-Cyclopentenylboronic acid 850036-28-1
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-07-02
Zhuozhou Wenxi import and Export Co., Ltd
Product
CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

850036-28-1, CYCLOPENTEN-1-YLBORONIC ACIDRelated Search:


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