CYCLOPENTEN-1-YLBORONIC ACID
- Product Name
- CYCLOPENTEN-1-YLBORONIC ACID
- CAS No.
- 850036-28-1
- Chemical Name
- CYCLOPENTEN-1-YLBORONIC ACID
- Synonyms
- openten-1-yL;1-Boronocyclopent-1-ene;Cyclopenten-1-ylboronic;Cyclopentenylboronic acid;1-Cyclopenteneboronic Acid;1-Cyclopentenylboronic acid;CYCLOPENTEN-1-YLBORONIC ACID;Cyclopent-1-ene-1-boronic acid;1-CYCLOPENTEN-1-YLBORONIC ACID;Cyclopent-1-en-1-ylboronic acid
- CBNumber
- CB7230602
- Molecular Formula
- C5H9BO2
- Formula Weight
- 111.93
- MOL File
- 850036-28-1.mol
CYCLOPENTEN-1-YLBORONIC ACID Property
- Melting point:
- 134-140°C
- Boiling point:
- 246.7±33.0 °C(Predicted)
- Density
- 1.08±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- pka
- 9.44±0.20(Predicted)
- form
- solid
- color
- white to pale yellow
- InChI
- 1S/C5H9BO2/c7-6(8)5-3-1-2-4-5/h3,7-8H,1-2,4H2
- InChIKey
- UZBHNSVUMGIKLU-UHFFFAOYSA-N
- SMILES
- OB(O)C1=CCCC1
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-41-37/38
- Safety Statements
- 26-36/37/39-39
- WGK Germany
- WGK 3
- Hazard Note
- Harmful/Irritant/Keep Cold
- TSCA
- No
- HS Code
- 29319090
- Storage Class
- 11 - Combustible Solids
- Hazard Classifications
- Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- C2893
- Product name
- 1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $74
- Updated
- 2025/07/31
- Product number
- C2893
- Product name
- 1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $219
- Updated
- 2025/07/31
- Product number
- C991468
- Product name
- Cyclopenten-1-ylboronicacid
- Packaging
- 5g
- Price
- $1100
- Updated
- 2021/12/16
- Product number
- 6460-1-X1
- Product name
- Cyclopent-1-ene-1-boronic acid
- Packaging
- 25g
- Price
- $373
- Updated
- 2021/12/16
- Product number
- 34973
- Product name
- Cyclopent-1-en-1-ylboronicacid
- Purity
- 97%
- Packaging
- 1g
- Price
- $400
- Updated
- 2021/12/16
CYCLOPENTEN-1-YLBORONIC ACID Chemical Properties,Usage,Production
Chemical Properties
Off-white powder
Uses
suzuki reaction
Synthesis
Cyclopenten-1-ylboronic acid is prepared as follows:
The first step of the raw material 1-chlorocyclopentene preparation: to a 2L four-necked bottle equipped with magnetic stirring, thermometer, condenser tube and exhaust gas alkali absorption device, add 374.2 (1.818mol, 1.05) phosphorus pentachloride, 863g of n-heptane, warming to 70 ??, drop 151.4g (1.803mol, 1eq) cyclopentanone, about 2 hours after the drop, and continue the reaction Half an hour, after cooling down to 0 ??, dropwise addition of 6 mol / L sodium hydroxide solution 0.69 kg, stirring for one hour, separation of the upper organic layer, the organic layer was washed once with saturated sodium bicarbonate, to obtain 1-chlorocyclopentene n-hexane solution 799 g, the internal standard yield of 81.1%;
The second step of preparation of cyclopenten-1-ylboronic acid: to a 5L four-necked flask equipped with mechanical stirring, thermometer, argon protection and reflux condenser tube was added T2215.5g (1.608mol, 1.1eq), lithium metal 22.6g (3.216mol, 2.2eq), tetrahydrofuran 678g, cooled down to -10??C, and dropwise addition of 1-chlorocyclopentene's Heptane solution (1eq), titration is completed insulation -10 ?? stirring 11 hours, GC control, the end of the reaction, add 1.3kg6N hydrochloric acid adjust PH = 2 ~ 3, stratification, the aqueous layer and then 400g of ethyl acetate extracted once, combined with the organic layer, 40 ?? distillation under reduced pressure, to not flow, precipitation of solids, add 200g of n-heptane-10 ?? pulp, filtration, drying to obtain the white solid cyclopentene -1-ylboronic acid 89.3g, yield 54.5%.
CYCLOPENTEN-1-YLBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
CYCLOPENTEN-1-YLBORONIC ACID Suppliers
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View Lastest Price from CYCLOPENTEN-1-YLBORONIC ACID manufacturers
- Product
- 1-Cyclopentenylboronic acid 850036-28-1
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-07-02
- Product
- CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- CYCLOPENTEN-1-YLBORONIC ACID 850036-28-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09