ChemicalBook > CAS DataBase List > 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

Product Name
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
CAS No.
18388-03-9
Chemical Name
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
Synonyms
2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE;2-Methylene-3-chloropropyltrimethylsilane;2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE;2-(chloromethyl)prop-2-enyl-trimethylsilane;2-(Trimethylsilylmethyl)-3-chloro-1-propene;2-(Trimethylsilylmethyl)-2-propenyl chloride;[2-(Chloromethyl)-2-propenyl]trimethylsilane;Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-;2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
CBNumber
CB7243343
Molecular Formula
C7H15ClSi
Formula Weight
162.73
MOL File
18388-03-9.mol
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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Property

Boiling point:
162-163 °C/768 mmHg (lit.)
Density 
0.899 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.453(lit.)
Flash point:
110 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
Oil
color 
Clear Colourless
Specific Gravity
0.899
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
1747038
Stability:
Moisture Sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
TSCA 
No
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
318345
Product name
2-(Chloromethyl)allyl-trimethylsilane
Purity
97%
Packaging
1g
Price
$116
Updated
2024/03/01
Sigma-Aldrich
Product number
318345
Product name
2-(Chloromethyl)allyl-trimethylsilane
Purity
97%
Packaging
5g
Price
$414
Updated
2024/03/01
TRC
Product number
C371430
Product name
2-​(Chloromethyl)​allyl-​trimethylsilane
Packaging
500mg
Price
$95
Updated
2021/12/16
Arctom
Product number
SY248950
Product name
[2-(Chloromethyl)allyl]trimethylsilane
Purity
≥97%
Packaging
1g
Price
$1350
Updated
2021/12/16
AHH
Product number
MT-05953
Product name
2-Chloromethyl-3-trimethylsilyl-1-propene
Purity
97%
Packaging
10g
Price
$318
Updated
2021/12/16
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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Chemical Properties,Usage,Production

Uses

2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Suppliers

China 30 France 1 Germany 1 Singapore 1 Switzerland 1 United Kingdom 3 United States 6 Global 43
CARBONE SCIENTIFIC CO.,LTD
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Fluorochem Ltd.
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18388-03-9, 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENERelated Search:

2-Chloroethyltriethoxysilane 2-CHLOROETHYLMETHYLDICHLOROSILANE 2-CHLOROETHYLMETHYLDIMETHOXYSILANE (2-METHYL-PROPENYL)TRIMETHYLSILANE Silane, (3-chloropropyl)dimethyl- Allyltrimethylsilane Allyl chloride 3-Chloro-2-methylpropene ALLYLDIMETHYLSILANE (3-CHLOROPROPYL)TRIMETHYLSILANE 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE ETHYLTRIMETHYLSILANE

  • 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
  • 2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE
  • 2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE
  • [2-(Chloromethyl)-2-propenyl]trimethylsilane
  • 2-(Trimethylsilylmethyl)-2-propenyl chloride
  • 2-(Trimethylsilylmethyl)-3-chloro-1-propene
  • 2-Methylene-3-chloropropyltrimethylsilane
  • 2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
  • 2-(chloromethyl)prop-2-enyl-trimethylsilane
  • Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-
  • 18388-03-9
  • CH33SiCH2CCH2ClCH2
  • C7H15ClSi
  • Alkenyl
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • Building Blocks